Study of Thermal Reactivity and Kinetics of HMX and Its PBX by Different Methods

Vacuum Stability Test(VST)was used to determine the thermal behavior and kinetic parameters of 1,3,5,7-tetranitro-1,3,5,7-tetrazocine(HMX)and its mixture with hydroxyl-terminated polybutadiene(HTPB)as a binder coded as HMX/HTPB.Model fitting and isoconversional method were applied to determine the kinetic parameters based on VST results.For comparison,non-isothermal thermogravimetry analysis data(TGA)was also used to calculate the kinetic parameters by using Kissinger,OFW(Ozawa,Flynn,and Wall)and KAS(Kissinger-Akahira-Sunose)methods.Advanced Kinetics and Technology Solution(AKTS)software was also used to determine the decomposition kinetics of the studied samples.Differential Scanning Calorimetry(DSC)was employed to determine the decomposition heat flow properties of the studied samples.Results show that the activation energies obtained using VST results is 360.1kJ/mol for pure HMX and 186.9kJ/mol for HMX/HTPB.The activation energies obtained by the three different methods using TGA results are in the range of 360-368kJ/mol for pure HMX and 190-206kJ/mol for HMX/HTPB.It is concluded that values of kinetic parameters obtained by VST are close to that obtained by the different techniques using TG/DTG results.The onset decomposition peak of HMX/HTPB is lower than that of HMX where the HTPB binder has negative effect on the thermal stability of HMX.The results of all the applied techniques prove that HMX/HTPB has lower activation energy and heat release than the pure HMX.HTPB polymeric matrix has negative effect on the kinetic parameters of HMX.