Two structurally characterized metal-cluster-centered supramolecular architectures named [Ag8（1,2-（C= C）2-C6H4）（Py[6]）（CF3CO2）6]·2.5MeOH （1） and [Ag12（1,2,4,5-（C=C）aC6H2）（Py[6]）2（CF3SO3）s]·...Two structurally characterized metal-cluster-centered supramolecular architectures named [Ag8（1,2-（C= C）2-C6H4）（Py[6]）（CF3CO2）6]·2.5MeOH （1） and [Ag12（1,2,4,5-（C=C）aC6H2）（Py[6]）2（CF3SO3）s]·4MeOH·3H2O （2） are synthesized through the interaction with a bowl-shaped macrocyclic ligand PyI61. Particularly, two dissimilar silver（I） clusters are resulted in 2 within the structure under the influence of the macrocyclic ligand Py[6]. Such dissimilarity of the silver（1） cluster is also reflected on the structural and photophysical differences between 1 and 2.展开更多
文摘Two structurally characterized metal-cluster-centered supramolecular architectures named [Ag8（1,2-（C= C）2-C6H4）（Py[6]）（CF3CO2）6]·2.5MeOH （1） and [Ag12（1,2,4,5-（C=C）aC6H2）（Py[6]）2（CF3SO3）s]·4MeOH·3H2O （2） are synthesized through the interaction with a bowl-shaped macrocyclic ligand PyI61. Particularly, two dissimilar silver（I） clusters are resulted in 2 within the structure under the influence of the macrocyclic ligand Py[6]. Such dissimilarity of the silver（1） cluster is also reflected on the structural and photophysical differences between 1 and 2.
