Synthesis,structural and optical properties of SrZrO_3:Eu^(3+) phosphor

Eu3＋activated Sr1-xEuxZrO3 （x=0.01-0.04） phosphor with perovskite structure was successfully synthesized by using com-bustion method. The structure, morphology and optical properties of the material were characterized by X-ray diffraction, scanning electron microscopy and fluorescence spectrometry. The XRD results indicated that crystals of SrZrO3：Eu3＋belongs to tetragonal perovskite system. The phosphor could be effectively excited by UV light and the emission spectra results indicated that red-dish-orange luminescence of SrZrO3：Eu3＋due to magnetic dipole transition 5D0→7F1 at 593 nm was dominant. Thus, the prepared phosphor showed remarkable luminescent properties which find applications in field emission display （FED） and plasma display panel （PDP） devices.

Synthesis and photoluminescent performance of novel europium(Ⅲ) carboxylates with heterocyclic ancillary ligands

Five novel europium(Ⅲ)complexes with 2-[4-(dibutylamino)-2-hydroxybenzoyl]benzoic acid(DAHB)as primary ligand and bathophenanthroline(batho),2,2’-bipyridyl(bipy),5,6-dimethyl-1,10-phenanthroline(dmph),1,10-phenanthroline(phen)as ancillary ligands were syn-thesized via solution precipitation method.The structural formulae of synthesized complexes were speculated to be Eu(DABH)_(3)·2H_(2)O(C1),Eu(DABH)_(3)·batho(C2),Eu(DABH)_(3)·bipy(C3),Eu(DABH)_(3)·dmph(C4)and Eu(DABH)_(3)·phen(C5)by elemental analysis,infrared spectroscopy and proton nuclear magnetic resonance spec-troscopy(^(1)H-NMR).The photoluminescent properties and thermal stability of the complexes were investigated by photoluminescent spectroscopy and thermogravimetric analysis(TG-DTG),respectively.The Commission Inter-nationale de I’Eclairage(CIE)color coordinates,Judd–Ofelt intensity parameter(Ω_(2)),total quantum yield,intrinsic quantum efficiency and energy transfer dynamics of com-plexes were also explored.The excitation spectra of com-plexes are extended up to visible region.These complexes exhibit characteristic photoemission of Eu^(3+)metal ion with high color purity in red region attributed to efficient energy transfer from ligand to metal ion.The replacement of water molecules from coordination sphere of europium ion by ancillary ligands results in enhancement of luminescent properties of the C2–C5 complexes,indicating that ancillary ligands act as additional light harvesting centers in sensiti-zation phenomenon.The thermal studies show that these complexes are suitable for meeting the requirement of temperature for fabrication of OLEDs devices.