A three-dimensional coordination polymer,namely {[Zn2（tzba）（dmtrz）（OH）]·3H2O}n（1,H2tzba = 4-（5H-tetrazol）benzoic acid,Hdmtrz = 3,5-dimethyl-lH,l,2,4-triazole）,was hydrothermally synthesized and characte...A three-dimensional coordination polymer,namely {[Zn2（tzba）（dmtrz）（OH）]·3H2O}n（1,H2tzba = 4-（5H-tetrazol）benzoic acid,Hdmtrz = 3,5-dimethyl-lH,l,2,4-triazole）,was hydrothermally synthesized and characterized by single-crystal X-ray diffraction.It crystallizes in monoclinic system,P21/c space group with a = 8.018（11）,b = 21.04（3）,c = 11.069（14） A,β=91.26（3）°,V= 1867（4） A^3,Z = 4,Dc = 1.729 g/cm^3,F（000） = 984,μ= 2.614 mm^（-1）,R（F^2 〉 2σ（F^2）） =0.0612 and wR（F^2） = 0.1533.Topological analysis reveals that compound 1 is a（3,5）-connected structure with a Schlafli symbol of（4~2.6）（4~2.6~5.8~3）,which is a rarely observed lhh topology.In addition,the CO2 adsorption performance and luminescent property of 1 have also been studied.展开更多
文摘A three-dimensional coordination polymer,namely {[Zn2（tzba）（dmtrz）（OH）]·3H2O}n（1,H2tzba = 4-（5H-tetrazol）benzoic acid,Hdmtrz = 3,5-dimethyl-lH,l,2,4-triazole）,was hydrothermally synthesized and characterized by single-crystal X-ray diffraction.It crystallizes in monoclinic system,P21/c space group with a = 8.018（11）,b = 21.04（3）,c = 11.069（14） A,β=91.26（3）°,V= 1867（4） A^3,Z = 4,Dc = 1.729 g/cm^3,F（000） = 984,μ= 2.614 mm^（-1）,R（F^2 〉 2σ（F^2）） =0.0612 and wR（F^2） = 0.1533.Topological analysis reveals that compound 1 is a（3,5）-connected structure with a Schlafli symbol of（4~2.6）（4~2.6~5.8~3）,which is a rarely observed lhh topology.In addition,the CO2 adsorption performance and luminescent property of 1 have also been studied.
