The complex [Zn4.5(SSA)3(CuL)3(H2O)6]n was synthesized and structurally determined, where SSA is fully deprotonated 5-sulfosalicylic acid(CuL, H2L=2,3-dioxo-5,6,14,15-dibenzo-1,4,8,12-tetraazacyclo-pentadeca- 7...The complex [Zn4.5(SSA)3(CuL)3(H2O)6]n was synthesized and structurally determined, where SSA is fully deprotonated 5-sulfosalicylic acid(CuL, H2L=2,3-dioxo-5,6,14,15-dibenzo-1,4,8,12-tetraazacyclo-pentadeca- 7,13-dien). The title complex crystallized in the triclinic system with space group P1^-, a=1.19788(17) nm, b=1.4253(2) nm, c=2.2890(4) nm, α=90.211(2)°, ,β=93.076(2)°, γ=90.600(2)°. The complex displayed a 1D ladderlike chain. All these 1D chains were further interlinked via hydrogen bonds, resulting in a 2D architecture. The luminescent property of the compound was also discussed.展开更多
基金Supported by the National Natural Science Foundation of China(Nos.20771083 and 20901059)
文摘The complex [Zn4.5(SSA)3(CuL)3(H2O)6]n was synthesized and structurally determined, where SSA is fully deprotonated 5-sulfosalicylic acid(CuL, H2L=2,3-dioxo-5,6,14,15-dibenzo-1,4,8,12-tetraazacyclo-pentadeca- 7,13-dien). The title complex crystallized in the triclinic system with space group P1^-, a=1.19788(17) nm, b=1.4253(2) nm, c=2.2890(4) nm, α=90.211(2)°, ,β=93.076(2)°, γ=90.600(2)°. The complex displayed a 1D ladderlike chain. All these 1D chains were further interlinked via hydrogen bonds, resulting in a 2D architecture. The luminescent property of the compound was also discussed.