Two dimensional(2D) transition metal oxides and chalcogenides demonstrate a promising performance in sodium-ion batteries(SIBs) application. In this study, we investigated the use of a composite of freeze dried V_2O_5...Two dimensional(2D) transition metal oxides and chalcogenides demonstrate a promising performance in sodium-ion batteries(SIBs) application. In this study, we investigated the use of a composite of freeze dried V_2O_5·nH_2O nanosheets and multi-walled carbon nanotube(MWCNT) as a negative electrode material for SIBs. Cyclic voltammetry(CV) results indicated that a reversible sodium-ion insertion/deinsertion into the composite electrode can be obtained in the potential window of 0.1–2.5 V vs. Na^+/Na. The composite electrodes delivered sodium storage capacities of 140 and 45 m Ah g^(-1) under applied current densities of 20 and 100 m A g^(-1), respectively. The pause test during constant current measurement showed a raise in the open circuit potential(OCP) of about 0.46 V, and a charge capacity loss of ~10%. These values are comparable with those reported for hard carbon electrodes. For comparison, electrodes of freeze dried V_2O_5·nH_2O nanosheets were prepared and tested for SIBs application. The results showed that the MWCNT plays a significant role in the electrochemical performance of the composite material.展开更多
Sodium-oxygen batteries(SOBs) have the potential to provide energy densities higher than the state-ofthe-art Li-ion batteries. However, controlling the formation of sodium superoxide(NaO_(2)) as the sole discharge pro...Sodium-oxygen batteries(SOBs) have the potential to provide energy densities higher than the state-ofthe-art Li-ion batteries. However, controlling the formation of sodium superoxide(NaO_(2)) as the sole discharge product on the cathode side is crucial to achieve durable and efficient SOBs. In this work, the discharge efficiency of two graphene-based cathodes was evaluated and compared with that of a commercial gas diffusion layer. The discharge products formed at the surface of these cathodes in a glyme-based electrolyte were carefully studied using a range of characterization techniques. NaO_(2) was detected as the main discharge product regardless of the specific cathode material while small amounts of Na_(2)O_(2).2H_(2)O and carbonate-like side-products were detected by X-ray diffraction as well as by Raman and infrared spectroscopies. This work leverages the use of X-ray diffraction to determine the actual yield of NaO_(2)which is usually overlooked in this type of batteries. Thus, the proper quantification of the superoxide formed on the cathode surface is widely underestimated;even though is crucial for determining the efficiency of the battery while eliminating the parasitic chemistry in SOBs. Here, we develop an ex-situ analysis method to determine the amount of NaO_(2) generated upon discharge in SOBs by transmission X-ray diffraction and quantitative Rietveld analysis. This work unveils that the yield of NaO_(2) depends on the depth of discharge where high capacities lead to very low discharge efficiency, regardless of the used cathode. We anticipate that the methodology developed herein will provide a convenient diagnosis tool in future efforts to optimize the performance of the different cell components in SOBs.展开更多
基金the Swedish energy agency and the Swedish Research Council for Environment, Agricultural Sciences and Spatial Planning(FORMAS) for financial support
文摘Two dimensional(2D) transition metal oxides and chalcogenides demonstrate a promising performance in sodium-ion batteries(SIBs) application. In this study, we investigated the use of a composite of freeze dried V_2O_5·nH_2O nanosheets and multi-walled carbon nanotube(MWCNT) as a negative electrode material for SIBs. Cyclic voltammetry(CV) results indicated that a reversible sodium-ion insertion/deinsertion into the composite electrode can be obtained in the potential window of 0.1–2.5 V vs. Na^+/Na. The composite electrodes delivered sodium storage capacities of 140 and 45 m Ah g^(-1) under applied current densities of 20 and 100 m A g^(-1), respectively. The pause test during constant current measurement showed a raise in the open circuit potential(OCP) of about 0.46 V, and a charge capacity loss of ~10%. These values are comparable with those reported for hard carbon electrodes. For comparison, electrodes of freeze dried V_2O_5·nH_2O nanosheets were prepared and tested for SIBs application. The results showed that the MWCNT plays a significant role in the electrochemical performance of the composite material.
基金the European Union (Graphene Flagship-Core 3, Grant number 881603) for the financial support of this workfunding by the Spanish Ministerio de Ciencia,Innovación y Universidades (MICINN),Agencia Estatal de Investigación (AEI) and the European Regional Development Fund (ERDF) through project RTI2018-100832-B-I00financial support from Stand Up for Energy and the Swedish Energy Agency。
文摘Sodium-oxygen batteries(SOBs) have the potential to provide energy densities higher than the state-ofthe-art Li-ion batteries. However, controlling the formation of sodium superoxide(NaO_(2)) as the sole discharge product on the cathode side is crucial to achieve durable and efficient SOBs. In this work, the discharge efficiency of two graphene-based cathodes was evaluated and compared with that of a commercial gas diffusion layer. The discharge products formed at the surface of these cathodes in a glyme-based electrolyte were carefully studied using a range of characterization techniques. NaO_(2) was detected as the main discharge product regardless of the specific cathode material while small amounts of Na_(2)O_(2).2H_(2)O and carbonate-like side-products were detected by X-ray diffraction as well as by Raman and infrared spectroscopies. This work leverages the use of X-ray diffraction to determine the actual yield of NaO_(2)which is usually overlooked in this type of batteries. Thus, the proper quantification of the superoxide formed on the cathode surface is widely underestimated;even though is crucial for determining the efficiency of the battery while eliminating the parasitic chemistry in SOBs. Here, we develop an ex-situ analysis method to determine the amount of NaO_(2) generated upon discharge in SOBs by transmission X-ray diffraction and quantitative Rietveld analysis. This work unveils that the yield of NaO_(2) depends on the depth of discharge where high capacities lead to very low discharge efficiency, regardless of the used cathode. We anticipate that the methodology developed herein will provide a convenient diagnosis tool in future efforts to optimize the performance of the different cell components in SOBs.