Five organotin（IV） complexes, were obtained by reaction of SnR2C12 （R = Ph, Me, Bu） with ONO donor Schiff bases. The synthesized complexes have been investigated by elemental analysis and IR, 1H NMR, and ll9Sn NMR...Five organotin（IV） complexes, were obtained by reaction of SnR2C12 （R = Ph, Me, Bu） with ONO donor Schiff bases. The synthesized complexes have been investigated by elemental analysis and IR, 1H NMR, and ll9Sn NMR spectroscopy. These data show that the Schiff base acts as a tridentate dianionic ligand and coordinates via the imine nitrogen and two oxygen atoms. The X- ray crystallography of complex 4 shows a dimeric structure for this molecule. The in vitro antibacterial activities of the Schiff bases and their complexes have been evaluated against Gram-positive （Bacillus subtilis and Staphylococcus aureus） and Gram-negative （Escherichia coli and Pseudomonas aeruginosa） bacteria and compared with the standard antibacterial drugs.展开更多
基金Support of this work by Shahid Chamran University,Ahvaz,Iran is gratefully acknowledged
文摘Five organotin（IV） complexes, were obtained by reaction of SnR2C12 （R = Ph, Me, Bu） with ONO donor Schiff bases. The synthesized complexes have been investigated by elemental analysis and IR, 1H NMR, and ll9Sn NMR spectroscopy. These data show that the Schiff base acts as a tridentate dianionic ligand and coordinates via the imine nitrogen and two oxygen atoms. The X- ray crystallography of complex 4 shows a dimeric structure for this molecule. The in vitro antibacterial activities of the Schiff bases and their complexes have been evaluated against Gram-positive （Bacillus subtilis and Staphylococcus aureus） and Gram-negative （Escherichia coli and Pseudomonas aeruginosa） bacteria and compared with the standard antibacterial drugs.
