To identify and establish beneficiation techniques for banded hematite quartzite （BHQ） iron ore, a comprehensive research on BHQ ore treatment was carried out. The BHQ ore was assayed as 38.9wt% Fe, 42.5wt% SiO2, an...To identify and establish beneficiation techniques for banded hematite quartzite （BHQ） iron ore, a comprehensive research on BHQ ore treatment was carried out. The BHQ ore was assayed as 38.9wt% Fe, 42.5wt% SiO2, and 1.0wt% Al2O3. In this ore, hematite and quartz are present as the major mineral phases where goethite, martite, and magnetite are present in small amounts. The liberation of hematite particles can be enhanced to about 82% by reducing the particle size to below 63 μm. The rejection of silica particles can be obtained by magnetic and flotation separation techniques. Overall, the BHQ ore can be enriched to 65.3wt% Fe at 61.9% iron recovery. A flowsheet has been suggested for the commercial exploitation of the BHQ ore.展开更多
The quality of coke affects the performance of the blast furnace, factors affecting coke quality include coal properties, coal charge granulometry and carbonization conditions. The coke properties in elude the size an...The quality of coke affects the performance of the blast furnace, factors affecting coke quality include coal properties, coal charge granulometry and carbonization conditions. The coke properties in elude the size analysis, cold strength (Micum Indices-M4(). MI0) and hot strength (Coke Reactivity Index-CRI, Coke Strength after Reaction-CSR) properties and structural properties such as coke structure and texture. Structural properties comprise the porosity, pore-cell wall thickness and pore sizes, while textures consist of the carbon forms in the coke. In present work, advanced method such as image analysis method was used to interpret coke microstructure. Conventional methods such as determination of coke porosity by measurement of real and apparent density and mercury porosimetry have a number of limitations. Coke size, magnification, number of image frames captured, process of pellet preparations and coke properties such as M4(), M|0, CRI and CSR (low, medium and high values) were taken as variables for experimental purposes. The coke structure parameters such as porosity, length, perimeter, breadth, roundness, pore-wall thickness and pore size distribution of the pores were determined by image analysis method. This method provided average porosity in addition to pore-wall thickness and pore-size distribution. The pore wall thickness measuremenl by image analysis method provided significant correlations with M40, CRI and CSR values. This explained the usability of image analysis for coke structure measurement.展开更多
Landslides are common natural hazards occurring in most parts of the world and have considerable adverse economic effects. Residual shear strength of clay is one of the most important factors in the determination of s...Landslides are common natural hazards occurring in most parts of the world and have considerable adverse economic effects. Residual shear strength of clay is one of the most important factors in the determination of stability of slopes or landslides. This effect is more pronounced in sensitive clays which show large changes in shear strength from peak to residual states. This study analyses the prediction of the residual strength of clay based on a new prediction model, functional networks（FN） using data available in the literature. The performance of FN was compared with support vector machine（SVM） and artificial neural network（ANN） based on statistical parameters like correlation coefficient（R）, Nash–Sutcliff coefficient of efficiency（E）, absolute average error（AAE）, maximum average error（MAE） and root mean square error（RMSE）. Based on R and E parameters, FN is found to be a better prediction tool than ANN for the given data. However, the R and E values for FN are less than SVM. A prediction equation is presented that can be used by practicing geotechnical engineers. A sensitivity analysis is carried out to ascertain the importance of various inputs in the prediction of the output.展开更多
Mineralogical characterization and liberation of valuable minerals are primary concerns in rnineml processing industries. The pre- sent investigation focuses on quantitative mineralogy, elemental deportment, and locki...Mineralogical characterization and liberation of valuable minerals are primary concerns in rnineml processing industries. The pre- sent investigation focuses on quantitative mineralogy, elemental deportment, and locking-liberation characteristics of the beneficiation of tailings from a chrome ore beneficiation plant in the Sukinda region, Odisha; methods used for the study of the beneficiated tailings are QEMSCAN~, X-ray diffraction （XRD）, and mineral chemistry by a scanning electron microscope equipped with an energy-dispersive spec- trometer （SEM-EDS）. The tailing sample was fine grained （69.48wt% below 45 μm size）, containing 20.25wt% Cr203 and 39.19wt% Fe203, with a Cr：Fe mass ratio of 0.51. Mineralogical investigations using QEMSCAN studies revealed that chromite, goethite, and gibbsite are the dominant mineral phases with minor amounts of hematite, kaolinite, and quartz. The sample contained 34.22wt% chromite, and chromite liberation is more than 80% for grains smaller than 250 ~tm in size. Based on these results, it was predicted that liberated chromite and high-grade middling chromite particles could be separated from the gangue by various concentration techniques. The tailing sample was beneficiated by hydrocyclone, tabling, wet high-intensity magnetic separation （WHIMS）, and flotation in order to recover the chromite. A chromite concentrate with 45.29wt% Cr203 and a Cr：Fe mass ratio of 1.85 can be produced from these low-grade chromite ore beneficiation plant rejects.展开更多
Experimental data on the pressure drop across different types of elbow for non-Newtonian pseudoplastic liquid flow in laminar condition have been presented. A generalized correlation has been developed for predicting ...Experimental data on the pressure drop across different types of elbow for non-Newtonian pseudoplastic liquid flow in laminar condition have been presented. A generalized correlation has been developed for predicting the frictional pressure drop across the elbows in the horizontal plane.展开更多
Laser induced periodic surface structures(LIPSS)represent a kind of top down approach to produce highly reproducible nano/microstructures without going for any sophisticated process of lithography.This method is much ...Laser induced periodic surface structures(LIPSS)represent a kind of top down approach to produce highly reproducible nano/microstructures without going for any sophisticated process of lithography.This method is much simpler and cost effective.In this work,LIPSS on Si surfaces were generated using femtosecond laser pulses of 800 nm wavelength.Photocatalytic substrates were prepared by depositing TiO2 thin films on top of the structured and unstructured Si wafer.The coatings were produced by sputtering from a Ti target in two different types of oxygen atmospheres.In first case,the oxygen pressure within the sputtering chamber was chosen to be high(3×10^–2 mbar)whereas it was one order of magnitude lower in second case(2.1×10^–3 mbar).In photocatalytic dye decomposition study of Methylene blue dye it was found that in the presence of LIPSS the activity can be enhanced by 2.1 and 3.3 times with high pressure and low pressure grown TiO2 thin films,respectively.The increase in photocatalytic activity is attributed to the enlargement of effective surface area.In comparative study,the dye decomposition rates of TiO2 thin films grown on LIPSS are found to be much higher than the value for standard reference thin film material Pilkington Activ^TM.展开更多
This paper reports that ferromagnetism(FM)can be induced in ferroelectric barium titanate(BaTiO_(3))ceramic with selection of appropriate substituents like Zn and Mn.High density polycrystalline samples of Zn and Mn s...This paper reports that ferromagnetism(FM)can be induced in ferroelectric barium titanate(BaTiO_(3))ceramic with selection of appropriate substituents like Zn and Mn.High density polycrystalline samples of Zn and Mn substituted BaTiO_(3)(Ba_(1-x)Zn_(x)Ti_(1-x)Mn_(x)O_(3),x=0,0.02,0.04,0.06,0.08 and 0.1)were prepared using slow step solid state sintering technique to study the effect of equiproprotional substituents on structural,ferroelectric and magnetic properties of BaTiO_(3)(BTO).High precision electrical and magnetic measurements were carried out along with XRD,XPS,and SEM to understand and co-relate magnetic and ferroelectric hysteresis loop observed at room temperature with different values of‘x’.It is seen that ferroelectric hysteresis loop(P~E)is deteriorated(became lossy type)with the increase of Zn and Mn concentration.However,at x=0.1,the material showed the signature of room temperature ferromagnetism,which is an index for BTO to became a promising material for multiferroic applications.M~H loops observed in Zn and Mn substituted BTO are expected to be due to the formation of oxygen vacancies and exchange interaction induced magnetism.展开更多
文摘To identify and establish beneficiation techniques for banded hematite quartzite （BHQ） iron ore, a comprehensive research on BHQ ore treatment was carried out. The BHQ ore was assayed as 38.9wt% Fe, 42.5wt% SiO2, and 1.0wt% Al2O3. In this ore, hematite and quartz are present as the major mineral phases where goethite, martite, and magnetite are present in small amounts. The liberation of hematite particles can be enhanced to about 82% by reducing the particle size to below 63 μm. The rejection of silica particles can be obtained by magnetic and flotation separation techniques. Overall, the BHQ ore can be enriched to 65.3wt% Fe at 61.9% iron recovery. A flowsheet has been suggested for the commercial exploitation of the BHQ ore.
文摘The quality of coke affects the performance of the blast furnace, factors affecting coke quality include coal properties, coal charge granulometry and carbonization conditions. The coke properties in elude the size analysis, cold strength (Micum Indices-M4(). MI0) and hot strength (Coke Reactivity Index-CRI, Coke Strength after Reaction-CSR) properties and structural properties such as coke structure and texture. Structural properties comprise the porosity, pore-cell wall thickness and pore sizes, while textures consist of the carbon forms in the coke. In present work, advanced method such as image analysis method was used to interpret coke microstructure. Conventional methods such as determination of coke porosity by measurement of real and apparent density and mercury porosimetry have a number of limitations. Coke size, magnification, number of image frames captured, process of pellet preparations and coke properties such as M4(), M|0, CRI and CSR (low, medium and high values) were taken as variables for experimental purposes. The coke structure parameters such as porosity, length, perimeter, breadth, roundness, pore-wall thickness and pore size distribution of the pores were determined by image analysis method. This method provided average porosity in addition to pore-wall thickness and pore-size distribution. The pore wall thickness measuremenl by image analysis method provided significant correlations with M40, CRI and CSR values. This explained the usability of image analysis for coke structure measurement.
文摘Landslides are common natural hazards occurring in most parts of the world and have considerable adverse economic effects. Residual shear strength of clay is one of the most important factors in the determination of stability of slopes or landslides. This effect is more pronounced in sensitive clays which show large changes in shear strength from peak to residual states. This study analyses the prediction of the residual strength of clay based on a new prediction model, functional networks（FN） using data available in the literature. The performance of FN was compared with support vector machine（SVM） and artificial neural network（ANN） based on statistical parameters like correlation coefficient（R）, Nash–Sutcliff coefficient of efficiency（E）, absolute average error（AAE）, maximum average error（MAE） and root mean square error（RMSE）. Based on R and E parameters, FN is found to be a better prediction tool than ANN for the given data. However, the R and E values for FN are less than SVM. A prediction equation is presented that can be used by practicing geotechnical engineers. A sensitivity analysis is carried out to ascertain the importance of various inputs in the prediction of the output.
文摘Mineralogical characterization and liberation of valuable minerals are primary concerns in rnineml processing industries. The pre- sent investigation focuses on quantitative mineralogy, elemental deportment, and locking-liberation characteristics of the beneficiation of tailings from a chrome ore beneficiation plant in the Sukinda region, Odisha; methods used for the study of the beneficiated tailings are QEMSCAN~, X-ray diffraction （XRD）, and mineral chemistry by a scanning electron microscope equipped with an energy-dispersive spec- trometer （SEM-EDS）. The tailing sample was fine grained （69.48wt% below 45 μm size）, containing 20.25wt% Cr203 and 39.19wt% Fe203, with a Cr：Fe mass ratio of 0.51. Mineralogical investigations using QEMSCAN studies revealed that chromite, goethite, and gibbsite are the dominant mineral phases with minor amounts of hematite, kaolinite, and quartz. The sample contained 34.22wt% chromite, and chromite liberation is more than 80% for grains smaller than 250 ~tm in size. Based on these results, it was predicted that liberated chromite and high-grade middling chromite particles could be separated from the gangue by various concentration techniques. The tailing sample was beneficiated by hydrocyclone, tabling, wet high-intensity magnetic separation （WHIMS）, and flotation in order to recover the chromite. A chromite concentrate with 45.29wt% Cr203 and a Cr：Fe mass ratio of 1.85 can be produced from these low-grade chromite ore beneficiation plant rejects.
文摘Experimental data on the pressure drop across different types of elbow for non-Newtonian pseudoplastic liquid flow in laminar condition have been presented. A generalized correlation has been developed for predicting the frictional pressure drop across the elbows in the horizontal plane.
基金Deutsche Forschungsgemeinschaft (DFG), Germany (Grant number GR 1782/12)Science and Engineering Research Board (SERB), India (Grant number EMR/2015/001175)
文摘Laser induced periodic surface structures(LIPSS)represent a kind of top down approach to produce highly reproducible nano/microstructures without going for any sophisticated process of lithography.This method is much simpler and cost effective.In this work,LIPSS on Si surfaces were generated using femtosecond laser pulses of 800 nm wavelength.Photocatalytic substrates were prepared by depositing TiO2 thin films on top of the structured and unstructured Si wafer.The coatings were produced by sputtering from a Ti target in two different types of oxygen atmospheres.In first case,the oxygen pressure within the sputtering chamber was chosen to be high(3×10^–2 mbar)whereas it was one order of magnitude lower in second case(2.1×10^–3 mbar).In photocatalytic dye decomposition study of Methylene blue dye it was found that in the presence of LIPSS the activity can be enhanced by 2.1 and 3.3 times with high pressure and low pressure grown TiO2 thin films,respectively.The increase in photocatalytic activity is attributed to the enlargement of effective surface area.In comparative study,the dye decomposition rates of TiO2 thin films grown on LIPSS are found to be much higher than the value for standard reference thin film material Pilkington Activ^TM.
基金Author S.K.Das acknowledges to CSIR,New Delhi for providing financial support
文摘This paper reports that ferromagnetism(FM)can be induced in ferroelectric barium titanate(BaTiO_(3))ceramic with selection of appropriate substituents like Zn and Mn.High density polycrystalline samples of Zn and Mn substituted BaTiO_(3)(Ba_(1-x)Zn_(x)Ti_(1-x)Mn_(x)O_(3),x=0,0.02,0.04,0.06,0.08 and 0.1)were prepared using slow step solid state sintering technique to study the effect of equiproprotional substituents on structural,ferroelectric and magnetic properties of BaTiO_(3)(BTO).High precision electrical and magnetic measurements were carried out along with XRD,XPS,and SEM to understand and co-relate magnetic and ferroelectric hysteresis loop observed at room temperature with different values of‘x’.It is seen that ferroelectric hysteresis loop(P~E)is deteriorated(became lossy type)with the increase of Zn and Mn concentration.However,at x=0.1,the material showed the signature of room temperature ferromagnetism,which is an index for BTO to became a promising material for multiferroic applications.M~H loops observed in Zn and Mn substituted BTO are expected to be due to the formation of oxygen vacancies and exchange interaction induced magnetism.
