Assembly of Cd（Ⅱ） nitrate with a new dipyridyltriazole building block 3-（2-pyridyl）-5-（3＇-pyridyl）-1H-1,2,4-triazole（2,3＇-Hbpt） and benzoic acid（Hba） yields a new coordination compound [Cd（2,3A-bpt）（b...Assembly of Cd（Ⅱ） nitrate with a new dipyridyltriazole building block 3-（2-pyridyl）-5-（3＇-pyridyl）-1H-1,2,4-triazole（2,3＇-Hbpt） and benzoic acid（Hba） yields a new coordination compound [Cd（2,3A-bpt）（ba）（H2O）] which was characterized by single-crystal X-ray diffraction, elemental analysis, IR spectrum, TGA and XRPD analysis. Single-crystal X-ray diffraction analysis indicates that the complex belongs to triclinic system, space group P1 with a = 6.8972（6）, b = 8.8182（7）, c = 16.0484（1） A, α = 75.6330（1）, β = 85.294（2）, γ = 69.3450（1）°, V = 884.76（13） A3, Z = 2, Dc = 1.778 g/cm^3, μ = 1.276 mm-1, Mr = 473.76, F（000） = 472, the final R = 0.0380 and wR = 0.1054 with I 2σ（I）. The Cd（Ⅱ） ion is coordinated by three N-terminal atoms from two 2,3A-Hbpt ligands as well as three O-terminal atoms from ba- and lattice water forming a distorted octahedral coordinated geometry. With the lattice water as hydrogen bond donor, the structure of the title complex is linked into a 2D layer-hole structure from the 0D motif. Theoretical calculation based on density functional theory（DFT） for the ligand is also employed to explicate the stability of different conformations. Moreover, the complex exhibits strong solid state fluorescent emission at room temperature which indicates that the title complex could be a good candidate for potential photoactive materials.展开更多
A mesoporous Al-Mg composite oxide with a hexagonal structure was synthesized with aluminium nitrate and magnesium nitrate as the reagents and sodium dodecyl sulfate（SDS） as the template in the presence of ethylened...A mesoporous Al-Mg composite oxide with a hexagonal structure was synthesized with aluminium nitrate and magnesium nitrate as the reagents and sodium dodecyl sulfate（SDS） as the template in the presence of ethylenediamine. The XRD, nitrogen adsorption-desorption and TEM studies indicate that the composite has a hexagonal framework structure and an average pore diameter of 2. 6 nm. The TG/DTA spectra indicate that the decomposition and the removal of the occluded surfactant of the sample take place in a range of 230-550 ℃. The mesoporous Al-Mg composite oxide exhibites a highly catalytic activity for the oxyethylation of fatty alcohols. Narrow-range distributed ethoxylates are formed in the presence of the mesoporous Al-Mg composite oxide catalyst. The distribution selectivity coefficient（Cx） is 24 when the mesoporous Al-Mg composite oxide was used as a catalyst for the oxyethylation of octanol and the average adduct degree of ethoxylates is 6. 4.展开更多
It is given a brief introduction to formal logic in the paper,furthermore,a detail analysis on logic structure of articles is made.As a result,an scientific essay structure is designed to bridge the gap between mathem...It is given a brief introduction to formal logic in the paper,furthermore,a detail analysis on logic structure of articles is made.As a result,an scientific essay structure is designed to bridge the gap between mathematicians and reporters or writers.By the logic mathematic model,we are able to discover something valuable in writing and in reading,at least scientific research papers.展开更多
Co3O4-Ce O2 nanoparticles with increasing Co/Ce atomic ratio were prepared by wet impregnation and characterized by means of X-ray photoelectron. Co3O4 is prevalent in the samples with lower cobalt content, whereas Co...Co3O4-Ce O2 nanoparticles with increasing Co/Ce atomic ratio were prepared by wet impregnation and characterized by means of X-ray photoelectron. Co3O4 is prevalent in the samples with lower cobalt content, whereas Co3O4 is the main presence at high Co/Ce atomic ratios.Ce O2 is slightly reduced: Ce(III) is evident at the interface supported/ supporting oxide.X-ray diffraction and scanning electron microscopy allowed us to obtain interesting information concerning particle dimensions and growing morphology. New acidic/basic sites are evident on the surface of the nanocomposites; this is particularly evident in the samples with lower cobalt content.展开更多
基金Supported by the National Natural Science Foundation of China(No.21263019)the Natural Science Foundation of Ningxia(No.NZ13029)
文摘Assembly of Cd（Ⅱ） nitrate with a new dipyridyltriazole building block 3-（2-pyridyl）-5-（3＇-pyridyl）-1H-1,2,4-triazole（2,3＇-Hbpt） and benzoic acid（Hba） yields a new coordination compound [Cd（2,3A-bpt）（ba）（H2O）] which was characterized by single-crystal X-ray diffraction, elemental analysis, IR spectrum, TGA and XRPD analysis. Single-crystal X-ray diffraction analysis indicates that the complex belongs to triclinic system, space group P1 with a = 6.8972（6）, b = 8.8182（7）, c = 16.0484（1） A, α = 75.6330（1）, β = 85.294（2）, γ = 69.3450（1）°, V = 884.76（13） A3, Z = 2, Dc = 1.778 g/cm^3, μ = 1.276 mm-1, Mr = 473.76, F（000） = 472, the final R = 0.0380 and wR = 0.1054 with I 2σ（I）. The Cd（Ⅱ） ion is coordinated by three N-terminal atoms from two 2,3A-Hbpt ligands as well as three O-terminal atoms from ba- and lattice water forming a distorted octahedral coordinated geometry. With the lattice water as hydrogen bond donor, the structure of the title complex is linked into a 2D layer-hole structure from the 0D motif. Theoretical calculation based on density functional theory（DFT） for the ligand is also employed to explicate the stability of different conformations. Moreover, the complex exhibits strong solid state fluorescent emission at room temperature which indicates that the title complex could be a good candidate for potential photoactive materials.
基金Supported by the Natural Science Foundation of Heilongjiang Province(No.9810B).
文摘A mesoporous Al-Mg composite oxide with a hexagonal structure was synthesized with aluminium nitrate and magnesium nitrate as the reagents and sodium dodecyl sulfate（SDS） as the template in the presence of ethylenediamine. The XRD, nitrogen adsorption-desorption and TEM studies indicate that the composite has a hexagonal framework structure and an average pore diameter of 2. 6 nm. The TG/DTA spectra indicate that the decomposition and the removal of the occluded surfactant of the sample take place in a range of 230-550 ℃. The mesoporous Al-Mg composite oxide exhibites a highly catalytic activity for the oxyethylation of fatty alcohols. Narrow-range distributed ethoxylates are formed in the presence of the mesoporous Al-Mg composite oxide catalyst. The distribution selectivity coefficient（Cx） is 24 when the mesoporous Al-Mg composite oxide was used as a catalyst for the oxyethylation of octanol and the average adduct degree of ethoxylates is 6. 4.
文摘It is given a brief introduction to formal logic in the paper,furthermore,a detail analysis on logic structure of articles is made.As a result,an scientific essay structure is designed to bridge the gap between mathematicians and reporters or writers.By the logic mathematic model,we are able to discover something valuable in writing and in reading,at least scientific research papers.
基金support of this research by the Key Projects of the Natural Science Foundation of Heilongjiang Province (No. B201010)
文摘Co3O4-Ce O2 nanoparticles with increasing Co/Ce atomic ratio were prepared by wet impregnation and characterized by means of X-ray photoelectron. Co3O4 is prevalent in the samples with lower cobalt content, whereas Co3O4 is the main presence at high Co/Ce atomic ratios.Ce O2 is slightly reduced: Ce(III) is evident at the interface supported/ supporting oxide.X-ray diffraction and scanning electron microscopy allowed us to obtain interesting information concerning particle dimensions and growing morphology. New acidic/basic sites are evident on the surface of the nanocomposites; this is particularly evident in the samples with lower cobalt content.
