The reason why chlorsulfuron(2-chloro-N-[4-methoxy-6-methyl-1,3,5-triazin-2-yl)amino]carbonyl]benzenesulfonamide)bound residues can still make an in-jury to rotational crops is still kept unknown. The experiment was c...The reason why chlorsulfuron(2-chloro-N-[4-methoxy-6-methyl-1,3,5-triazin-2-yl)amino]carbonyl]benzenesulfonamide)bound residues can still make an in-jury to rotational crops is still kept unknown. The experiment was conducted under laboratory conditions to determine the dynamics of extractable and non-extractable (bound) residues of chlorsulfuron in soil, and the distribution of chlorsulfuron bound residues in organic matter fractions. The results showed that extractable 14C-residues decreased t0 25.12% of applied chlorsulfuron over an incubation period of 150 days;this in turn, the formation of bound residues increased to 47.07% of the applied. The proportions of 14C-bound residues in soil organic matter fractions increase in order of: humic acid (HA)<humin<fulvic acid(FA), most of bound residues ekisted in FA fraction, however, the amount of bound residues in humin fraction increase with incubation time. The fact that most of bound residues existed in water-soluble FA fraction is tentatively regarded as one of major reasons why 14C-chlorsulfuron bound residues can still make an injury to rotational crops.展开更多
When individual microorganisms were used to release bound pesticide residues, it was ussually not take into full account whether the autoclavingmethod could lead to the release of bound residues. The soil containing b...When individual microorganisms were used to release bound pesticide residues, it was ussually not take into full account whether the autoclavingmethod could lead to the release of bound residues. The soil containing bound 14Cchlorsulfuron residues was treated with an autoclave in this study. The results revealthat the bound 14C-chlorsulfuron residue can be released from the soil when treatedwith the autoclave and the release rate can be remarkably enhanced by adding water into the soil when subjected to such treatment. A TLC analysis showed that thereleased 14C-residue was one of the degraded products of 14C-chlorsulfuron. Afterderivatization and analysis using the GC-MS, the released 14C-residue was tentativelyidentified aS 2-amino-4-hydroXyl-6-methyl-1,3,展开更多
文摘The reason why chlorsulfuron(2-chloro-N-[4-methoxy-6-methyl-1,3,5-triazin-2-yl)amino]carbonyl]benzenesulfonamide)bound residues can still make an in-jury to rotational crops is still kept unknown. The experiment was conducted under laboratory conditions to determine the dynamics of extractable and non-extractable (bound) residues of chlorsulfuron in soil, and the distribution of chlorsulfuron bound residues in organic matter fractions. The results showed that extractable 14C-residues decreased t0 25.12% of applied chlorsulfuron over an incubation period of 150 days;this in turn, the formation of bound residues increased to 47.07% of the applied. The proportions of 14C-bound residues in soil organic matter fractions increase in order of: humic acid (HA)<humin<fulvic acid(FA), most of bound residues ekisted in FA fraction, however, the amount of bound residues in humin fraction increase with incubation time. The fact that most of bound residues existed in water-soluble FA fraction is tentatively regarded as one of major reasons why 14C-chlorsulfuron bound residues can still make an injury to rotational crops.
文摘When individual microorganisms were used to release bound pesticide residues, it was ussually not take into full account whether the autoclavingmethod could lead to the release of bound residues. The soil containing bound 14Cchlorsulfuron residues was treated with an autoclave in this study. The results revealthat the bound 14C-chlorsulfuron residue can be released from the soil when treatedwith the autoclave and the release rate can be remarkably enhanced by adding water into the soil when subjected to such treatment. A TLC analysis showed that thereleased 14C-residue was one of the degraded products of 14C-chlorsulfuron. Afterderivatization and analysis using the GC-MS, the released 14C-residue was tentativelyidentified aS 2-amino-4-hydroXyl-6-methyl-1,3,
