Potential risk of soil irrigation with treated wastewater over 40 years:a field experiment under semi-arid conditions in northeastern Tunisia

In Tunisia,water scarcity is only adding pressure on water demand in agriculture.In the context of sustainable development goals,Tunisia has been reusing treated wastewater(TWW)as a renewable and inexpensive source for soil fertigation and groundwater(GW)recharge.However,major risks can be expected when the irrigation water is of poor quality.This study aims for evaluating the potential risk of TWW and GW irrigation on soil parameters.Accordingly,we evaluated the suitability of water quality through the analysis of major and minor cations and anions,metallic trace elements(MTEs),and the sodium hazard by using the sodium adsorption ratio(SAR)and the soluble sodium percentage(SSP).The risk of soil sodicity was further assessed by SAR and the exchangeable sodium percentage(ESP).The degree of soil pollution caused by MTEs accumulation was evaluated using geoaccumulation index(Igeo)and pollution load index(PLI).Soil maps were generated using inverse spline interpolation in ArcGIS software.The results show that both water samples(i.e.,TWW and GW)are suitable for soil irrigation in terms of salinity(electrical conductivity<7000μS/cm)and sodicity(SAR<10.00;SSP<60.00%).However,the contents of PO_(4)^(3-),Cu^(2+),and Cd^(2+)exceed the maximum threshold values set by the national and other standards.Concerning the soil samples,the average levels of SAR and ESP are within the standards(SAR<13.00;ESP<15.00%).On the other hand,PLI results reveal moderate pollution in the plot irrigated with TWW and no to moderate pollution in the plot irrigated with GW.Igeo results indicate that Cu^(2+)is the metallic trace element(MTE)with the highest risk of soil pollution in both plots(Igeo>5.00),followed by Ni^(2+)and Pb^(2+).Nevertheless,Cd^(2+)presents the lowest risk of soil pollution(Igeo<0.00).Statistical data indicates that Ca^(2+),Na+,Ni^(2+),and Pb^(2+)are highly distributed in both plots(coefficient of variation>50.0%).This study shows that the use of imagery tools,such as ArcGIS,can provide important information for evaluating the current status of soil fertility or pollution and for better managing soil irrigation with TWW.

Monitoring the variation of soil quality with sewage sludge application rates in absence of rhizosphere effect

Agricultural soils in semi-arid regions have frequently been degraded due to adverse climatic conditions,organic matter depletion,and poor farming practices.To enhance soil quality,this study examines the reuse of sewage sludge(SS)as an available source of organic matter in a typical Mediterranean sandy-loam soil.Accordingly,we studied the cumulative effect of two annual applications of 40,80 and 120 tons of sludge per ha on soil quality in absence of vegetation.The dose-dependent improvement of organic matter content was the most significant event that reflected sludge application rates,and consequently influenced other soil properties.Accordingly,soil structural stability increased by 13.3%,28.8%and 59.4%for treatments SS-40,SS-80 and SS-120 respectively as compared to unamended control.Structural stability improvement was also confirmed by the dose-dependent variation of other edaphic factors including calcium content,the microbial quotient as well as Welt and C:N ratios.These param-eters are involved in cementing soil aggregates by cation bridging,the formation of microbial mucilage,and clay-humic complexes.Soil magnetic susceptibility(SMS)was measured in situ as a possible rapid tool to evaluate soil condition.SMS showed significant correlation with sludge dose and stability amelioration testifying to the aggregation role that can play Al2O3 and particularly Fe2O3 minerals added by the hematite-rich sludge.Besides,analytical results and field observations revealed no trends of soil salinization or acidification by excessive sludge amounts.By avoiding the rhizosphere effect,outcomes could reflect the resilience and intrinsic capacity of the soil to cope with excessive sludge loads.