Metal clusters exhibit diverse structures,emerging functions,and applications;thus,incorporating clusters into metal–organic frameworks(MOFs)brings tremendous merits.Although the construction of cluster-based MOFs is...Metal clusters exhibit diverse structures,emerging functions,and applications;thus,incorporating clusters into metal–organic frameworks(MOFs)brings tremendous merits.Although the construction of cluster-based MOFs is sophisticated,the reticular materials constructed from a combination of the chemistry of metal clusters and covalent organic frameworks(COFs)remain unexplored.展开更多
基金supported financially by the National Natural Science Foundation of China(nos.21731002,21975104,and 21901085)and the Guangdong Major Project of Basic and Applied Research(no.2019B030302009).G.-H.N.is thankful for the financial support from Guangdong Basic and Applied Basic Research Foundation(no.2019B151502024)Guangdong Province Pearl River Scholar Funded Scheme(2019),and the Fundamental Research Funds for the Central Universities(no.21619315).
文摘Metal clusters exhibit diverse structures,emerging functions,and applications;thus,incorporating clusters into metal–organic frameworks(MOFs)brings tremendous merits.Although the construction of cluster-based MOFs is sophisticated,the reticular materials constructed from a combination of the chemistry of metal clusters and covalent organic frameworks(COFs)remain unexplored.