Water-soluble Mn (Ⅲ)-porphyrins supported on various carriers as monooxygenase—like catalysts were used for n—Hexane hydroxylation by PhIO. The hydroxylation yields and XPS measurement of the catalysts indicate tha...Water-soluble Mn (Ⅲ)-porphyrins supported on various carriers as monooxygenase—like catalysts were used for n—Hexane hydroxylation by PhIO. The hydroxylation yields and XPS measurement of the catalysts indicate that the carriers containing—OH groups have favorable steric and electronic effect on Mn—porphyrins. Some influencing factors and the role of carriers are discussed.展开更多
文摘Water-soluble Mn (Ⅲ)-porphyrins supported on various carriers as monooxygenase—like catalysts were used for n—Hexane hydroxylation by PhIO. The hydroxylation yields and XPS measurement of the catalysts indicate that the carriers containing—OH groups have favorable steric and electronic effect on Mn—porphyrins. Some influencing factors and the role of carriers are discussed.
