Two new europium （Ⅲ） coordination polymers formulated as Eu2（H20）a（ox）4]· （CsH6N）2-2H20 （1） and Eu2（ad）3（H20）4]＇0.25H20 （2） （H20x = oxalic acid, H2ad = adipic acid） have been synthesized from ...Two new europium （Ⅲ） coordination polymers formulated as Eu2（H20）a（ox）4]· （CsH6N）2-2H20 （1） and Eu2（ad）3（H20）4]＇0.25H20 （2） （H20x = oxalic acid, H2ad = adipic acid） have been synthesized from the self-assembly of lanthanide ions Eu^3＋ with flexible oxalic and adipic acid ligands, respectively. Structural analyses revealed that complex 1 exhibits three-dimensional metalorganic frameworks, and 2 has intricate two-dimensional interpenetrated metal-organic networks. In addition, the photoluminescent properties of complexes 1 and 2 were discussed in detail, which shows strong red emission, corresponding to ^5Do →^7F？ transition of Eu^3＋ ions.展开更多
Two new borate compounds, C4H10N2·B6O8（OH）2 and （NH3CH2CH2NH3）B5O8 （OH）2, have been solvothermally synthesized and structurally characterized by single-crystal X-ray diffraction, IR, elemental analysis and...Two new borate compounds, C4H10N2·B6O8（OH）2 and （NH3CH2CH2NH3）B5O8 （OH）2, have been solvothermally synthesized and structurally characterized by single-crystal X-ray diffraction, IR, elemental analysis and thermal analysis. Compound 1 crystallizes in the monoclinic system, space group P21/c, with a = 8.3318（17）, b = 6.2118（12）, c = 12.479（3） A, β = 108.96（3）°, V = 610.8（2） A^3, Mr = 313.02, Z = 2, 13,.= 1.702 g/cm^,/J = 0.150 mm^-1, F（000） = 320, R = 0.0387 and wR = 0.0924. Its layered structure is linked by infinite covalently coordinated neutral sheets with 3,20-membered window system, which are built up from alternative B6O8（OH）2 subunits donated by two piperzazine nitrogen donors. 2 crystallizes in monoclinic, space group Co, with a = 6.7207（13）, b = 11.481 （2）, c = 12.564（3）A,β = 95.25（3）°, V = 965.4（3） A^3, Mr = 261.18, Z = 4, Dc = 1.797 g/cm^3,/t = 0.164 mm^-1, F（000） = 536, R = 0.0396 and wR = 0.0752. Its oxoborate structure is generated from the sheets of 3,9-membered boron rings bonded diamine molecules through electrostatic and H-bonding interactions to form a two-dimensional layered network.展开更多
基金The project was supported by the scientific and technological department of Henan Province （No. 102300410269）
文摘Two new europium （Ⅲ） coordination polymers formulated as Eu2（H20）a（ox）4]· （CsH6N）2-2H20 （1） and Eu2（ad）3（H20）4]＇0.25H20 （2） （H20x = oxalic acid, H2ad = adipic acid） have been synthesized from the self-assembly of lanthanide ions Eu^3＋ with flexible oxalic and adipic acid ligands, respectively. Structural analyses revealed that complex 1 exhibits three-dimensional metalorganic frameworks, and 2 has intricate two-dimensional interpenetrated metal-organic networks. In addition, the photoluminescent properties of complexes 1 and 2 were discussed in detail, which shows strong red emission, corresponding to ^5Do →^7F？ transition of Eu^3＋ ions.
基金the Natural Science Foundation of Henan Province (0611021600, 0311050500)the Key Discipline Foundation of Zhoukou Normal University
文摘Two new borate compounds, C4H10N2·B6O8（OH）2 and （NH3CH2CH2NH3）B5O8 （OH）2, have been solvothermally synthesized and structurally characterized by single-crystal X-ray diffraction, IR, elemental analysis and thermal analysis. Compound 1 crystallizes in the monoclinic system, space group P21/c, with a = 8.3318（17）, b = 6.2118（12）, c = 12.479（3） A, β = 108.96（3）°, V = 610.8（2） A^3, Mr = 313.02, Z = 2, 13,.= 1.702 g/cm^,/J = 0.150 mm^-1, F（000） = 320, R = 0.0387 and wR = 0.0924. Its layered structure is linked by infinite covalently coordinated neutral sheets with 3,20-membered window system, which are built up from alternative B6O8（OH）2 subunits donated by two piperzazine nitrogen donors. 2 crystallizes in monoclinic, space group Co, with a = 6.7207（13）, b = 11.481 （2）, c = 12.564（3）A,β = 95.25（3）°, V = 965.4（3） A^3, Mr = 261.18, Z = 4, Dc = 1.797 g/cm^3,/t = 0.164 mm^-1, F（000） = 536, R = 0.0396 and wR = 0.0752. Its oxoborate structure is generated from the sheets of 3,9-membered boron rings bonded diamine molecules through electrostatic and H-bonding interactions to form a two-dimensional layered network.
