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高比能锂离子电池层状富锂正极材料改性策略研究进展 被引量:1
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作者 鲁航语 侯瑞林 +2 位作者 褚世勇 周豪慎 郭少华 《物理化学学报》 SCIE CAS CSCD 北大核心 2023年第7期62-78,共17页
层状富锂材料具有超过250 mAh·g-1的高可逆比容量,被认为是下一代高比能锂离子电池最具商业化前景的正极材料之一。然而,层状富锂材料在实际应用之前仍需解决诸多挑战,如高电压氧释放、层状到岩盐相的结构变化、过渡金属离子迁移... 层状富锂材料具有超过250 mAh·g-1的高可逆比容量,被认为是下一代高比能锂离子电池最具商业化前景的正极材料之一。然而,层状富锂材料在实际应用之前仍需解决诸多挑战,如高电压氧释放、层状到岩盐相的结构变化、过渡金属离子迁移等结构劣化,并由此带来了较低的初始库伦效率、电压/容量的衰减以及循环寿命的不足。针对以上问题,进行层状富锂材料改性无疑是一种行之有效的方法。本综述全面介绍了层状富锂材料的结构、组分以及电化学性能,在此基础上对材料改性策略进行了系统阐述,详细介绍了体相掺杂、表面包覆、缺陷设计、离子交换和微结构调控等一系列改性策略的现状以及发展趋势,最终提出了高容量和长循环层状富锂材料和高比能锂离子电池的设计思路。 展开更多
关键词 锂离子电池 层状富锂正极材料 电化学机制 改性策略 掺杂 包覆 缺陷设计
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User Profile in Smart Elderly Care Community:Findings from Community in Western China
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作者 Yan Wei Xiaowei Liu ruilin hou 《Journal of Beijing Institute of Technology》 EI CAS 2023年第2期156-167,共12页
With the increase in the aging population,the need for elderly care services has diversified,and smart elderly care has become an effective measure to cope with this increasing aging population.Based on the data from ... With the increase in the aging population,the need for elderly care services has diversified,and smart elderly care has become an effective measure to cope with this increasing aging population.Based on the data from the platform“Guan Hu Tong”of RQ Company in the community of Shaanxi Province in western China,this study mined the data of smart elderly care services through the recency,frequency and monetary value(RFM)model and the backpropagation(BP)neural network model,constructed the user profile of the elderly,and predicted users’practical demands.The following conclusions were drawn:The oldest users are important target users of smart elderly care service platforms;Elderly women living alone rely more on smart elderly care services;Meal delivery and health follow-up services are the most popular among elderly users. 展开更多
关键词 smart elderly care user profile backpropagation(BP)neural network
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“盐/离子液体包水”电解液用于2.8 V水系锂离子电容器 被引量:6
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作者 窦青云 王月 +7 位作者 王爱平 叶萌 侯瑞林 鲁玉兰 苏利军 施思齐 张洪章 阎兴斌 《Science Bulletin》 SCIE EI CAS CSCD 2020年第21期1812-1822,M0004,共12页
发展不可燃、高电压的电解液对未来的能源存储设备具有重要意义.水系电解液不可燃,易于操作,并且其稳定电压窗口可以通过增大浓度的方式进行拓宽.然而,由于盐在水中溶解度的限制,进一步拓宽水系电解液的电压窗口遇到了瓶颈,导致大多数... 发展不可燃、高电压的电解液对未来的能源存储设备具有重要意义.水系电解液不可燃,易于操作,并且其稳定电压窗口可以通过增大浓度的方式进行拓宽.然而,由于盐在水中溶解度的限制,进一步拓宽水系电解液的电压窗口遇到了瓶颈,导致大多数的高性能负极材料在水系电解液中很难进行可逆的氧化还原反应.本文通过在锂盐和水的体系中引入不可燃的离子液体作为共溶剂,开发了一种含水量极低的"盐/离子液体包水"电解液(WiSIL).使用该WiSIL电解液,商用五氧化二铌(Nb2O5)材料可以在较低电位下工作(-1.6 V vs.Ag/AgCl)并贡献其全部容量.而且,基于Nb2O5的锂离子电容器能够在2.8 V的电压下运行,展现出3000圈的循环稳定性.与相应的有机体系比较,该水系锂离子电容器具有相当的能量和功率密度(0.37 kw kg^-1时51.9 wh kg^-1,4.9 kw kg^-1时16.4 wh kg^-1),但安全性更高、使用更方便. 展开更多
关键词 锂离子电容器 水系电解液 负极材料 离子液体 五氧化二铌 氧化还原反应 有机体系 能源存储
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Nitrogen-doped carbon nanotubes by multistep pyrolysis process as a promising anode material for lithium ion hybrid capacitors
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作者 Juan Yang Dan Xu +4 位作者 ruilin hou Junwei Lang Zhaoli Wang Zhengping Dong Jiantai Ma 《Chinese Chemical Letters》 SCIE CAS CSCD 2020年第9期2239-2244,共6页
Lithium-ion hybrid capacitors(LIHCs) is a promising electrochemical energy storage devices which combines the advantages of lithium-ion batteries and capacitors.Herein,we developed a facile multistep pyrolysis method,... Lithium-ion hybrid capacitors(LIHCs) is a promising electrochemical energy storage devices which combines the advantages of lithium-ion batteries and capacitors.Herein,we developed a facile multistep pyrolysis method,prepared an amorphous structure and a high-level N-doping carbon nanotubes(NCNTs),and by removing the Co catalyst,opening the port of NCNTs,and using NCNTs as anode material.It is shows good performance due to the electrolyte ions enter into the electrode materials and facilitate the charge transfer.Furthermore,we employ the porous carbon material(APDC) as the cathode to couple with anodes of NCNTs,building a LIHCs,it shows a high energy density of 173 Wh/kg at 200 W/kg and still retains 53 Wh/kg at a high power density of 10 kW/kg within the voltage window of 0-4.0 V,as well as outstanding cyclic life keep 80% capacity after 5000 cycles.This work provides an opportunity for the preparation of NCNTs,that is as a promising high-performance anode for LIHCs. 展开更多
关键词 N-doping carbon nanotubes Multistep pyrolysis Anode Porous carbon Lithium ion hybrid capacitors
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