A new ligand,2-(2-methoxynaphthyl)-1H-imidazo[4,5-f][1,10]phenanthroline(mnipH),was synthesized by the condensation of 2-methoxy-1-naphthaldehyde and 5,6-diamino-1,10-phenanthroline.Then three ionic copper(I)complexes...A new ligand,2-(2-methoxynaphthyl)-1H-imidazo[4,5-f][1,10]phenanthroline(mnipH),was synthesized by the condensation of 2-methoxy-1-naphthaldehyde and 5,6-diamino-1,10-phenanthroline.Then three ionic copper(I)complexes were obtained through the reactions of[Cu(MeCN)4]ClO4,mnipH and the chelating diphosphine ligands with a molar ratio of 1:1:1.The photoluminescence and the corresponding luminescent mechanism of all copper(I)complexes in the solid state were investigated at room temperature.展开更多
基金supported financially by the National Natural Science Foundation of China(21271091)。
文摘A new ligand,2-(2-methoxynaphthyl)-1H-imidazo[4,5-f][1,10]phenanthroline(mnipH),was synthesized by the condensation of 2-methoxy-1-naphthaldehyde and 5,6-diamino-1,10-phenanthroline.Then three ionic copper(I)complexes were obtained through the reactions of[Cu(MeCN)4]ClO4,mnipH and the chelating diphosphine ligands with a molar ratio of 1:1:1.The photoluminescence and the corresponding luminescent mechanism of all copper(I)complexes in the solid state were investigated at room temperature.
