The Pt(IV) complex cis,cis,trans-[Pt(PMSA)2Cl2(OH)2]·2H2O(1), where PMSA = N-3-pyridinylmethanesulfonamide, has been synthesized and characterized by elemental analysis, molar electric conductivity and IR...The Pt(IV) complex cis,cis,trans-[Pt(PMSA)2Cl2(OH)2]·2H2O(1), where PMSA = N-3-pyridinylmethanesulfonamide, has been synthesized and characterized by elemental analysis, molar electric conductivity and IR spectrum. X-ray crystallography revealed that the title compound crystallizes in the monoclinic C2/c space group with unit cell dimensions a = 16.5424(7), b = 8.6973(3), c = 16.6079(6) A, β = 117.185(5)° and Z = 4. Pt(IV) has an octahedral coordination geometry and the PMSA ligands are coordinated via the pyridine N atom. They are in a transoid orientation between each other and are inclined in the same direction with respect to the Pt-C1-Cli-N-Ni plane at an angle of 64.6(1)° (symmetry operation: (i) 1- x, y, 3/2-z). The structure is stabilized by a system of hydrogen bonds involving the complex and water molecules.展开更多
基金support of the Bulgarian National Science Fund under contract DRNF 02/1
文摘The Pt(IV) complex cis,cis,trans-[Pt(PMSA)2Cl2(OH)2]·2H2O(1), where PMSA = N-3-pyridinylmethanesulfonamide, has been synthesized and characterized by elemental analysis, molar electric conductivity and IR spectrum. X-ray crystallography revealed that the title compound crystallizes in the monoclinic C2/c space group with unit cell dimensions a = 16.5424(7), b = 8.6973(3), c = 16.6079(6) A, β = 117.185(5)° and Z = 4. Pt(IV) has an octahedral coordination geometry and the PMSA ligands are coordinated via the pyridine N atom. They are in a transoid orientation between each other and are inclined in the same direction with respect to the Pt-C1-Cli-N-Ni plane at an angle of 64.6(1)° (symmetry operation: (i) 1- x, y, 3/2-z). The structure is stabilized by a system of hydrogen bonds involving the complex and water molecules.