This review discusses the numerous routes to all-carbon quaternary centers based on the unique radical chemistry of xanthates. Itsummarizes the various approaches to the synthesis of tertiary xanthates then describes ...This review discusses the numerous routes to all-carbon quaternary centers based on the unique radical chemistry of xanthates. Itsummarizes the various approaches to the synthesis of tertiary xanthates then describes the intra- and intermolecular radicaladditions and combinations thereof that have so far been used to construct quaternary centers.展开更多
基金Ecole PolytechniqueCNRS+7 种基金DGAMNRTThe Fondation Alfred Kastlerthe Royal Commission for the Exhibition of 1851the China Research CouncilAventis(now Sanofi)Rhodia(now Solvay)Syngenta
文摘This review discusses the numerous routes to all-carbon quaternary centers based on the unique radical chemistry of xanthates. Itsummarizes the various approaches to the synthesis of tertiary xanthates then describes the intra- and intermolecular radicaladditions and combinations thereof that have so far been used to construct quaternary centers.
