期刊文献+
共找到9篇文章
< 1 >
每页显示 20 50 100
多元介孔MOFs:通过调节表面亲水/疏水性实现酶固定化的多功能平台
1
作者 冯玉晓 马庆庆 +5 位作者 王子辰 张群力 赵利雪 崔建东 杜英杰 贾士儒 《Chinese Journal of Catalysis》 SCIE CAS CSCD 2024年第5期386-398,共13页
作为高效的生物催化剂,酶在食品加工、医药制造、化学工业和能源开发等众多领域发挥着重要作用.然而,游离状态的酶由于存在稳定性差、易失活、难以回收利用及不适用于连续化生产等问题,限制了其广泛应用.为了解决上述难题,人们探索发展... 作为高效的生物催化剂,酶在食品加工、医药制造、化学工业和能源开发等众多领域发挥着重要作用.然而,游离状态的酶由于存在稳定性差、易失活、难以回收利用及不适用于连续化生产等问题,限制了其广泛应用.为了解决上述难题,人们探索发展了固定化酶技术.固定化酶不仅保留了原有的催化活性,而且在稳定性方面有了显著提升,从而极大地提高了酶的利用效率.随着固定化酶材料和酶工程领域的不断发展,固定化酶技术为酶的应用开辟了更广阔的前景.沸石-咪唑骨架材料-8(ZIF-8)作为一种金属-有机骨架(MOFs)材料,因其独特的结构特性而被广泛用作酶固定化载体.然而,ZIF-8的微孔结构和固有的疏水性,以及前体物2-甲基咪唑(2-MeIm)的质子化现象,常常影响固定化酶的活性.为克服这些限制,本文采用多元配体竞争和孔隙工程相结合的策略,设计并制备了一种具有可调节亲水/疏水表面的新型多元介孔MOFs(mMOFs),并用作酶固定化载体.在mMOFs的制备过程中,采用亲水性和配位能力更强的3-甲基-1H-1,2,4-三唑(3-MTZ)和5-甲基四唑(5-MTA)配体,以部分替代传统的2-MeIm配体.随后,这些多元配体(包括2-MeIm,3-MTZ和5-MTA)与七水硫酸锌结合,在甲醇溶液中通过自凝聚作用形成透明的胶体溶液,进而完全溶解在水中.在此过程中,七水硫酸锌发挥了软模板的作用,引导介孔的形成,从而成功制备出新型多元介孔mMOFs.接着,利用这些mMOFs作为酶固定化的载体,固定了辣根过氧化物酶(HRP)和葡萄糖氧化酶(GOx),并详细研究了其催化性能.结果表明,与传统的ZIF-8载体相比,以mMOFs为载体的固定化酶展现出了更高的酶活性和稳定性.催化性能提升主要归因于mMOFs的亲水性和介孔结构改善了酶和底物间的传质,同时2-MeIm的质子化效应减弱也为酶提供了优良的微环境,稳定了酶的构象.综上,本文采用多元配体竞争与孔隙工程相结合的策略,成功构建了一种具有可调节亲水/疏水表面的新型多元介孔mMOFs,并用于酶固定化,所得固定化酶表现出较好的催化性能.通过深入的研究,揭示了该固定化酶表现出良好催化性能的作用机制,为可控设计制备性能优越的、以MOFs为载体的固定化酶提供了新思路,并为进一步拓宽MOFs材料的应用范围提供了参考. 展开更多
关键词 介孔金属-有机骨架 竞争性配体 软模板 固定化酶
下载PDF
Investigation of the friction coefficient evolution and lubricant breakdown behaviour of AA7075 aluminium alloy forming processes at elevated temperatures 被引量:3
2
作者 Xiao Yang qunli zhang +4 位作者 Yang Zheng Xiaochuan Liu Denis Politis Omer El Fakir Liliang Wang 《International Journal of Extreme Manufacturing》 EI 2021年第2期99-105,共7页
The lubricant behaviour at elevated temperatures was investigated by conducting pin-on-disc tests between P20 tool steel and AA7075 aluminium alloy. The effects of temperature, initial lubricant volume, contact pressu... The lubricant behaviour at elevated temperatures was investigated by conducting pin-on-disc tests between P20 tool steel and AA7075 aluminium alloy. The effects of temperature, initial lubricant volume, contact pressure and sliding speed on the lubricant behaviour(i.e. evolutions of the coefficient of friction(COF) and the breakdown phenomenon) were experimentally studied. The evolutions of COF at elevated temperatures consisted of three distinct stages with different friction mechanisms. The first stage(stage Ⅰ) occurred with low friction when the boundary lubrication was present. The second stage(stage Ⅱ) was the transition process in which the COF rapidly increased as the lubricant film thickness decreased to a critical value. In the final plateau stage(stage Ⅲ), lubricant breakdown occurred and intimate contact at the interface led to high friction values. At the low friction stage(stage Ⅰ), the value of COF increased with increasing temperature. The increase in temperature, contact pressure and sliding speed as well as the decrease in initial lubricant volume accelerated the lubricant breakdown. 展开更多
关键词 elevated temperatures friction evolution lubricant breakdown behaviour pin-on-disc test
下载PDF
Practical Performance of Passive Thermal Catalysis for Indoor Formaldehyde 被引量:1
3
作者 Ge zhang Yan Li +2 位作者 Jiao Bai qunli zhang Jing Liu 《Journal of Harbin Institute of Technology(New Series)》 EI CAS 2019年第2期55-60,共6页
The purpose of this study is to investigate the practical performance of passive thermal catalysis for indoor formaldehyde. A heating plate coated with noble metal catalyst Pt/TiO_2 was made to simulate the radiators ... The purpose of this study is to investigate the practical performance of passive thermal catalysis for indoor formaldehyde. A heating plate coated with noble metal catalyst Pt/TiO_2 was made to simulate the radiators with a passive thermal catalysis function. The formaldehyde degradation rate in the presence of the simulated radiator was measured in a stainless-steel chamber under controlled temperature and compared with that in the presence of catalyst powder. The influence of temperature and the concentration of formaldehyde on the degradation performance was measured thoroughly and fitted in the polynomial form. It was found that the degradation capability of the coated catalyst dropped from that of the catalyst power, and the degradation capability trends of both materials in various temperatures were different. The clean air delivery rate(CADR) was found to be merely the function of temperature and irrelevant to indoor formaldehyde concentration in the investigated range. 展开更多
关键词 FORMALDEHYDE PT/TIO2 degradation PASSIVE THERMAL CATALYSIS CADR
下载PDF
Matrix Measure with Application in Quantized Synchronization Analysis of Complex Networks with Delayed Time via the General Intermittent Control
4
作者 qunli zhang 《Applied Mathematics》 2013年第10期1417-1426,共10页
This paper concerned with the quantized synchronization analysis problem. The scope of state vectors of dynamic systems, based on the matrix measure, is estimated. By using the general intermittent control, some simpl... This paper concerned with the quantized synchronization analysis problem. The scope of state vectors of dynamic systems, based on the matrix measure, is estimated. By using the general intermittent control, some simple yet generic criteria are derived ensuring the exponential stability of dynamic systems. Then, both the general intermittent networked controller and the quantized parameters can be designed, which guarantee that the nodes of the complex network are synchronized. Finally, simulation examples are given to illustrate the effectiveness and feasibility of the proposed method. 展开更多
关键词 Matrix Measure The General INTERMITTENT Control EXPONENTIAL Stability QUANTIZED SYNCHRONIZATION Complex Networks
下载PDF
DeST 3.0:A new-generation building performance simulation platform 被引量:7
5
作者 Da Yan Xin Zhou +28 位作者 Jingjing An Xuyuan Kang Fan Bu Youming Chen Yiqun Pan Yan Gao qunli zhang Hui Zhou Kuining Qiu Jing Liu Yan Liu Honglian Li Lei zhang Hong Dong Lixin Sun Song Pan Xiang Zhou Zhe Tian Wenjie zhang Ruhong Wu Hongsan Sun Yu Huang Xiaohong Su Yongwei zhang Rui Shen Diankun Chen Guangyuan Wei Yixing Chen Jinqing Peng 《Building Simulation》 SCIE EI CSCD 2022年第11期1849-1868,共20页
Buildings contribute to almost 30%of total energy consumption worldwide.Developing building energy modeling programs is of great significance for lifecycle building performance assessment and optimization.Advances in ... Buildings contribute to almost 30%of total energy consumption worldwide.Developing building energy modeling programs is of great significance for lifecycle building performance assessment and optimization.Advances in novel building technologies,the requirements of high-performance computation,and the demands for multi-objective models have brought new challenges for building energy modeling software and platforms.To meet the increasing simulation demands,DeST 3.0,a new-generation building performance simulation platform,was developed and released.The structure of DeST 3.0 incorporates four simulation engines,including building analysis and simulation(BAS)engine,HVAC system engine,combined plant simulation(CPS)engine,and energy system(ES)engine,connected by air loop and water loop balancing iterations.DeST 3.0 offers numerous new simulation features,such as advanced simulation modules for building envelopes,occupant behavior and energy systems,cross-platform and compatible simulation kernel,FMI/FMU-based co-simulation functionalities,and high-performance parallel simulation architecture.DeST 3.0 has been thoroughly evaluated and validated using code verification,inter-program comparison,and case-study calibration.DeST 3.0 has been applied in various aspects throughout the building lifecycle,supporting building design,operation,retrofit analysis,code appliance,technology adaptability evaluation as well as research and education.The new generation building simulation platform DeST 3.0 provides an efficient tool and comprehensive simulation platform for lifecycle building performance analysis and optimization. 展开更多
关键词 DeST building performance SIMULATION building energy modeling
原文传递
Effect of TiAl3 Content on Thermal Shock Resistance of Bionic Self-healing Thermal Barrier Coatings
6
作者 Panpan zhang Yujia Guo +3 位作者 Zhihui zhang Xiaofeng zhang qunli zhang Jianhua Yao 《Journal of Bionic Engineering》 SCIE EI CSCD 2022年第1期126-138,共13页
Inspired by the self-healing function of biological organisms,Bionic Laser Alloying(BLA)process was adopted to fabricate the bionic self-healing Thermal Barrier Coatings(TBCs).The BLA with different fractions of TiAl3... Inspired by the self-healing function of biological organisms,Bionic Laser Alloying(BLA)process was adopted to fabricate the bionic self-healing Thermal Barrier Coatings(TBCs).The BLA with different fractions of TiAl3 self-healing agent and Ceria and Yttria-Stabilized Zirconia(CYSZ)on the plasma-sprayed 7YSZ TBCs was carried out by a pulsed Nd:YAG laser.The effect of TiAl3 content on the microstructure,phase composition,and thermal shock behaviors of the bionic self-healing TBCs were investigated.Results indicated that the bionic self-healing TBCs had better thermal shock resistance than that of the as-sprayed TBCs.The thermal shock resistance increased first and then decreased with increasing TiAl3 fraction.The thermal shock resistance of the bionic self-healing TBCs with 15%TiAl3 is triple that of the as-sprayed TBCs.On one hand,the columnar crystals and vertical cracks could improve strain compatibility of TBCs during the thermal shock process;on the other hand,the TiAl3 as a self-healing agent reacted with oxygen in air at high temperature to seal the microcracks,thereby delaying the crack connection. 展开更多
关键词 Thermal barrier coating LASER Bionic self-healing Thermal shock resistance
原文传递
APPLICATIONS OF NONLINEAR MEASURE ABOUT l^2-NORM TO SYNCHRONIZATION ANALYSIS OF COMPLEX NETWORKS VIA THE GENERAL INTERMITTENT CONTROL
7
作者 qunli zhang 《Annals of Differential Equations》 2015年第1期115-126,共12页
Based on the nonlinear measure about /-norm,a novel and effective approach is applied to estimate the scope of state vectors of dynamic systems.By the general intermittent control,some simple yet generic criteria are ... Based on the nonlinear measure about /-norm,a novel and effective approach is applied to estimate the scope of state vectors of dynamic systems.By the general intermittent control,some simple yet generic criteria are derived ensuring the exponential stability of dynamic systems.The numerical simulations,whose theoretical results are applied to robust synchronization of complex networks,demonstrate the effectiveness and feasibility of the proposed technique. 展开更多
关键词 nonlinear measure the general intermittent control exponential stability SYNCHRONIZATION complex networks
原文传递
GENERALIZED DHALQUIST CONSTANT WITH APPLICATION IN STABLE ANALYSIS FOR DYNAMIC SYSTEMS ON TIME SCALES
8
作者 qunli zhang 《Annals of Differential Equations》 2013年第2期248-252,共5页
A novel and effective approach to exponentially stable analysis for dynamic systems on time scales is investigated using the nonlinear operator named the generalized Dahlquist constant in this paper, and simple yet ge... A novel and effective approach to exponentially stable analysis for dynamic systems on time scales is investigated using the nonlinear operator named the generalized Dahlquist constant in this paper, and simple yet generic criteria are derived ensuring the robust stability. 展开更多
关键词 dynamic system time scales generalized Dahlquist constant exponentially stable impulsive control
原文传递
Cross-linkedα-amylase aggregates on Fe3O4 magnetic nanoparticles modified with polydopamine/polyethyleneimine for efficient hydrolysis of starch
9
作者 Jiandong Cui Xiuming Tang +3 位作者 Qingqing Ma Yuyan Chang qunli zhang Shiru Jia 《Particuology》 SCIE EI CAS 2024年第7期98-105,共8页
In this workα-amylase was immobilized on magnetic Fe3O4 nanoparticles with polyethylenimine(PEI)/polydopamine(PDA)coating or 3-aminopropyl triethoxysilane(APTES)for the first time via adsorption–precipitation–cross... In this workα-amylase was immobilized on magnetic Fe3O4 nanoparticles with polyethylenimine(PEI)/polydopamine(PDA)coating or 3-aminopropyl triethoxysilane(APTES)for the first time via adsorption–precipitation–cross-linking.Compared with the freeα-amylase,the resultant magnetic cross-linkedα-amylase aggregates(PEI/PDA-M-CLEAs and N-M-CLEAs)exhibited excellent thermal and storage stability as well as pH stability.After storage at 25°C for 60 days,freeα-amylase only retained 60%of its initial activity,while PEI/PDA-M-CLEAs and N-M-CLEAs retained 80%and 78%of their initial activities,respectively.Furthermore,N-M-CLEAs and PEI/PDA-M-CLEAs showed good reusability.After 6 repeated uses,PEI/PDA-M-CLEAs and N-M-CLEAs still maintained 65%and 62%of their initial activities,respectively.Especially,PEI/PDA-M-CLEAs and N-M-CLEAs exhibited higher starch hydrolysis efficiency than freeα-amylase.The maximum dextrose equivalent(DE)values of starch hydrolysis by PEI/PDA-M-CLEAs and N-M-CLEAs reached 29.24%and 28.79%within 90 min,respectively.However,the maximum DE values of starch hydrolysis by the freeα-amylase was only 27.89%even in 150 min.The magnetic cross-linkedα-amylase aggregates could be introduced as effective biocatalyst for industrial applications in production of maltose syrups. 展开更多
关键词 α-amylase Magnetic nanoparticles Functional modification Magnetic cross-linked enzyme aggregates Hydrolysis of starch
原文传递
上一页 1 下一页 到第
使用帮助 返回顶部