With the intensifying challenge of global warming driven largely by anthropogenic activities,effective greenhouse gas capture techniques are critical.This paper focuses on the role of deep eutectic solvents(DES)as pro...With the intensifying challenge of global warming driven largely by anthropogenic activities,effective greenhouse gas capture techniques are critical.This paper focuses on the role of deep eutectic solvents(DES)as promising agents for such capture at the source.We review the key DES-based methods for greenhouse gas capture,drawing conclusions from a thorough analysis of the existing literature.In particular,we examine the effect of DES structure on gas solubilities and explore the mechanism of gas solubility in DES through molecular simulation.We present a synthesis of state-of-the-art results in this area,assessing the potential of DES as an alternative to current industrial gas capture methods.Furthermore,we propose future research directions for the design of novel DES tailored to more specific applications.展开更多
Herein,the synthesis and characterization methods of natural deep eutectic solvents based on monoterpenoids have been presented.Low viscous fluids with suitable physicochemical properties are produced.The materials ar...Herein,the synthesis and characterization methods of natural deep eutectic solvents based on monoterpenoids have been presented.Low viscous fluids with suitable physicochemical properties are produced.The materials are non-toxic,biodegradable,and cost-effective.Thus,they can be used to develop sustainable solvents for various processes and can find their applications in various fields.A theoretical study based on quantum chemistry and classical molecular dynamics is used for the nanoscopic characterization of structure,dynamics,and hydrogen bonding.The reported results help analyze the properties of this new family of solvents.The required information for developing structure–property relationships for proper solvent design to form a sustainable chemistry framework is obtained.展开更多
基金supported by Ministerio de Ciencia,Innovaci on y Universidades(Spain,project RTI2018-101987-B-I00)European Union Next Generation EU/PRTR funds and Western Michigan University Faculty Research and Creative Activities Award(FRACAA-23-0039670)
文摘With the intensifying challenge of global warming driven largely by anthropogenic activities,effective greenhouse gas capture techniques are critical.This paper focuses on the role of deep eutectic solvents(DES)as promising agents for such capture at the source.We review the key DES-based methods for greenhouse gas capture,drawing conclusions from a thorough analysis of the existing literature.In particular,we examine the effect of DES structure on gas solubilities and explore the mechanism of gas solubility in DES through molecular simulation.We present a synthesis of state-of-the-art results in this area,assessing the potential of DES as an alternative to current industrial gas capture methods.Furthermore,we propose future research directions for the design of novel DES tailored to more specific applications.
基金funded by the Junta de Castilla y Leon(Spain,project NANOCOMP-BU058P20)the Ministerio de Ciencia,Innovación y Universidades(Spain,project RTI2018–101987-B-I00)。
文摘Herein,the synthesis and characterization methods of natural deep eutectic solvents based on monoterpenoids have been presented.Low viscous fluids with suitable physicochemical properties are produced.The materials are non-toxic,biodegradable,and cost-effective.Thus,they can be used to develop sustainable solvents for various processes and can find their applications in various fields.A theoretical study based on quantum chemistry and classical molecular dynamics is used for the nanoscopic characterization of structure,dynamics,and hydrogen bonding.The reported results help analyze the properties of this new family of solvents.The required information for developing structure–property relationships for proper solvent design to form a sustainable chemistry framework is obtained.
