The rheological behavior of microparticulate structures of geopolymers was studied.The materials were developed from alternative sources of aluminosilicate and were activated in different concentrations using 5,10,and...The rheological behavior of microparticulate structures of geopolymers was studied.The materials were developed from alternative sources of aluminosilicate and were activated in different concentrations using 5,10,and 15M sodium hydroxide,and sodium silicate,which were added in a 2:1ratio (by volume).The solid constituents used were bottom ash/metakaolin and neat metakaolin in a 2:1blend. The theological characteristics were determined after 5min of homogenization and a subsequent curing of the pastes at room temperature for 28 days.The materials presented amorphous characteristics, which confirmed the formation of geopolymers.A thixotropic behavior was observed for all forrfiulations,except for bottom ash/metakaolin activated at 5M,which resulted in geopolymers with a lower intensity compared with those activated at 10 and 15M,High activator concentrations exhibited a proportional relationship for geopolymer ring growth,which resulted in a reduced structure mobility and, consequently,an increased viscosity and yield stress.The effects are more evident in the metakaolin samples,and are associated with the water content that is required for reaction.Samples that were activated with 10M sodium hydroxide presented a favorable workability and particle packing,in terms of the theological and structural aspects.展开更多
文摘The rheological behavior of microparticulate structures of geopolymers was studied.The materials were developed from alternative sources of aluminosilicate and were activated in different concentrations using 5,10,and 15M sodium hydroxide,and sodium silicate,which were added in a 2:1ratio (by volume).The solid constituents used were bottom ash/metakaolin and neat metakaolin in a 2:1blend. The theological characteristics were determined after 5min of homogenization and a subsequent curing of the pastes at room temperature for 28 days.The materials presented amorphous characteristics, which confirmed the formation of geopolymers.A thixotropic behavior was observed for all forrfiulations,except for bottom ash/metakaolin activated at 5M,which resulted in geopolymers with a lower intensity compared with those activated at 10 and 15M,High activator concentrations exhibited a proportional relationship for geopolymer ring growth,which resulted in a reduced structure mobility and, consequently,an increased viscosity and yield stress.The effects are more evident in the metakaolin samples,and are associated with the water content that is required for reaction.Samples that were activated with 10M sodium hydroxide presented a favorable workability and particle packing,in terms of the theological and structural aspects.
