Covalent organic frameworks(COFs)characterized by structural diversity,face-to-face stacking and open channels exhibit unique advantages as photothermal materials but have rarely been applied in solar-driven water eva...Covalent organic frameworks(COFs)characterized by structural diversity,face-to-face stacking and open channels exhibit unique advantages as photothermal materials but have rarely been applied in solar-driven water evaporation due to complicated framework design,tedious synthesis,and low solar-to-vapor efficiency.Herein,we report a materials design strategy to produce efficient and robust photothermal COF by anchoring nonemissive radicals to the pore surface by a[2+2]cycloaddition–retroelectrocyclization reaction.展开更多
基金supported by the National Natural Science Foundation of China(grant nos.21975078 and 51973063)the Guangdong Basic and Applied Basic Research Foundation(no.2021A1515010311)+1 种基金the Natural Science Foundation of Guangdong Province(no.2019B030301003)the 111 Project,and the Thousand Talents Plan.C.Gu and Y.Su acknowledge the scholarship support from the China Scholarship Council(grant nos.202006155049 and 202006150059).Q.X.acknowledges the financial support from the Shanghai Pujiang Program(no.19PJ1410400)and the Natural Science Foundation of Shanghai(no.20ZR1464000).Z.C.and Y.L.acknowledge the financial support of the Tip-top Scientific and Technical Innovative Youth Talents of Guangdong Special Support Program(no.2019TQ05C890),and the Pearl River S&T Nova Program of Guangzhou(no.201710010194).
文摘Covalent organic frameworks(COFs)characterized by structural diversity,face-to-face stacking and open channels exhibit unique advantages as photothermal materials but have rarely been applied in solar-driven water evaporation due to complicated framework design,tedious synthesis,and low solar-to-vapor efficiency.Herein,we report a materials design strategy to produce efficient and robust photothermal COF by anchoring nonemissive radicals to the pore surface by a[2+2]cycloaddition–retroelectrocyclization reaction.
