Glycolic acid was polymerized under vacuum in the presence and absence of nano sized clay.The added clay catalyzed the condensation polymerization which can be confirmed by recording FTIR spectroscopy and intrinsic vi...Glycolic acid was polymerized under vacuum in the presence and absence of nano sized clay.The added clay catalyzed the condensation polymerization which can be confirmed by recording FTIR spectroscopy and intrinsic viscosity (Ⅳ)values.The relative intensity of C=O/CH is increased while increasing the amount of clay.DSC showed the appearance of multiple endotherms of poly(glycolic acid).TGA showed the percentage weight residue remain above 750℃for polymer-nano composite system was 21% and hence proved the fl...展开更多
Copper nanoparticle was synthesized in the presence of heptadecafluorononanoic acid by the conventional solution immersion method at room temperature from the copper plate, as a resource material. The bulk etching rat...Copper nanoparticle was synthesized in the presence of heptadecafluorononanoic acid by the conventional solution immersion method at room temperature from the copper plate, as a resource material. The bulk etching rate was calculated by the weight loss method. The pale green colored Cu-HDFN was characterized by Fourier transform infrared spectroscopy, UV-Visible spectroscopy, X-ray photoelectron spectroscopy, scanning electron microscopy, transmission electron microscopy and contact angle measurements and the results are critically analyzed.展开更多
The target of the present investigation is synthesis and characterization of an amphiphilic diblock copolymer with antibacterial property. Ring opening polymerization （ROP） of ε-caprolactone （CL） and tetrahydrofu...The target of the present investigation is synthesis and characterization of an amphiphilic diblock copolymer with antibacterial property. Ring opening polymerization （ROP） of ε-caprolactone （CL） and tetrahydrofuran （THF） was carried out under inert atmosphere by using L-cysteine as a bridging agent in the presence of stannous octoate （SO） as a catalyst. The nano silver end capped diblock copolymer was synthesized by in situ method. Thus obtained nano silver end capped L-cysteine bridged diblock copolymer was characterized by various analytical methods like Fourier transform infrared （FTIR） spectroscopy, nuclear magnetic resonance （NMR） spectroscopy, circular dichroism （CD）, fluorescence spectroscopy, gel permeation chromatography （GPC）, X-ray photoelectron spectroscopy （XPS）, thermogravimetric analysis （TGA）, differential scanning calorimetry （DSC）, field emission scanning electron microscopy （FESEM）, high resolution transmission electron microscopy （HRTEM） and zeta potential. The antimicrobial property of the nano silver end capped diblock copolymer against e-coli was tested.展开更多
文摘Glycolic acid was polymerized under vacuum in the presence and absence of nano sized clay.The added clay catalyzed the condensation polymerization which can be confirmed by recording FTIR spectroscopy and intrinsic viscosity (Ⅳ)values.The relative intensity of C=O/CH is increased while increasing the amount of clay.DSC showed the appearance of multiple endotherms of poly(glycolic acid).TGA showed the percentage weight residue remain above 750℃for polymer-nano composite system was 21% and hence proved the fl...
文摘Copper nanoparticle was synthesized in the presence of heptadecafluorononanoic acid by the conventional solution immersion method at room temperature from the copper plate, as a resource material. The bulk etching rate was calculated by the weight loss method. The pale green colored Cu-HDFN was characterized by Fourier transform infrared spectroscopy, UV-Visible spectroscopy, X-ray photoelectron spectroscopy, scanning electron microscopy, transmission electron microscopy and contact angle measurements and the results are critically analyzed.
文摘The target of the present investigation is synthesis and characterization of an amphiphilic diblock copolymer with antibacterial property. Ring opening polymerization （ROP） of ε-caprolactone （CL） and tetrahydrofuran （THF） was carried out under inert atmosphere by using L-cysteine as a bridging agent in the presence of stannous octoate （SO） as a catalyst. The nano silver end capped diblock copolymer was synthesized by in situ method. Thus obtained nano silver end capped L-cysteine bridged diblock copolymer was characterized by various analytical methods like Fourier transform infrared （FTIR） spectroscopy, nuclear magnetic resonance （NMR） spectroscopy, circular dichroism （CD）, fluorescence spectroscopy, gel permeation chromatography （GPC）, X-ray photoelectron spectroscopy （XPS）, thermogravimetric analysis （TGA）, differential scanning calorimetry （DSC）, field emission scanning electron microscopy （FESEM）, high resolution transmission electron microscopy （HRTEM） and zeta potential. The antimicrobial property of the nano silver end capped diblock copolymer against e-coli was tested.
