Nitrogen(N)-doped carbon materials as metal catalyst supports have attracted signifi cant attention,but the eff ect of N dopants on catalytic performance remains unclear,especially for complex reaction processes such ...Nitrogen(N)-doped carbon materials as metal catalyst supports have attracted signifi cant attention,but the eff ect of N dopants on catalytic performance remains unclear,especially for complex reaction processes such as Fischer-Tropsch synthesis(FTS).Herein,we engineered ruthenium(Ru)FTS catalysts supported on N-doped carbon overlayers on TiO_(2)nanoparticles.By regulating the carbonization temperatures,we successfully controlled the types and contents of N dopants to identify their impacts on metal-support interactions(MSI).Our fi ndings revealed that N dopants establish a favorable surface environment for electron transfer from the support to the Ru species.Moreover,pyridinic N demonstrates the highest electron-donating ability,followed by pyrrolic N and graphitic N.In addition to realizing excellent catalytic stability,strengthening the interaction between Ru sites and N dopants increases the Ru^(0)/Ru^(δ+)ratios to enlarge the active site numbers and surface electron density of Ru species to enhance the strength of adsorbed CO.Consequently,it improves the catalyst’s overall performance,encompassing intrinsic and apparent activities,as well as its ability for carbon chain growth.Accordingly,the as-synthesized Ru/TiO_(2)@CN-700 catalyst with abundant pyridine N dopants exhibits a superhigh C_(5+)time yield of 219.4 mol CO/(mol Ru·h)and C_(5+)selectivity of 85.5%.展开更多
Visible light(VL)plays an important role in achieving high-precision positioning and low bit error radio(BER)data communication.However,most VL-based systems can not achieve positioning and communication,simultaneousl...Visible light(VL)plays an important role in achieving high-precision positioning and low bit error radio(BER)data communication.However,most VL-based systems can not achieve positioning and communication,simultaneously.There are two problems:1)the hybrid systems are difficult to extract distinguishable positioning beacon features without affecting communication performance,2)in the hybrid systems,the lost data bits in the inter-frame gap(IFG)are hard to recover,which affects positioning and communication performance.Therefore,in this article,we propose a novel VL-based hybrid positioning and communication system,named HY-PC system,to solve the above problems.First,we propose the robust T-W mapping for recognizing specific Light Emitting Diodes(LEDs),which can provide stable LED recognition accuracy without adding extra beacon data and does not decrease the communication rate.Furthermore,we also propose the novel linear block coding and bit interleaving mechanism,which can recover the lost data bits in the IFG and improve data communication performance.Finally,we use commercial off-the-shelf devices to implement our HY-PC system,extensive experimental results show that our HY-PC system can achieve consistent high-precision positioning and low-BER data communication,simultaneously.展开更多
In visible light positioning systems,some scholars have proposed target tracking algorithms to balance the relationship among positioning accuracy,real-time performance,and robustness.However,there are still two probl...In visible light positioning systems,some scholars have proposed target tracking algorithms to balance the relationship among positioning accuracy,real-time performance,and robustness.However,there are still two problems:(1)When the captured LED disappears and the uncertain LED reappears,existing tracking algorithms may recognize the landmark in error;(2)The receiver is not always able to achieve positioning under various moving statuses.In this paper,we propose an enhanced visual target tracking algorithm to solve the above problems.First,we design the lightweight recognition/demodulation mechanism,which combines Kalman filtering with simple image preprocessing to quickly track and accurately demodulate the landmark.Then,we use the Gaussian mixture model and the LED color feature to enable the system to achieve positioning,when the receiver is under various moving statuses.Experimental results show that our system can achieve high-precision dynamic positioning and improve the system’s comprehensive performance.展开更多
基金the financial support from by the National Key Research and Development Program of China(No.2022YFB4101800)National Natural Science Foundation of China(No.22278298)Program for Introducing Talents of Discipline to Universities of China(No.BP0618007).
文摘Nitrogen(N)-doped carbon materials as metal catalyst supports have attracted signifi cant attention,but the eff ect of N dopants on catalytic performance remains unclear,especially for complex reaction processes such as Fischer-Tropsch synthesis(FTS).Herein,we engineered ruthenium(Ru)FTS catalysts supported on N-doped carbon overlayers on TiO_(2)nanoparticles.By regulating the carbonization temperatures,we successfully controlled the types and contents of N dopants to identify their impacts on metal-support interactions(MSI).Our fi ndings revealed that N dopants establish a favorable surface environment for electron transfer from the support to the Ru species.Moreover,pyridinic N demonstrates the highest electron-donating ability,followed by pyrrolic N and graphitic N.In addition to realizing excellent catalytic stability,strengthening the interaction between Ru sites and N dopants increases the Ru^(0)/Ru^(δ+)ratios to enlarge the active site numbers and surface electron density of Ru species to enhance the strength of adsorbed CO.Consequently,it improves the catalyst’s overall performance,encompassing intrinsic and apparent activities,as well as its ability for carbon chain growth.Accordingly,the as-synthesized Ru/TiO_(2)@CN-700 catalyst with abundant pyridine N dopants exhibits a superhigh C_(5+)time yield of 219.4 mol CO/(mol Ru·h)and C_(5+)selectivity of 85.5%.
基金supported by the Guangdong Basic and Applied Basic Research Foundation No.2021A1515110958National Natural Science Foundation of China No.62202215+2 种基金SYLU introduced high-level talents scientific research support planChongqing University Innovation Research Group(CXQT21019)Chongqing Talents Project(CQYC201903048)。
文摘Visible light(VL)plays an important role in achieving high-precision positioning and low bit error radio(BER)data communication.However,most VL-based systems can not achieve positioning and communication,simultaneously.There are two problems:1)the hybrid systems are difficult to extract distinguishable positioning beacon features without affecting communication performance,2)in the hybrid systems,the lost data bits in the inter-frame gap(IFG)are hard to recover,which affects positioning and communication performance.Therefore,in this article,we propose a novel VL-based hybrid positioning and communication system,named HY-PC system,to solve the above problems.First,we propose the robust T-W mapping for recognizing specific Light Emitting Diodes(LEDs),which can provide stable LED recognition accuracy without adding extra beacon data and does not decrease the communication rate.Furthermore,we also propose the novel linear block coding and bit interleaving mechanism,which can recover the lost data bits in the IFG and improve data communication performance.Finally,we use commercial off-the-shelf devices to implement our HY-PC system,extensive experimental results show that our HY-PC system can achieve consistent high-precision positioning and low-BER data communication,simultaneously.
基金supported by the Guangdong Basic and Applied Basic Research Foundation No.2021A1515110958National Natural Science Foundation of China No.62202215+1 种基金SYLU introduced high-level talents scientific research support plan,Chongqing University Innovation Research Group(CXQT21019)Chongqing Talents Project(CQYC201903048)。
文摘In visible light positioning systems,some scholars have proposed target tracking algorithms to balance the relationship among positioning accuracy,real-time performance,and robustness.However,there are still two problems:(1)When the captured LED disappears and the uncertain LED reappears,existing tracking algorithms may recognize the landmark in error;(2)The receiver is not always able to achieve positioning under various moving statuses.In this paper,we propose an enhanced visual target tracking algorithm to solve the above problems.First,we design the lightweight recognition/demodulation mechanism,which combines Kalman filtering with simple image preprocessing to quickly track and accurately demodulate the landmark.Then,we use the Gaussian mixture model and the LED color feature to enable the system to achieve positioning,when the receiver is under various moving statuses.Experimental results show that our system can achieve high-precision dynamic positioning and improve the system’s comprehensive performance.
