In recent decades, polar regions of the planet have witnessed an increase in human presence. Antarctica is considered one of the most pristine regions of the world, but it could be affected by pollution owing to anthr...In recent decades, polar regions of the planet have witnessed an increase in human presence. Antarctica is considered one of the most pristine regions of the world, but it could be affected by pollution owing to anthropogenic activities, particularly in the Antarctic Peninsula. Human presence can increase the levels of some trace metals in Antarctic environments, an issue that needs to be evaluated. To acquire data of trace metal contamination in the Antarctic Peninsula region, concentrations （dry weight） of Cd, Pb, As, Cu, Hg and Zn in fresh excrement of Ad61ie penguins were determined by atomic absorption spectrophotometry. During the 2012/2013 austral summer, samples were collected from four important nesting sites on the Antarctic Peninsula： Arctowski Base, Kopaitic Island （both sites in the northern Antarctic Peninsula）, Yalour Island and Avian Island （both sites in the southern Antarctic Peninsula）. Data showed that Ad61ie penguin excreta had significantly higher levels （mg.kg~） of As, Cd, Hg, Pb and Cu at Arctowski Base and Kopaitic Island, both sites that have major anthropogenic activities that probably contributed to increased metal levels. The levels of trace metals in Ad61ie penguins were similar to those reported in excreta of Antarctic species in previous studies, and lower than those in excreta of other Antarctic animals. Data suggest that metals ingested by these penguin species that feed in the sea, end up in terrestrial ecosystems.展开更多
This pilot study documented the occurrence and levels of brominated flame retardants in the tissues of farmed and wild salmon in southern Chile.Samples of Coho salmon and rainbow trout were obtained from fish farms,ri...This pilot study documented the occurrence and levels of brominated flame retardants in the tissues of farmed and wild salmon in southern Chile.Samples of Coho salmon and rainbow trout were obtained from fish farms,rivers and lakes in the Patagonia in Aysen Region,Chile.The samples were analyzed by Gas Chromatography Negative Chemical Ionization Mass Spectrometry for the different polybrominated diphenyl ether（PBDE） congeners.Contaminants were observed in all the samples,and the congeners BDE 17,28,47 and 66 were observed in all both farmed and wild samples.The concentrations were higher in the farmed Coho salmon,presenting significant differences with wild salmon.The levels reached 182 pg/g wet weight（ww） vs.120 ww.In the case of the rainbow trout,the concentrations were lower,although the congener profile was quite similar.The levels reached an average of 100 pg/g ww in the farmed fish versus 110 pg/g ww in wild fish,and no significant difference was observed between the species.In both species,the congener with the highest concentration was BDE 47.Based on this information,the BDE ？ow was estimated for commerce,which is a form of pollutant transport not usually considered in POP pollution studies.A preliminary estimation indicated that the quantity of PBDEs mobilized by commerce was in the order of kg,and in the case of Chile might reach almost 1 kg.展开更多
基金supported by project INACH T 1809project FONDECYT 1140466project INACH RG 09-14
文摘In recent decades, polar regions of the planet have witnessed an increase in human presence. Antarctica is considered one of the most pristine regions of the world, but it could be affected by pollution owing to anthropogenic activities, particularly in the Antarctic Peninsula. Human presence can increase the levels of some trace metals in Antarctic environments, an issue that needs to be evaluated. To acquire data of trace metal contamination in the Antarctic Peninsula region, concentrations （dry weight） of Cd, Pb, As, Cu, Hg and Zn in fresh excrement of Ad61ie penguins were determined by atomic absorption spectrophotometry. During the 2012/2013 austral summer, samples were collected from four important nesting sites on the Antarctic Peninsula： Arctowski Base, Kopaitic Island （both sites in the northern Antarctic Peninsula）, Yalour Island and Avian Island （both sites in the southern Antarctic Peninsula）. Data showed that Ad61ie penguin excreta had significantly higher levels （mg.kg~） of As, Cd, Hg, Pb and Cu at Arctowski Base and Kopaitic Island, both sites that have major anthropogenic activities that probably contributed to increased metal levels. The levels of trace metals in Ad61ie penguins were similar to those reported in excreta of Antarctic species in previous studies, and lower than those in excreta of other Antarctic animals. Data suggest that metals ingested by these penguin species that feed in the sea, end up in terrestrial ecosystems.
基金supported by Fondecyt No. 1080294 and Fondecyt 1110719 (R Barra)
文摘This pilot study documented the occurrence and levels of brominated flame retardants in the tissues of farmed and wild salmon in southern Chile.Samples of Coho salmon and rainbow trout were obtained from fish farms,rivers and lakes in the Patagonia in Aysen Region,Chile.The samples were analyzed by Gas Chromatography Negative Chemical Ionization Mass Spectrometry for the different polybrominated diphenyl ether（PBDE） congeners.Contaminants were observed in all the samples,and the congeners BDE 17,28,47 and 66 were observed in all both farmed and wild samples.The concentrations were higher in the farmed Coho salmon,presenting significant differences with wild salmon.The levels reached 182 pg/g wet weight（ww） vs.120 ww.In the case of the rainbow trout,the concentrations were lower,although the congener profile was quite similar.The levels reached an average of 100 pg/g ww in the farmed fish versus 110 pg/g ww in wild fish,and no significant difference was observed between the species.In both species,the congener with the highest concentration was BDE 47.Based on this information,the BDE ？ow was estimated for commerce,which is a form of pollutant transport not usually considered in POP pollution studies.A preliminary estimation indicated that the quantity of PBDEs mobilized by commerce was in the order of kg,and in the case of Chile might reach almost 1 kg.
