Since the carbon dioxide(CO_(2))capture using solid sorbent is a reversible reaction,the solid sorbent can be regenerated by the desorption process.Therefore,the desorption process is one of the key important processe...Since the carbon dioxide(CO_(2))capture using solid sorbent is a reversible reaction,the solid sorbent can be regenerated by the desorption process.Therefore,the desorption process is one of the key important processes for the CO_(2)capture system.Traditionally,most of the literature studies focus on the desorption of solid sorbent under an N_(2)atmosphere.However,the desorption process of the solid sorbent is inappropriate in the real system because the system will need another process to separate CO_(2)and nitrogen(N_(2))after the desorption process.This study focused on the CO_(2)desorption of potassium carbonate supported on gamma-alumina(K2CO3/γ-Al_(2)O_(3))in a wet fluidized bed under a steam atmosphere by using the multiphase computational fluid dynamics(CFD)simulation.The effects of water thickness and dry restitution coefficient on CO_(2)desorption rate were investigated to provide a realistic particle collision behavior and to explore their effects on CO_(2)desorption phenomena.Moreover,the effect of steam velocity on the hydrodynamic behaviors of fluidization which on CO_(2)desorption rate was studied.The simulated results demonstrated that all the parameters,water thickness,dry restitution coefficient,and steam velocity had significantly affected system hydrodynamics and CO_(2)desorption rate in the wet fluidization desorption process.Furthermore,the effect of desorption temperature on CO_(2)desorption rate was evaluated for finding the appropriate temperature for CO_(2)desorption process of K2CO3/γ-Al_(2)O_(3).The results showed that the appropriate desorption temperature for CO_(2)desorption under steam atmosphere was the temperature over 150℃.展开更多
基金supported by the National Research Council of Thailand and Chulalongkorn University for providing the Mid-Career Research Grant(NRCT5-RSA63001-24)the Research Fund from Thailand Science Research and Innovation Fund Chulalongkorn University(DIS66230001).
文摘Since the carbon dioxide(CO_(2))capture using solid sorbent is a reversible reaction,the solid sorbent can be regenerated by the desorption process.Therefore,the desorption process is one of the key important processes for the CO_(2)capture system.Traditionally,most of the literature studies focus on the desorption of solid sorbent under an N_(2)atmosphere.However,the desorption process of the solid sorbent is inappropriate in the real system because the system will need another process to separate CO_(2)and nitrogen(N_(2))after the desorption process.This study focused on the CO_(2)desorption of potassium carbonate supported on gamma-alumina(K2CO3/γ-Al_(2)O_(3))in a wet fluidized bed under a steam atmosphere by using the multiphase computational fluid dynamics(CFD)simulation.The effects of water thickness and dry restitution coefficient on CO_(2)desorption rate were investigated to provide a realistic particle collision behavior and to explore their effects on CO_(2)desorption phenomena.Moreover,the effect of steam velocity on the hydrodynamic behaviors of fluidization which on CO_(2)desorption rate was studied.The simulated results demonstrated that all the parameters,water thickness,dry restitution coefficient,and steam velocity had significantly affected system hydrodynamics and CO_(2)desorption rate in the wet fluidization desorption process.Furthermore,the effect of desorption temperature on CO_(2)desorption rate was evaluated for finding the appropriate temperature for CO_(2)desorption process of K2CO3/γ-Al_(2)O_(3).The results showed that the appropriate desorption temperature for CO_(2)desorption under steam atmosphere was the temperature over 150℃.
