As one of the representatives of Anthropocene fiction, Cormac McCarthy’s The Road focuses on the protagonists’ looking for hope for living. It can be inferred when analyzed with Tönnies’ theory that a communit...As one of the representatives of Anthropocene fiction, Cormac McCarthy’s The Road focuses on the protagonists’ looking for hope for living. It can be inferred when analyzed with Tönnies’ theory that a community is constructed within the relationship between father and son, together with other characters that are involved in the narration. Accordingly, the changing process of community is demonstrated in a progressive sequence of blood-geopolitics-spirit, revealing a sense of progression in an Anthropocene context. This paper analyzes and explores the process of evolution in three dimensions reflected in the novel: construction, crisis, and the reconstruction of community. It is considered that The Road conveys powerful calls of the yearn for the survival of the individual, which can be regarded as a reflection of the human condition in reality. Meanwhile, its distinct and full-scale evolution of community process expressed in the novel also presents a referentiality to the age of Anthropocene.展开更多
The oxygen-bridged dinuclear rare earth complexes(Ln=Nd(1),Y(2))bearing N-heterocyclic olefin moieties were synthesized by treating the imidazolidinium salt[SIMes-H]Br with potassium amide and rare earth bis(trimethyl...The oxygen-bridged dinuclear rare earth complexes(Ln=Nd(1),Y(2))bearing N-heterocyclic olefin moieties were synthesized by treating the imidazolidinium salt[SIMes-H]Br with potassium amide and rare earth bis(trimethylsilyl)amides.Complex 1 was characterized by X-ray diffraction analysis and complex 2 was characterized by 1H NMR spectroscopy.Both complexes were characterized by elemental analysis.Crystal data of complex 1:C74H138O2N8Si8Nd2,Mr=1685.12,orthorhombic,space group Pbca,a=25.1105(7),b=11.9188(2),c=29.6151(7)?,V=8863.4(4)?^3,Z=4,Dc=1.263 g·cm^-3,μ=1.311 mm^-1,F(000)=3544,the final R=0.0418 and wR=0.0770 for all data.The ring-opening of tetrahydrofuran molecule was proven,the possible mechanism for the formation of N-heterocyclic olefin(NHO)-rare earth complexes was speculated and the electronic and steric properties of SIMes and rare earth amides were discussed.This work provides a better understanding of N-heterocyclic carbene rare earth chemistry.展开更多
基金This paper is an interim research finding of the 2024 institutional project of “Integration of Research and Teaching” at Jinling Institute of Technology: “Research on Individual Ethical Writing in Western Climate Novels” and the initiation project for high-level researchers at Jinling Institute of Technology: “Research on the Community Imagination in Contemporary British Climate Novels” (jit-b-202326).
文摘As one of the representatives of Anthropocene fiction, Cormac McCarthy’s The Road focuses on the protagonists’ looking for hope for living. It can be inferred when analyzed with Tönnies’ theory that a community is constructed within the relationship between father and son, together with other characters that are involved in the narration. Accordingly, the changing process of community is demonstrated in a progressive sequence of blood-geopolitics-spirit, revealing a sense of progression in an Anthropocene context. This paper analyzes and explores the process of evolution in three dimensions reflected in the novel: construction, crisis, and the reconstruction of community. It is considered that The Road conveys powerful calls of the yearn for the survival of the individual, which can be regarded as a reflection of the human condition in reality. Meanwhile, its distinct and full-scale evolution of community process expressed in the novel also presents a referentiality to the age of Anthropocene.
文摘The oxygen-bridged dinuclear rare earth complexes(Ln=Nd(1),Y(2))bearing N-heterocyclic olefin moieties were synthesized by treating the imidazolidinium salt[SIMes-H]Br with potassium amide and rare earth bis(trimethylsilyl)amides.Complex 1 was characterized by X-ray diffraction analysis and complex 2 was characterized by 1H NMR spectroscopy.Both complexes were characterized by elemental analysis.Crystal data of complex 1:C74H138O2N8Si8Nd2,Mr=1685.12,orthorhombic,space group Pbca,a=25.1105(7),b=11.9188(2),c=29.6151(7)?,V=8863.4(4)?^3,Z=4,Dc=1.263 g·cm^-3,μ=1.311 mm^-1,F(000)=3544,the final R=0.0418 and wR=0.0770 for all data.The ring-opening of tetrahydrofuran molecule was proven,the possible mechanism for the formation of N-heterocyclic olefin(NHO)-rare earth complexes was speculated and the electronic and steric properties of SIMes and rare earth amides were discussed.This work provides a better understanding of N-heterocyclic carbene rare earth chemistry.
