Total 138 coal samples and 14 parting samples were taken from the No. 6 Seam of the Jungar Coalfield, Inner Mongolia. These samples were analysed by optical microscopy, sequential chemical extraction procedure （SCEP...Total 138 coal samples and 14 parting samples were taken from the No. 6 Seam of the Jungar Coalfield, Inner Mongolia. These samples were analysed by optical microscopy, sequential chemical extraction procedure （SCEP）, inductively coupled plasma mass spectrometry （ICP-MS）, X-ray powder diffraction （XRD）, and scanning electron microscope in conjunction with an energy-dispersive X-ray spectrometer （SEM-EDX） analysis. The results indicate that the Li contents have reached the industrial grade of the coal associated Li deposit, and the total Li reserves have reached 2406600 tons, that is, 5157000 tons Li2O in the No. 6 seam in the Jungar Coalfield. The sequential chemical extraction procedure results suggest that the Li concentration is mainly related to inorganic matter. The minerals in the coals consist of kaolinite, boehmite, chlorite-group mineral, quartz, calcite, pyrite, siderite and amorphous clay material. Some Li could be absorbed by clay minerals in the Li-bearing coal seam. The chlorite phase？could be？most likely the host for a part of Li. The Yinshan Oldland should be the most possible source of Li of the coal.展开更多
Samples around a coal gangue dump of the Gequan Coal Mine were collected in April 2009. GC (gas chromatography) and GC/MS (gas chromatography/mass spectrometry) were employed to analyze the composition of organic matt...Samples around a coal gangue dump of the Gequan Coal Mine were collected in April 2009. GC (gas chromatography) and GC/MS (gas chromatography/mass spectrometry) were employed to analyze the composition of organic matter in the samples. ICP-MS (inductively coupled plasma mass spectrometry) was used to determine the concentrations of heavy metals. The contents of organic extracts are within the range of 140-750 mg/kg. Alkand aro-ratios are relatively high. Compared to those of the background sample (GQ13 ), the contents of saturated hydrocarbon compounds in all the samples are relatively high. The contents of polycyclic aromatic hydrocarbons (PAHs) are relatively high with the distance getting closer to the coal gangue dump. These indicate that organic matter in the samples is from coal particles of the coal gangue dump. The distributions of heavy metals are very similar: the contents decrease with distance from the dump, which indicates that the harmful heavy metals from the coal gangue dump have polluted as thick as at least 500 m.展开更多
Total of 23 bench samples were taken from the No. 7 Coal of Iqe Coalfield, Qinghai Province, China, following Chinese Standard Method GB/T 482-2008 （2008）. These samples were analyzed by powder X-ray diffraction （...Total of 23 bench samples were taken from the No. 7 Coal of Iqe Coalfield, Qinghai Province, China, following Chinese Standard Method GB/T 482-2008 （2008）. These samples were analyzed by powder X-ray diffraction （XRD）, inductively coupled plasma mass spectrometry （ICP- MS） and X-ray fluorescence （XRF）. The results indicate that the No. 7 Coal belongs to a low rank （Ro.ran =0.659%） and high-ash coal （40.54%）. Compared to common Chinese and world low-rank coals, the lqe coal contains anomalous concentrations of rare metal elements, rare-scattered （dispersed） elements and rare earth elements. The highest contents of Rb, Cs, Ga and REY reach to 180, 26, 37, and 397 ppm, respectively. Their average contents of these elements are 10.9, 15, 4.8 and 3.5 times higher than those of world coals, respectively. Minerals in the coal include kaolinite, quartz, muscovite, siderite, and traces of rutile, and brookite. Kaolinite could be main host minerals of Rb, Cs, Ga and REY. The anomalous rare element Rb and Cs accumulation in the Iqe coal is related to both organic and inorganic matter. The REY concentrations may be related to circulation of thermal solutions, contained or sorbed by clayey particles, and organic matter as well.展开更多
Generally, sandstone-type uranium deposits can be divided into three zones according to their redox conditions: oxidized zone, ore zone and reduced zone. The Dongsheng uranium deposit belongs to this type. In order to...Generally, sandstone-type uranium deposits can be divided into three zones according to their redox conditions: oxidized zone, ore zone and reduced zone. The Dongsheng uranium deposit belongs to this type. In order to study its geochemical characteristics, 11 samples were taken from the three zones of the Dongsheng uranium deposit. Five samples of them were collected from the oxidized zone, four samples from the ore zone and two samples from the reduced zone. These samples were analyzed using organic and inorganic geochemical methods. The results of GC traces and ICP-MASS indicate that the three zones show different organic and inorganic geochemical characteristics.展开更多
Academician Dai Jinxing has long been engaged in natural gas geology and geochemical researches,and has made prominent contributions to the establishment and development of China’s theory of coal-derived gas.He has o...Academician Dai Jinxing has long been engaged in natural gas geology and geochemical researches,and has made prominent contributions to the establishment and development of China’s theory of coal-derived gas.He has opened up new areas of coal-derived gas exploration,natural gas formation theory and formation“ control conditions of large ” medium gas fields.展开更多
The most Li deposits were found in lake waters or igneous rock. In recent years, anomalous concentrations of lithium in coal have been reported by several coal geologists （Sun et al., 2010, 2012a, 2013a; Dai et al., ...The most Li deposits were found in lake waters or igneous rock. In recent years, anomalous concentrations of lithium in coal have been reported by several coal geologists （Sun et al., 2010, 2012a, 2013a; Dai et al., 2012）. Some coal geologists argued that these concentrations have economic significance （Sun et al., 2012b, 2013b, 2014）. This discovery has even been reported by Khanchuk et al. （2013） in ＂The Newsletter of Society for Organic Petrology＂, and the report was reprinted by the Geospectrum of the American Geosciences Institute （Geospectrum, 2014）. However,展开更多
The Fankou Pb-Zn deposit is a very important and famous deposit in China. The time of Pb-Zn enrichment has been debated for a long time in this deposit. A total of seventeen samples of three sections were taken from t...The Fankou Pb-Zn deposit is a very important and famous deposit in China. The time of Pb-Zn enrichment has been debated for a long time in this deposit. A total of seventeen samples of three sections were taken from the Fankou mine for the study of mineralization time and the mechanism of ore formation. The samples were analyzed by microscope, Soxhlet-extract, GC, and GC/MS methods. The results indicated that organic bulk parameters vary with the Pb-Zn contents in different samples and clearly were influenced by ore sulfide formation. Organically geochemical parameters (MPI 1, CPI) indicate that the paleotemperatures in the Fankou deposit are lower than 80℃ in all three sections. Sulfides in the wall rocks might occur mainly during synsedimentation or early diagenesis by BSR or partly by PR, rather than by TSR at such low temperatures, this stage may be the first mineralization stage. Sulfides near the faults might be formed by TSR after sedimentation, this stage may be the second mineralization stage.展开更多
Abstract: Previous studies have shown that the oxidizing brines from the Early Permian Rotliegende sequence have influences on the organic matter of Kupferschiefer. However, inside the Rotliegende sequence there are t...Abstract: Previous studies have shown that the oxidizing brines from the Early Permian Rotliegende sequence have influences on the organic matter of Kupferschiefer. However, inside the Rotliegende sequence there are two other black shales: the Lower and Upper Antracosia shales, which have not been studied as much in detail as in Kupferschiefer. In the present study 12 samples from the Lower and Upper Antracosia shales were analyzed by organic geochemical methods in order to clarify the influences of the oxidizing brines on organic matter. The results indicate that the organic matter of the samples from the Upper Antracosia shale and the bottom of the Lower Antracosia shale was oxidized under the influences of the oxidizing brines. The oxidation resulted in a depletion of saturated hydrocarbons and the alkyls of the aromatic compounds.展开更多
基金financially supported by the National Science Fundamental of China Projects(Nos.41072115 and 51174262)the project of the Science Foundation of Hebei(No.D2011402034)
文摘Total 138 coal samples and 14 parting samples were taken from the No. 6 Seam of the Jungar Coalfield, Inner Mongolia. These samples were analysed by optical microscopy, sequential chemical extraction procedure （SCEP）, inductively coupled plasma mass spectrometry （ICP-MS）, X-ray powder diffraction （XRD）, and scanning electron microscope in conjunction with an energy-dispersive X-ray spectrometer （SEM-EDX） analysis. The results indicate that the Li contents have reached the industrial grade of the coal associated Li deposit, and the total Li reserves have reached 2406600 tons, that is, 5157000 tons Li2O in the No. 6 seam in the Jungar Coalfield. The sequential chemical extraction procedure results suggest that the Li concentration is mainly related to inorganic matter. The minerals in the coals consist of kaolinite, boehmite, chlorite-group mineral, quartz, calcite, pyrite, siderite and amorphous clay material. Some Li could be absorbed by clay minerals in the Li-bearing coal seam. The chlorite phase？could be？most likely the host for a part of Li. The Yinshan Oldland should be the most possible source of Li of the coal.
基金supported by the Hebei Science Funding (D2006000625)Hebei Financial Support Plan for Science and Technology (10276701D)
文摘Samples around a coal gangue dump of the Gequan Coal Mine were collected in April 2009. GC (gas chromatography) and GC/MS (gas chromatography/mass spectrometry) were employed to analyze the composition of organic matter in the samples. ICP-MS (inductively coupled plasma mass spectrometry) was used to determine the concentrations of heavy metals. The contents of organic extracts are within the range of 140-750 mg/kg. Alkand aro-ratios are relatively high. Compared to those of the background sample (GQ13 ), the contents of saturated hydrocarbon compounds in all the samples are relatively high. The contents of polycyclic aromatic hydrocarbons (PAHs) are relatively high with the distance getting closer to the coal gangue dump. These indicate that organic matter in the samples is from coal particles of the coal gangue dump. The distributions of heavy metals are very similar: the contents decrease with distance from the dump, which indicates that the harmful heavy metals from the coal gangue dump have polluted as thick as at least 500 m.
基金supported by the China geological survey project"Qaidam Basin Oil and Gas Resources Evaluation"(Nr:([2013]4-(3),001-008)National Natural Science Foundation of China(No.41330317)
文摘Total of 23 bench samples were taken from the No. 7 Coal of Iqe Coalfield, Qinghai Province, China, following Chinese Standard Method GB/T 482-2008 （2008）. These samples were analyzed by powder X-ray diffraction （XRD）, inductively coupled plasma mass spectrometry （ICP- MS） and X-ray fluorescence （XRF）. The results indicate that the No. 7 Coal belongs to a low rank （Ro.ran =0.659%） and high-ash coal （40.54%）. Compared to common Chinese and world low-rank coals, the lqe coal contains anomalous concentrations of rare metal elements, rare-scattered （dispersed） elements and rare earth elements. The highest contents of Rb, Cs, Ga and REY reach to 180, 26, 37, and 397 ppm, respectively. Their average contents of these elements are 10.9, 15, 4.8 and 3.5 times higher than those of world coals, respectively. Minerals in the coal include kaolinite, quartz, muscovite, siderite, and traces of rutile, and brookite. Kaolinite could be main host minerals of Rb, Cs, Ga and REY. The anomalous rare element Rb and Cs accumulation in the Iqe coal is related to both organic and inorganic matter. The REY concentrations may be related to circulation of thermal solutions, contained or sorbed by clayey particles, and organic matter as well.
文摘Generally, sandstone-type uranium deposits can be divided into three zones according to their redox conditions: oxidized zone, ore zone and reduced zone. The Dongsheng uranium deposit belongs to this type. In order to study its geochemical characteristics, 11 samples were taken from the three zones of the Dongsheng uranium deposit. Five samples of them were collected from the oxidized zone, four samples from the ore zone and two samples from the reduced zone. These samples were analyzed using organic and inorganic geochemical methods. The results of GC traces and ICP-MASS indicate that the three zones show different organic and inorganic geochemical characteristics.
文摘Academician Dai Jinxing has long been engaged in natural gas geology and geochemical researches,and has made prominent contributions to the establishment and development of China’s theory of coal-derived gas.He has opened up new areas of coal-derived gas exploration,natural gas formation theory and formation“ control conditions of large ” medium gas fields.
基金financially supported by the National Science Fundamental of China Projects(Nos.41330317 and 51174262)
文摘The most Li deposits were found in lake waters or igneous rock. In recent years, anomalous concentrations of lithium in coal have been reported by several coal geologists （Sun et al., 2010, 2012a, 2013a; Dai et al., 2012）. Some coal geologists argued that these concentrations have economic significance （Sun et al., 2012b, 2013b, 2014）. This discovery has even been reported by Khanchuk et al. （2013） in ＂The Newsletter of Society for Organic Petrology＂, and the report was reprinted by the Geospectrum of the American Geosciences Institute （Geospectrum, 2014）. However,
基金support to this study by the NSFC Projects (Nos.40173004 and 40773040) is gratefully acknowledged
文摘The Fankou Pb-Zn deposit is a very important and famous deposit in China. The time of Pb-Zn enrichment has been debated for a long time in this deposit. A total of seventeen samples of three sections were taken from the Fankou mine for the study of mineralization time and the mechanism of ore formation. The samples were analyzed by microscope, Soxhlet-extract, GC, and GC/MS methods. The results indicated that organic bulk parameters vary with the Pb-Zn contents in different samples and clearly were influenced by ore sulfide formation. Organically geochemical parameters (MPI 1, CPI) indicate that the paleotemperatures in the Fankou deposit are lower than 80℃ in all three sections. Sulfides in the wall rocks might occur mainly during synsedimentation or early diagenesis by BSR or partly by PR, rather than by TSR at such low temperatures, this stage may be the first mineralization stage. Sulfides near the faults might be formed by TSR after sedimentation, this stage may be the second mineralization stage.
文摘Abstract: Previous studies have shown that the oxidizing brines from the Early Permian Rotliegende sequence have influences on the organic matter of Kupferschiefer. However, inside the Rotliegende sequence there are two other black shales: the Lower and Upper Antracosia shales, which have not been studied as much in detail as in Kupferschiefer. In the present study 12 samples from the Lower and Upper Antracosia shales were analyzed by organic geochemical methods in order to clarify the influences of the oxidizing brines on organic matter. The results indicate that the organic matter of the samples from the Upper Antracosia shale and the bottom of the Lower Antracosia shale was oxidized under the influences of the oxidizing brines. The oxidation resulted in a depletion of saturated hydrocarbons and the alkyls of the aromatic compounds.
