5-O-Benzoyl- 1,2-O-isopropylidene- α-D-erythro-ketofuranose-3-ulose-3-aminothiose 3 was synthesized and characterized by spectral analysis, and its crystal structure was determined by X-ray diffraction analysis. The ...5-O-Benzoyl- 1,2-O-isopropylidene- α-D-erythro-ketofuranose-3-ulose-3-aminothiose 3 was synthesized and characterized by spectral analysis, and its crystal structure was determined by X-ray diffraction analysis. The crystal belongs to orthorhombic, space group P212121 with a=6.6276（13）, b=10.993（2）, c=25.027（5）（A）, β=90°, V=1823.4（6）（A）3, Z=4, C16H20N3O5S, Mr=366.41, Dc=1.335 g/cm^3,μ=0.208 mm^-1, F（000）=772, S=1.007, the final R=0.0465 and wR=0.1061 for 3251 observed reflections （I 〉 2σ（I））. Four hydrogen bonds are observed. The absolute configuration of this molecule was confirmed by comparing with that of the original material.展开更多
基金National Natural Science Foundation of China (No. 20472075)
文摘5-O-Benzoyl- 1,2-O-isopropylidene- α-D-erythro-ketofuranose-3-ulose-3-aminothiose 3 was synthesized and characterized by spectral analysis, and its crystal structure was determined by X-ray diffraction analysis. The crystal belongs to orthorhombic, space group P212121 with a=6.6276（13）, b=10.993（2）, c=25.027（5）（A）, β=90°, V=1823.4（6）（A）3, Z=4, C16H20N3O5S, Mr=366.41, Dc=1.335 g/cm^3,μ=0.208 mm^-1, F（000）=772, S=1.007, the final R=0.0465 and wR=0.1061 for 3251 observed reflections （I 〉 2σ（I））. Four hydrogen bonds are observed. The absolute configuration of this molecule was confirmed by comparing with that of the original material.
