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(μ-烯丙基硫)(μ-苯基硫)六碳基二铁亲核取代反应动力学的研究
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作者 陈荣悌 张启衍 +1 位作者 宋礼成 朱承越 《高等学校化学学报》 SCIE EI CAS 1985年第2期166-168,共3页
一、实验部分1.药品配合物Fe_(2)(CO)6(μ-SCH_(2)CH=CH_(2))(μ-SPh)(A)的合成及性质见参考文献[1],配体PPh2Et系参照文献[2]的方法合成,b.p.(22mmHg)=184℃,d=1.019(26℃),PPh_(3)、甲苯为分析纯。因为配合物A遇氧分解,所有操作均在... 一、实验部分1.药品配合物Fe_(2)(CO)6(μ-SCH_(2)CH=CH_(2))(μ-SPh)(A)的合成及性质见参考文献[1],配体PPh2Et系参照文献[2]的方法合成,b.p.(22mmHg)=184℃,d=1.019(26℃),PPh_(3)、甲苯为分析纯。因为配合物A遇氧分解,所有操作均在严格绝氧条件下进行。 展开更多
关键词 亲核取代反应 烯丙基 动力学 分析纯
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Geological features and hydrocarbon accumulation in the Xinken oil field,Tarim Basin 被引量:1
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作者 song lichen ZHU Guangyou +3 位作者 LIU Xingwang ZHU Yongfeng SU Jin WANG Kai 《Chinese Journal Of Geochemistry》 EI CAS CSCD 2013年第4期367-379,共13页
Recently,a large-scale Ordovician oil and gas pool has been discovered in Xinken,north of the Tarim Basin,and it has strongly heterogeneous reservoirs and complicated fluid distribution.Through analyzing oil,gas and w... Recently,a large-scale Ordovician oil and gas pool has been discovered in Xinken,north of the Tarim Basin,and it has strongly heterogeneous reservoirs and complicated fluid distribution.Through analyzing oil,gas and water samples collected from this area,in combination of field production and testing data,this study reveals that the Xinken oil pool contains dominantly normal oil characterized by low viscosity,low sulphur,and high wax.It has a low content of natural gas,which presents typical characteristics of wet gas and is oil-associated gas.Oil-gas correlation shows that the oil was from the Middle-Upper Ordovician source rocks and the charge and accumulation of oil and gas took place in the Late Hercynian Period.Controlled by paleogeomorphology,sedimentary facies,ancient karstification,faults,and other factors in the Caledonian Period,the Ordovician carbonate reservoirs are dominated by dissolved pores,cavities and fractures.The reservoir body of fractures and cavities is distributed in the shape of strip and laminate along faults and excellent reservoirs are mostly in the range of 70–100 m below the top of the Yijianfang Formation.As a whole,the Xinken oil pool is a fracture-cavity pool controlled by interbedded karst reservoirs and is a complex composed of stacked karst fractures and cavities of various sizes.It contains oil in large areas horizontally,which is quasi-laminated in distribution,and the accumulation of oil and gas is controlled by the distribution and development degree of the Ordovician carbonate reservoirs.The study shows that this area has abundant resources and a great exploration potential for oil and gas. 展开更多
关键词 塔里木盆地北部 油气成藏 地质特征 碳酸盐岩储层 石油伴生气 油田 储层控制 非均质储层
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“文强刊弱”的挑战与石油科技期刊的应对策略和实践 被引量:4
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作者 张朝军 高日丽 +2 位作者 胡苇玮 宋立臣 张敏 《中国科技期刊研究》 CSSCI 北大核心 2018年第6期546-551,共6页
【目的】探索缩短科技期刊发展缓慢与中国科技迅猛发展之间差距的策略。【方法】结合石油类学术期刊办刊实践和近年研究,对目前中国科技期刊国际化进程中的瓶颈问题进行分析,揭示"文强刊弱"的原因及负面效应,深度挖掘石油科... 【目的】探索缩短科技期刊发展缓慢与中国科技迅猛发展之间差距的策略。【方法】结合石油类学术期刊办刊实践和近年研究,对目前中国科技期刊国际化进程中的瓶颈问题进行分析,揭示"文强刊弱"的原因及负面效应,深度挖掘石油科技期刊与石油科技同步发展的应对策略和办刊经验。【结果】中文科技期刊应按照类型特色化发展,并以石油科技期刊为例指出行业权威期刊应以夯实中文办刊为基础,逐步国际化发展。【结论】科技期刊可发挥国内中文办刊优势,激发我国科学家母语创作激情,报道科技创新重大进展,弘扬工匠精神,推进科学编辑培养,把握学术动态,并以中英文双语为起步,推进"四双"办刊模式,与国家科技发展保持同步,提升期刊国际影响力,打造权威学术期刊品牌,助力国家科技创新。 展开更多
关键词 科技期刊 文刊倒挂 文强刊弱 石油期刊 中英文双语期刊 “四双”办刊
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