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摩尔比n(SiO2)/n(Al2O3)对发泡地质聚合物物理性能和微观结构的影响 被引量:3
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作者 芮雅峰 王栋民 +2 位作者 崔勇 袁宁 焦亚茹 《矿业科学学报》 2019年第3期261-268,共8页
使用固硫灰(CFAS)、硅灰(SF)、水玻璃(WG)、NaOH和H2O2制备发泡地质聚合物,用硅灰来调节地质聚合物的摩尔比n(SiO2)/n(Al2O3),测试新拌浆体的发泡倍数、发泡速率。对硬化后浆体进行强度和表观密度等性能的测试,结合Image-Pro Plus软件... 使用固硫灰(CFAS)、硅灰(SF)、水玻璃(WG)、NaOH和H2O2制备发泡地质聚合物,用硅灰来调节地质聚合物的摩尔比n(SiO2)/n(Al2O3),测试新拌浆体的发泡倍数、发泡速率。对硬化后浆体进行强度和表观密度等性能的测试,结合Image-Pro Plus软件分析孔径分布;通过X射线衍射(XRD)、傅里叶红外光谱(FTIR)、扫描电镜(SEM)等手段分析发泡地质聚合物的微观结构。结果表明:在试验条件下,摩尔比n(SiO2)/n(Al2O3)的提高加速了水化反应速率,适宜的摩尔比使得发泡时间提前;红外光谱波数的迁移表明,碱激发后Si—O与Al—O键发生重排,合适的摩尔比对地质聚合物的重排反应是有利的,提高了聚合度;XRD图谱显示有沸石等产物生成;当摩尔比n(SiO2)/n(Al2O3)为2.79时,试件28 d强度及表观密度分别为1.06 MPa和231 g/L,此时试件微观结构具有良好的致密性。 展开更多
关键词 摩尔比 地质聚合物 强度 孔径分布
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Living concrete with self-healing function on cracks attributed to inclusion of microorganisms: Theory, technology and engineering applications——A review 被引量:8
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作者 QIAN ChunXiang ZHENG TianWen rui yafeng 《Science China(Technological Sciences)》 SCIE EI CAS CSCD 2021年第10期2067-2083,共17页
Concrete is the most widely used composite material in civil engineering.Microbial induced calcium carbonate precipitation(MICP)is a green and environmental friendly technology,which has received extensive attention i... Concrete is the most widely used composite material in civil engineering.Microbial induced calcium carbonate precipitation(MICP)is a green and environmental friendly technology,which has received extensive attention in repair of concrete cracks.This paper introduces the research progress in Southeast University research in past 16 years.In the early stage,MICP technology of urea hydrolyzed by Bacillus pasteurii was mainly investigated to repair the surface cracks and to fill large-size cracks with grouting.However,aiming at the hidden cracks that were difficult for human intervention,a new mineralization route of Bacillus mucilaginosus was proposed,which could repair faster than Bacillus alcalophilus,and the problem of ammonia emission in the repair process of Bacillus pasteurii was also solved.In addition,in order to improve the protection of bacteria and the self-healing efficiency of the later age cracks,the methods of fiber immobilization,carrier uniformly immobilization and core-shell structural immobilization had been compared and studied.The results showed that core-shell structural immobilization had good protection ability and strong designability.What’s more,the paper also summarized the characteristics of spore germination,cell activity,nucleation and biological calcium carbonate in crack zone,and introduced the application experience of microbial self-healing concrete in water conservancy projects and subway stations. 展开更多
关键词 living concrete SELF-HEALING CRACK MICROORGANISMS engineering application
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