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基于简易微波方法制备高性能MoS2/石墨烯纳米复合材料用于高效析氢反应(英文) 被引量:4
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作者 Shatila Sarwar Amit Nautiyal +8 位作者 Jonathan Cook 袁一斐 李俊豪 Sunil Uprety reza shahbazian-yassar 王瑞刚 Minseo Park Michael J.Bozack 张新宇 《Science China Materials》 SCIE EI CSCD 2020年第1期62-74,共13页
用于析氢反应(HER)的低成本、高效能催化剂对于推进基于清洁氢气的能源工业非常重要.二维二硫化钼(MoS2)具有显著的催化性能,因而已被人们广泛深入研究.然而,大多数现有的合成方法耗时、复杂且效率较低.本文通过超快(60秒)微波引发的方... 用于析氢反应(HER)的低成本、高效能催化剂对于推进基于清洁氢气的能源工业非常重要.二维二硫化钼(MoS2)具有显著的催化性能,因而已被人们广泛深入研究.然而,大多数现有的合成方法耗时、复杂且效率较低.本文通过超快(60秒)微波引发的方法生产MoS2/石墨烯催化剂.石墨烯的高比表面积和导电性为MoS2纳米片的生长提供了有利的导电网络和快速电荷转移动力.文中制备的MoS2/石墨烯纳米复合材料在酸性介质中对HER表现出优异的电催化活性,具有62 mV的低起始电位,高阴极电流和43.3mV/dec的Tafel斜率.除了优异的催化活性外, MoS2/石墨烯还具有较长的循环稳定性,在250 mV的过电位下阴极电流密度高达1000 mA cm^-2.此外, MoS2/石墨烯催化剂在30–120°C范围内具有出色的HER活性和36.51 kJ mol^-1的低活化能,提供了潜在的大批量生产和制备的机会. 展开更多
关键词 析氢反应 Tafel斜率 MOS2 阴极电流密度 石墨烯 能源工业 电催化活性 电荷转移
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Nanocomposite materials in orthopedic applications 被引量:2
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作者 Mostafa R.Shirdar Nasim Farajpour +1 位作者 reza shahbazian-yassar Tolou Shokuhfar 《Frontiers of Chemical Science and Engineering》 SCIE EI CAS CSCD 2019年第1期1-13,共13页
This chapter is an introduction to nanocomposite materials and its classifications with emphasis on orthopedic application. It covers different types of matrix n anocomposites in eluding ceramics, metal, polymer and n... This chapter is an introduction to nanocomposite materials and its classifications with emphasis on orthopedic application. It covers different types of matrix n anocomposites in eluding ceramics, metal, polymer and natural-based nanocomposites with the main features and applications in the orthopedic. In addition, it presents structure, composition, and biomechanical features ofbone as a natural nanocomposite. Finally, it deliberately presents developing methods for nanocomposites bone grafting. 展开更多
关键词 NANOCOMPOSITE materials ORTHOPEDIC APPLICATIONS BONE GRAFTING NANOCOMPOSITES NANOCOMPOSITES classification
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Interfacial engineering of lithium-polymer batteries with in situ UV cross-linking
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作者 Ramin Rojaee Samuel Plunkett +3 位作者 Md Golam Rasul Meng Cheng Vahid Jabbari reza shahbazian-yassar 《InfoMat》 SCIE CAS 2021年第9期1016-1027,共12页
Developing promising solid-state Li batteries with capabilities of high current densities have been a major challenge partly due to large interfacial resistance across the electrode/electrolyte interfaces.This work re... Developing promising solid-state Li batteries with capabilities of high current densities have been a major challenge partly due to large interfacial resistance across the electrode/electrolyte interfaces.This work represents an integrated network of self-standing polymer electrolyte and active electrode materials with in situ UV cross-linking.This method provides a uniform morphology of composite polymer electrolyte with low thickness of 20-40μm.This modification leads to promising cycling results with 85%specific capacity retention in LijjLiFePO4 cell over 100 cycles at high current densities of 170 mA g1(~25μA cm^(-2),1 C).By applying this method,the interfacial resistance decreases as high as seven folds compared to noncross-linked interfaces.The following work introduce a facile and cost-effective method in developing fastcharging self-standing polymer batteries with enhanced electrochemical properties. 展开更多
关键词 electrochemical impedance spectroscopy interfacial engineering lithium batteries selfstanding polymer electrolyte
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