Heterogeneous catalyst aluminium oxide(acidic) is found to be an effective catalyst for the solvent-free condensation reaction of indole with aldehydes in microwave irradiation with shorter reaction time and higher yi...Heterogeneous catalyst aluminium oxide(acidic) is found to be an effective catalyst for the solvent-free condensation reaction of indole with aldehydes in microwave irradiation with shorter reaction time and higher yields.展开更多
A convenient synthesis of quino[2,3-b] [ 1,5]benzoxazepines from substituted 2-chloroquinoline-3-carbaldehyde and 2-hydroxy- aniline by using stable, non-toxic and inexpensive catalyst 1,8-diazabicyclo-undecan-7-ene ...A convenient synthesis of quino[2,3-b] [ 1,5]benzoxazepines from substituted 2-chloroquinoline-3-carbaldehyde and 2-hydroxy- aniline by using stable, non-toxic and inexpensive catalyst 1,8-diazabicyclo-undecan-7-ene （DBU）/silica gel is described. This method affords the quino[2,3-b][1,5]benzoxazepines under the influence of microwave irradiation （360 W） in solvent-free conditions within short reaction times （2-3 min）, giving high yields of products （93-96%）.展开更多
文摘Heterogeneous catalyst aluminium oxide(acidic) is found to be an effective catalyst for the solvent-free condensation reaction of indole with aldehydes in microwave irradiation with shorter reaction time and higher yields.
文摘A convenient synthesis of quino[2,3-b] [ 1,5]benzoxazepines from substituted 2-chloroquinoline-3-carbaldehyde and 2-hydroxy- aniline by using stable, non-toxic and inexpensive catalyst 1,8-diazabicyclo-undecan-7-ene （DBU）/silica gel is described. This method affords the quino[2,3-b][1,5]benzoxazepines under the influence of microwave irradiation （360 W） in solvent-free conditions within short reaction times （2-3 min）, giving high yields of products （93-96%）.
