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PB/ITO-PET柔性电致变色薄膜制备及性能研究 被引量:1
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作者 朱多银 金志浩 +3 位作者 李文丽 汪前雨 武荣成 崔彦斌 《过程工程学报》 CAS CSCD 北大核心 2022年第2期176-185,共10页
柔性电致变色器件具有体积小、重量轻、可弯曲等优点,在可穿戴设备、曲面显示器、节能及自适应伪装等领域具有潜在应用前景。本工作以铁氰化钾、氯化钾、无水氯化铁为原料,采用电沉积方法在ITO-PET柔性基底上沉积普鲁士蓝(PB)制得PB/ITO... 柔性电致变色器件具有体积小、重量轻、可弯曲等优点,在可穿戴设备、曲面显示器、节能及自适应伪装等领域具有潜在应用前景。本工作以铁氰化钾、氯化钾、无水氯化铁为原料,采用电沉积方法在ITO-PET柔性基底上沉积普鲁士蓝(PB)制得PB/ITO-PET电致变色薄膜,并利用扫描电子显微镜、紫外光谱仪、电化学工作站对PB/ITO-PET电致变色薄膜微观结构和电化学性能进行分析表征。结果表明,电沉积时间为200 s时得到的PB/ITO-PET电致变色薄膜在700 nm波长处光吸收率达到0.755,且PB/ITO-PET电致变色薄膜可在较低电压(0.6 V/-0.3 V)下实现着色和褪色。其光调制范围为68%,着色/褪色响应时间分别为9 s/8 s,着色效率为108 cm^(2)/C。PB/ITO-PET电致变色薄膜经1000次着色-褪色循环后光调制范围为68%,着色效率为100.3 cm^(2)/C。PB/ITO-PET电致变色薄膜500次弯曲,着色效率为105.5 cm^(2)/C,并经1000次着色-褪色循环后着色效率为91cm^(2)/C,光调制范围为65%。利用ITO-PET为离子存储层(对电极)、凝胶电解质和PB/ITO-PET为工作电极组装得到柔性电致变色器件,其光调制范围为53%,着色/褪色响应时间分别为13 s/18 s。 展开更多
关键词 电沉积 普鲁士蓝 柔性基底 电致变色薄膜 电致变色器件
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Pyrolysis characteristics of waste tire particles in fixed-bed reactor with internals 被引量:5
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作者 Shipei Xu Dengguo Lai +6 位作者 Xi Zeng Lijuan Zhang Zhennan Han Jiguang Cheng rongcheng wu Ondřej Mašek Guangwen Xu 《Carbon Resources Conversion》 2018年第3期228-237,共10页
This study investigated the characteristics of pyrolysis for waste tire particles in the newly developed fixed-bed reactor with internals that are a central gas collection channel mounted inside reactor.And a few meta... This study investigated the characteristics of pyrolysis for waste tire particles in the newly developed fixed-bed reactor with internals that are a central gas collection channel mounted inside reactor.And a few metallic plates vertically welded on the internal wall of the reactors and extending to the region closing their central gas collection pipe walls.Experiments were conducted in two laboratory fixed bed reactors with or without the internals.The results shown that employing internals produced more light oil at externally heating temperatures above 700℃due to the inhibited secondary reactions in the reactor.The oil from the reactor with internals contained more aliphatic hydrocarbons and fewer aromatic hydrocarbons,leading to its higher H/C atomic ratios as for crude petroleum oil.The char yield was relatively stable for two beds and showed the higher heating values(HHVs)of about 23 MJ/kg.The gaseous product of pyrolysis mainly consisted of H2 and CH4,but the use of internals led to less pyrolysis gas through its promotion of oil production. 展开更多
关键词 PYROLYSIS Waste tire Fixed bed INTERNALS Secondary reactions
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