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Three-dimensionalization via control of laser-structuring parameters for high energy and high power lithium-ion battery under various operating con ditions 被引量:1
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作者 Junsu Park Hyeongi Song +6 位作者 Inseok Jang Jaepil Lee Jeongwook Um seong-guk bae Jihun Kim Sungho Jeong Hyeong-Jin Kim 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2022年第1期93-102,I0004,共11页
Laser-structuring is an effective method to promote ion diffusion and improve the performance of lithium-ion battery(LIB)electrodes.In this work,the effects of laser structuring parameters(groove pitch and depth)on th... Laser-structuring is an effective method to promote ion diffusion and improve the performance of lithium-ion battery(LIB)electrodes.In this work,the effects of laser structuring parameters(groove pitch and depth)on the fundamental characteristics of LIB electrode,such as interfacial area,internal resistances,material loss and electrochemical performance,are investigated,LiNi_(0.5)Co_(0.2)Mn_(0.3)O_(2) cathodes were structured by a femtosecond laser by varying groove depth and pitch,which resulted in a material loss of 5%-14%and an increase of 140%-260%in the in terfacial area between electrode surface and electrolyte.It is shown that the importance of groove depth and pitch on the electrochemical performance(specific capacity and areal discharge capacity)of laser-structured electrode varies with current rates.Groove pitch is more im porta nt at low current rate but groove depth is at high curre nt rate.From the mapping of lithium concentration within the electrodes of varying groove depth and pitch by laser-induced breakdown spectroscopy,it is verified that the groove functions as a diffusion path for lithium ions.The ionic,electronic,and charge transfer resistances measured with symmetric and half cells showed that these internal resistances are differently affected by laser structuring parameters and the changes in porosity,ionic diffusion and electronic pathways.It is demonstrated that the laser structuring parameters for maximum electrode performance and minimum capacity loss should be determined in consideration of the main operating conditions of LIBs. 展开更多
关键词 Lithium-ion battery Laser structuring Energy density Power density Laser induced breakdown spectroscopy Lithium-ion diffusion
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