A new type of ammine palladium(Ⅱ) chloride was prepared by evaporating the solution of [Pd(NH3)]4Cl2 at room temperature. Its crystal structure was refined from single-crystal X-ray data: P42/nmc, a=10.5390(10)A, c=1...A new type of ammine palladium(Ⅱ) chloride was prepared by evaporating the solution of [Pd(NH3)]4Cl2 at room temperature. Its crystal structure was refined from single-crystal X-ray data: P42/nmc, a=10.5390(10)A, c=16.905(3)A,, Z=2, and R=0.0357 for 731 structure factors and 52 variable [arameters. The framework of the title compound is composed of three sorts of structural units: [Pd(NH3)4]2+,[Pd(NH3)3Cl]+, and Cl-,of which the first kind of least squares plane exhibits distortion in some degree展开更多
文摘A new type of ammine palladium(Ⅱ) chloride was prepared by evaporating the solution of [Pd(NH3)]4Cl2 at room temperature. Its crystal structure was refined from single-crystal X-ray data: P42/nmc, a=10.5390(10)A, c=16.905(3)A,, Z=2, and R=0.0357 for 731 structure factors and 52 variable [arameters. The framework of the title compound is composed of three sorts of structural units: [Pd(NH3)4]2+,[Pd(NH3)3Cl]+, and Cl-,of which the first kind of least squares plane exhibits distortion in some degree
