We report the growth process of FeTe1-xSex (0 〈 x 〈 1) monolayer films on SrTi03 (STO) substrates through molecular beam epitaxy and discuss the possible ways to improve the film quality. By exploring the parame...We report the growth process of FeTe1-xSex (0 〈 x 〈 1) monolayer films on SrTi03 (STO) substrates through molecular beam epitaxy and discuss the possible ways to improve the film quality. By exploring the parameters of substrate treatment, growth control and post growth annealing, we successfully obtain a series of FeTe1-xSex monolayer films. In the whole growth process, we find the significance of the temperature control through surface roughness monitored by the reflection high-energy electron diffraction and scanning tunneling microscopy. We obtain the best quality of FeSe monolayer films with the STO substrate treated at T = 900 950℃ before growth, the FeSe deposited at T = 310℃ during growth and annealed at T = 380℃ after growth. For FeTe1-xSex (x-1), both the growth temperature and annealing temperature decrease to T=260℃. According to the angle- resolved photoemission spectroscopy measurements, the superconductivity of the FeTe1-xSex film is robust and insensitive to Se concentration. All the above are instructive for further investigations of the superconductivity in FeTe1-xSex films.展开更多
Extremely large magnetoresistance(XMR)has been explored in many nonmagnetic topologically nontrivial/trivial semimetals,while it is experimentally ambiguous which mechanism should be responsible in a specific material...Extremely large magnetoresistance(XMR)has been explored in many nonmagnetic topologically nontrivial/trivial semimetals,while it is experimentally ambiguous which mechanism should be responsible in a specific material due to the complex electronic structures.In this paper,the magnetoresistance origin of single crystal CaAl4 with C2/m structure at low temperature is investigated,exhibiting unsaturated magnetoresistance of~3000%at 2.5 K and 14 T as the fingerprints of XMR materials.By the combination of ARPES and the first-principles calculations,we elaborate multiband features and anisotropic Fermi surfaces,which can explain the mismatch of isotropic two-band model.Although the structural phase transition from I4/mmm to C2/m has been recognized,the subtle impact on electronic structure is revealed by our ARPES measurements.Considering that both charge compensation and potential topologically nontrivial band structure exist in CaAl4,our findings report CaAl4 as a new reference material for exploring the XMR phenomena.展开更多
We performed angle-resolved photoemission spectroscopy studies on a series of FeTe_(1-x)Se_x monolayer films grown on Sr TiO_3.The superconductivity of the films is robust and rather insensitive to the variations of t...We performed angle-resolved photoemission spectroscopy studies on a series of FeTe_(1-x)Se_x monolayer films grown on Sr TiO_3.The superconductivity of the films is robust and rather insensitive to the variations of the band position and effective mass caused by the substitution of Se by Te.However,the band gap between the electron-and hole-like bands at the Brillouin zone center decreases towards band inversion and parity exchange,which drive the system to a nontrivial topological state predicted by theoretical calculations.Our results provide a clear experimental indication that the FeTe_(1-x)Se_x monolayer materials are high-temperature connate topological superconductors in which band topology and superconductivity are integrated intrinsically.展开更多
基金Supported by the Ministry of Science and Technology of China under Grant Nos 2015CB921000,2016YFA0401000,2015CB921301 and 2016YFA0300300the National Natural Science Foundation of China under Grant Nos 11274381,11574371,11274362,1190020,11334012 and 11674371
文摘We report the growth process of FeTe1-xSex (0 〈 x 〈 1) monolayer films on SrTi03 (STO) substrates through molecular beam epitaxy and discuss the possible ways to improve the film quality. By exploring the parameters of substrate treatment, growth control and post growth annealing, we successfully obtain a series of FeTe1-xSex monolayer films. In the whole growth process, we find the significance of the temperature control through surface roughness monitored by the reflection high-energy electron diffraction and scanning tunneling microscopy. We obtain the best quality of FeSe monolayer films with the STO substrate treated at T = 900 950℃ before growth, the FeSe deposited at T = 310℃ during growth and annealed at T = 380℃ after growth. For FeTe1-xSex (x-1), both the growth temperature and annealing temperature decrease to T=260℃. According to the angle- resolved photoemission spectroscopy measurements, the superconductivity of the FeTe1-xSex film is robust and insensitive to Se concentration. All the above are instructive for further investigations of the superconductivity in FeTe1-xSex films.
基金Project supported by the National Natural Science Foundation of China (Grant Nos. 11774421, 12074425, 11874422, 11574391, and 11774424)the National Key Research and Development Program of China (Grant No. 2019YFA0308602)+1 种基金the Fundamental Research Funds for the Central Universities,Chinathe Research Funds of Renmin University of China (Grant Nos. 19XNLG13, 18XNLG14, and 19XNLG18)
文摘Extremely large magnetoresistance(XMR)has been explored in many nonmagnetic topologically nontrivial/trivial semimetals,while it is experimentally ambiguous which mechanism should be responsible in a specific material due to the complex electronic structures.In this paper,the magnetoresistance origin of single crystal CaAl4 with C2/m structure at low temperature is investigated,exhibiting unsaturated magnetoresistance of~3000%at 2.5 K and 14 T as the fingerprints of XMR materials.By the combination of ARPES and the first-principles calculations,we elaborate multiband features and anisotropic Fermi surfaces,which can explain the mismatch of isotropic two-band model.Although the structural phase transition from I4/mmm to C2/m has been recognized,the subtle impact on electronic structure is revealed by our ARPES measurements.Considering that both charge compensation and potential topologically nontrivial band structure exist in CaAl4,our findings report CaAl4 as a new reference material for exploring the XMR phenomena.
基金supported by grants from the Ministry of Science and Technology of China(2015CB921000,2016YFA0401000,2015CB921301,2016YFA0300300)the National Natural Science Foundation of China(11574371,11274362,1190020,11334012,11274381,11674371)
文摘We performed angle-resolved photoemission spectroscopy studies on a series of FeTe_(1-x)Se_x monolayer films grown on Sr TiO_3.The superconductivity of the films is robust and rather insensitive to the variations of the band position and effective mass caused by the substitution of Se by Te.However,the band gap between the electron-and hole-like bands at the Brillouin zone center decreases towards band inversion and parity exchange,which drive the system to a nontrivial topological state predicted by theoretical calculations.Our results provide a clear experimental indication that the FeTe_(1-x)Se_x monolayer materials are high-temperature connate topological superconductors in which band topology and superconductivity are integrated intrinsically.