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VLS和VSS生长机制调控的单层TMD中的反向掺杂分布
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作者 田闯 肖润涵 +12 位作者 隋妍萍 冯钰涵 王浩敏 赵孙文 刘家文 高秀丽 孙浩 彭松昂 金智 刘新宇 王爽 李湃 于广辉 《Science China Materials》 SCIE EI CAS CSCD 2023年第12期4723-4732,共10页
掺杂是改善过渡金属二硫族化合物(TMD)单层薄膜性能的重要方法.然而,现有的研究大多集中在掺杂能力上,对掺杂分布的研究还处于起步阶段.近年来,基于旋涂化学气相沉积法研究了掺杂原子空间掺杂分布的差异.这些掺杂的TMD大多是通过气-液-... 掺杂是改善过渡金属二硫族化合物(TMD)单层薄膜性能的重要方法.然而,现有的研究大多集中在掺杂能力上,对掺杂分布的研究还处于起步阶段.近年来,基于旋涂化学气相沉积法研究了掺杂原子空间掺杂分布的差异.这些掺杂的TMD大多是通过气-液-固(VLS)生长机制生长的.采用气-固-固(VSS)生长机制生长的TMD尚未被用来深入研究掺杂分布.本文采用Na_(2)WO_(4),NaVO_(3),NaOH(Na-Pre),(NH_(4))_(2)WO_(4),NH_(4)VO_(3)(NH_(4)-Pre)等前驱体合成V–WS_(2).观察到中心和边缘区域完全相反的掺杂分布.还观察到浓度变化较大的界面的出现.通过透射电子显微镜精确地表征了掺杂原子的空间浓度.根据密度泛函理论的计算结果,掺杂分布的差异是由初始态引起的,这与VLS和VSS的生长机制有关.这项工作为控制掺杂原子的分布提供了一种新的方法,对掺杂TMD在微电子和纳米电子器件中的应用具有重要意义. 展开更多
关键词 transition metal dichalcogenide doping distribution vapor-liquid-solid vapor-solid-solid chemical vapor deposition
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Nondestructive visualization of graphene on Pt with methylene blue surface modification
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作者 He Kang Yanhui Zhang +11 位作者 Yun Wu Shike Hu Jing Li Zhiying Chen Yanping Sui Shuang Wang Sunwen Zhao runhan xiao Guanghui Yu Songang Peng Zhi Jin Xinyu Liu 《Science China Materials》 SCIE EI CAS CSCD 2022年第10期2763-2770,共8页
Efficient large-scale nondestructive quality assessment of graphene on Pt is essential to the in-depth growth research and practical applications of graphene.Here,we present a very simple method for directly observing... Efficient large-scale nondestructive quality assessment of graphene on Pt is essential to the in-depth growth research and practical applications of graphene.Here,we present a very simple method for directly observing the domains and defects in graphene on Pt using an ordinary optical microscope.This was achieved by modifying graphene on Pt using methylene blue(MB).Because the chemical activities of graphene and Pt surface differ significantly,the adsorption and reaction of MB on graphene and platinum surface differ.We can determine the distribution of graphene crystal domains and defects by comparing the colors in the optical images.In addition,this characterization method causes no obvious damage to the Pt substrate and graphene.Moreover,it does not affect the recycling of the substrate or the subsequent characterization or application of graphene.Our study provides a nondestructive method for measuring the quality of graphene on Pt on a large scale,as well as a reference for the characterization and doping of other two-dimensional materials. 展开更多
关键词 GRAPHENE PT nondestructive visualization surface modification methylene blue
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