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选择性还原分离和回收酸性浸出液中的碲和铋
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作者 邵丽雄 刁江 +4 位作者 胡瑞鑫 冀成庆 谭文奉 李鸿乂 谢兵 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2023年第2期596-608,共13页
提出一种用Na_(2)SO_(3)和Fe粉选择性分离和回收碲铋矿酸性浸出液中碲、铋的简单、高效方法。采用SEM-EDS、XRD、XPS和ICP-OES等手段研究碲、铋的选择性还原机理。过剩系数为16的Na_(2)SO_(3)在80℃和10 min条件下可还原99.83%的Te,粗... 提出一种用Na_(2)SO_(3)和Fe粉选择性分离和回收碲铋矿酸性浸出液中碲、铋的简单、高效方法。采用SEM-EDS、XRD、XPS和ICP-OES等手段研究碲、铋的选择性还原机理。过剩系数为16的Na_(2)SO_(3)在80℃和10 min条件下可还原99.83%的Te,粗碲品位达93.78%。此外,搅拌促进Na_(2)SO_(3)溶解,从而加速Te还原。过剩系数为7.5的Fe在60℃和40 min条件下可置换99.39%的Bi,粗铋品位达92.35%。采用循环浸出碲铋矿的方法可提高浸出液中Te(Ⅳ)和Bi(Ⅲ)的浓度并降低Fe(Ⅲ)的浓度,减少Na_(2)SO_(3)的消耗。 展开更多
关键词 选择性还原 置换 浸出液
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Solidification and heat transfer of molten steel slag particles during air quenching process 被引量:1
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作者 Wen-feng Gu Jiang Diao +4 位作者 rui-xin hu Wen-sun Ge Wen-feng Tan Hong-yi Li Bing Xie 《Journal of Iron and Steel Research International》 SCIE EI CAS CSCD 2023年第9期1834-1842,共9页
In order to effectively utilize the resources and energy of molten steel slag,the variation of precipitation phase and specific heat of air quenched steel slag(AQSS)particles during continuous cooling process was inve... In order to effectively utilize the resources and energy of molten steel slag,the variation of precipitation phase and specific heat of air quenched steel slag(AQSS)particles during continuous cooling process was investigated by FactSage and thermogravimetry differential scanning calorimetry.The cooling and solidification process of molten AQSS particles was simulated by Fluent.The microstructure changes in AQSS particles in solidification process were analyzed using an ultrahigh temperature laser confocal microscope and a scanning electron microscope.The results indicated that in the cooling process of molten AQSS particles,the precipitation of Ca_(2)Fe_(2)O_(5) resulted in the largest change of specific heat.Under the condition of slow cooling,the cooling rate is more obviously affected by specific heat.When the initial air velocity was 300 m s^(-1),there was the highest temperature difference in AQSS particles during cooling process.What is more,the compactness of the boundary region of AQSS particles was obviously better than that of its central region. 展开更多
关键词 Specific heat Air quenched steel slag COOLING SOLIDIFICATION Microstructure change
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