Restricted use of hazardous environmental chemicals is one important challenge that the semiconductor industry needs to face to improve its sustainability.Ovonic threshold switching(OTS)ternary compound materials used...Restricted use of hazardous environmental chemicals is one important challenge that the semiconductor industry needs to face to improve its sustainability.Ovonic threshold switching(OTS)ternary compound materials used in memory selector devices contain As and Se.Engineering these elements out of these materials requires significant research effort.To facilitate this process,we performed systematic material screening for As/Se-free ternary materials,based on ab-initio simulations.To limit the large amount of possible chemical compositions to fewer promising candidates,we used physics-based material parameter filters like material stability,electronic properties,or change in polarizability.The OTS gauge concept is introduced as a computed parameter to estimate the probability of a material to show an OTS behavior.As a result,we identified 35 As/Se-free ternary alloy compositions for stand-alone OTS memory applications,as well as 12 compositions for RRAM selector applications.This work aims seeding the development of As/Se-free OTS materials.展开更多
基金This work was carried out in the framework of the imec Core CMOS-Active Memory Program.T.R.acknowledges the support by Research Foundation-Flanders(FWO)for providing the funding via strategic basic research PhD fellowship(grant no.1SD4721).
文摘Restricted use of hazardous environmental chemicals is one important challenge that the semiconductor industry needs to face to improve its sustainability.Ovonic threshold switching(OTS)ternary compound materials used in memory selector devices contain As and Se.Engineering these elements out of these materials requires significant research effort.To facilitate this process,we performed systematic material screening for As/Se-free ternary materials,based on ab-initio simulations.To limit the large amount of possible chemical compositions to fewer promising candidates,we used physics-based material parameter filters like material stability,electronic properties,or change in polarizability.The OTS gauge concept is introduced as a computed parameter to estimate the probability of a material to show an OTS behavior.As a result,we identified 35 As/Se-free ternary alloy compositions for stand-alone OTS memory applications,as well as 12 compositions for RRAM selector applications.This work aims seeding the development of As/Se-free OTS materials.
