In the first phase of this study, the effectiveness of intrinsic bioremediation on the containment of petroleum hydrocarbons was evaluated at a gasoline spill site. Evidences of the occurrence of intrinsic bioremediat...In the first phase of this study, the effectiveness of intrinsic bioremediation on the containment of petroleum hydrocarbons was evaluated at a gasoline spill site. Evidences of the occurrence of intrinsic bioremediation within the BTEX （benzene, toluene, ethylbenzene, and xylenes） plume included （1） decreased BTEX concentrations; （2） depletion of dissolved oxygen （DO）, nitrate, and sulfate; （3） production of dissolved ferrous iron, methane, and CO2; （4） deceased pH and redox potential; and （5） increased methanogens, total heterotrophs, and total anaerobes, especially within the highly contaminated areas. In the second phase of this study, enhanced aerobic bioremediation process was applied at site to enhance the BTEX decay rates. Air was injected into the subsurface near the mid-plume area to biostimulate the naturally occurring microorganisms for BTEX biodegradation. Field results showed that enhanced bioremediation process caused the change of BTEX removal mechanisms from anaerobic biodegradation inside the plume to aerobic biodegradation. This variation could be confirmed by the following field observations inside the plume due to the enhanced aerobic bioremediation process： （1） increased in DO, CO2, redox potential, nitrate, and sulfate, （2） decreased in dissolved ferrous iron, sulfide, and methane, （3） increased total heterotrophs and decreased total anaerobes. Field results also showed that the percentage of total BTEX removal increased from 92% to 99%, and the calculated total BTEX first-order natural attenuation rates increased from 0.0092% to 0.0188% per day, respectively, after the application of enhanced bioremediation system from the spill area to the downgradient area （located approximately 300 m from the source area）.展开更多
Nanomaterials are applicable in the areas of reduction of environmental burden,reduction/treatment of industrial and agricultural wastes,and nonpoint source(NPS)pollution control.First,environmental burden reduction i...Nanomaterials are applicable in the areas of reduction of environmental burden,reduction/treatment of industrial and agricultural wastes,and nonpoint source(NPS)pollution control.First,environmental burden reduction involves green process and engineering,emissions control,desulfurization/denitrification of nonrenewable energy sources,and improvement of agriculture and food systems.Second,reduction/treatment of industrial and agricultural wastes involves converting wastes into products,groundwater remediation,adsorption,delaying photocatalysis,and nanomembranes.Third,NPS pollution control involves controlling water pollution.Nanomaterials alter physical properties on a nanoscale due to their high specific surface area to volume ratio.They are used as catalysts,adsorbents,membranes,and additives to increase activity and capability due to their high specific surface areas and nano-sized effects.Thus,nanomaterials are more effective at treating environmental wastes because they reduce the amount of material needed.展开更多
文摘In the first phase of this study, the effectiveness of intrinsic bioremediation on the containment of petroleum hydrocarbons was evaluated at a gasoline spill site. Evidences of the occurrence of intrinsic bioremediation within the BTEX （benzene, toluene, ethylbenzene, and xylenes） plume included （1） decreased BTEX concentrations; （2） depletion of dissolved oxygen （DO）, nitrate, and sulfate; （3） production of dissolved ferrous iron, methane, and CO2; （4） deceased pH and redox potential; and （5） increased methanogens, total heterotrophs, and total anaerobes, especially within the highly contaminated areas. In the second phase of this study, enhanced aerobic bioremediation process was applied at site to enhance the BTEX decay rates. Air was injected into the subsurface near the mid-plume area to biostimulate the naturally occurring microorganisms for BTEX biodegradation. Field results showed that enhanced bioremediation process caused the change of BTEX removal mechanisms from anaerobic biodegradation inside the plume to aerobic biodegradation. This variation could be confirmed by the following field observations inside the plume due to the enhanced aerobic bioremediation process： （1） increased in DO, CO2, redox potential, nitrate, and sulfate, （2） decreased in dissolved ferrous iron, sulfide, and methane, （3） increased total heterotrophs and decreased total anaerobes. Field results also showed that the percentage of total BTEX removal increased from 92% to 99%, and the calculated total BTEX first-order natural attenuation rates increased from 0.0092% to 0.0188% per day, respectively, after the application of enhanced bioremediation system from the spill area to the downgradient area （located approximately 300 m from the source area）.
文摘Nanomaterials are applicable in the areas of reduction of environmental burden,reduction/treatment of industrial and agricultural wastes,and nonpoint source(NPS)pollution control.First,environmental burden reduction involves green process and engineering,emissions control,desulfurization/denitrification of nonrenewable energy sources,and improvement of agriculture and food systems.Second,reduction/treatment of industrial and agricultural wastes involves converting wastes into products,groundwater remediation,adsorption,delaying photocatalysis,and nanomembranes.Third,NPS pollution control involves controlling water pollution.Nanomaterials alter physical properties on a nanoscale due to their high specific surface area to volume ratio.They are used as catalysts,adsorbents,membranes,and additives to increase activity and capability due to their high specific surface areas and nano-sized effects.Thus,nanomaterials are more effective at treating environmental wastes because they reduce the amount of material needed.
