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A New Quaternary Ammonium Heteropolyoxotungstate Catalyst for Propylene Epoxidation to Propylene Oxide
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作者 Ying LU Meng LI +2 位作者 rong hua zhang Zu Wei XI Shuang GAOf Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023 《Chinese Chemical Letters》 SCIE CAS CSCD 2004年第12期1491-1493,共3页
A new quatemary ammonium heteropolyoxotungstant (cat.C) is prepared andcharacterized. And the cat.C also is an reaction-controlled phase-transfer catalyst The catalyticsystem of O_2/EAHQ (2-ethylanthrahydroquinone)/ca... A new quatemary ammonium heteropolyoxotungstant (cat.C) is prepared andcharacterized. And the cat.C also is an reaction-controlled phase-transfer catalyst The catalyticsystem of O_2/EAHQ (2-ethylanthrahydroquinone)/cat.c is used for the epoxidation of propylene.Under the optimal conditions, the yield of propylene oxide based on EAHQ is 84.1%, theselectivity for propylene oxide based on propylene is 99.8% and the conversion of propylene basedon EAHQ is 84.3%. The cat.c precipitates after the epoxidation reaction for easy separation.The cat C is stable enough to be recycled three times without any loss in selectivity. 展开更多
关键词 EPOXIDATION PROPYLENE reaction-controlled phase-transfer catalyst.
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On Generalized Inverse Transversals
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作者 rong hua zhang Shou Feng WANG 《Acta Mathematica Sinica,English Series》 SCIE CSCD 2008年第7期1193-1204,共12页
Let S be a regular semigroup, S° an inverse subsemigroup of S.S° is called a generalized inverse transversal of S, if V(x)∩S°≠Ф. In this paper, some properties of this kind of semigroups are discus... Let S be a regular semigroup, S° an inverse subsemigroup of S.S° is called a generalized inverse transversal of S, if V(x)∩S°≠Ф. In this paper, some properties of this kind of semigroups are discussed. In particular, a construction theorem is obtained which contains some recent results in the literature as its special cases. 展开更多
关键词 generalized inverse transversal inverse transversal regular semigroup
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