The leakage of organic phase change materials(OPCMs)at temperatures above their melting point severely limits their large-scale application.The introduction of porous supports has been identified as an efficient leaka...The leakage of organic phase change materials(OPCMs)at temperatures above their melting point severely limits their large-scale application.The introduction of porous supports has been identified as an efficient leakageproofing method.In this study,a novel carbonized Cu-coated melamine foam(MF)/reduced graphene oxide(rGO)framework(MF/rGO/Cu-C)is constructed as a support for fabricating stabilized multifunctional OPCMs.MF serves as the supporting material,while rGO and Cu act as functional reinforcements.As a thermal energy storage material,polyethylene glycol(PEG)is encapsulated into MF/rGO/Cu-C through a vacuum-assisted impregnation method to obtain PEG@MF/rGO/Cu-C composite with excellent comprehensive performance.PEG@MF/rGO/Cu-C exhibits high phase change enthalpies of 148.3 J g^(-1)(melting)and 143.9 J g^(-1)(crystallization),corresponding to a high energy storage capability of 92.7%.Simultaneously,MF/rGO/Cu-C endues the composite with an enhanced thermal conductivity of 0.4621Wm^(-1) K^(-1),which increases by 463%compared to that of PEG@MF.Furthermore,PEG@MF/rGO/Cu-C displays great light-to-thermal and electric-to-thermal conversion capabilities,thermal cycle stability,light-tothermal cycle stability,and shape stability,showing promising application prospects in different aspects.展开更多
基金National Natural Science Foundation of China,Grant/Award Numbers:51861005,52071092,U20A20237Guangxi Natural Science Foundation,Grant/Award Numbers:2019GXNSFDA245023,2019GXNSFGA245005,2020GXNSFGA297004,2021GXNSFFA196002Guangxi Bagui Scholar Foundation。
文摘The leakage of organic phase change materials(OPCMs)at temperatures above their melting point severely limits their large-scale application.The introduction of porous supports has been identified as an efficient leakageproofing method.In this study,a novel carbonized Cu-coated melamine foam(MF)/reduced graphene oxide(rGO)framework(MF/rGO/Cu-C)is constructed as a support for fabricating stabilized multifunctional OPCMs.MF serves as the supporting material,while rGO and Cu act as functional reinforcements.As a thermal energy storage material,polyethylene glycol(PEG)is encapsulated into MF/rGO/Cu-C through a vacuum-assisted impregnation method to obtain PEG@MF/rGO/Cu-C composite with excellent comprehensive performance.PEG@MF/rGO/Cu-C exhibits high phase change enthalpies of 148.3 J g^(-1)(melting)and 143.9 J g^(-1)(crystallization),corresponding to a high energy storage capability of 92.7%.Simultaneously,MF/rGO/Cu-C endues the composite with an enhanced thermal conductivity of 0.4621Wm^(-1) K^(-1),which increases by 463%compared to that of PEG@MF.Furthermore,PEG@MF/rGO/Cu-C displays great light-to-thermal and electric-to-thermal conversion capabilities,thermal cycle stability,light-tothermal cycle stability,and shape stability,showing promising application prospects in different aspects.
