The RHT technology and the second generation RHT catalysts were applied in design of an 1.7Mt/a VRDS unit at the SINOPEC Changling Branch Co. The commercial application result demonstrated that the RHT catalysts showe...The RHT technology and the second generation RHT catalysts were applied in design of an 1.7Mt/a VRDS unit at the SINOPEC Changling Branch Co. The commercial application result demonstrated that the RHT catalysts showed good activity and stability in processing low-sulfur and high-nitrogen residue. The first long period run of unit for processing high Fe and high Ca content residue was achieved. The reasons for excessive pressure drop of R-101 were ascribed to Fe and Ca deposition as well as coke formation.展开更多
New definition of virtual molecular-group components about CH and CH2 is proposed in the paper.The new reaction,hydrogenation of CH to CH2(HDCH),can be used to represent the change of C and H in RHT.By using the lumpi...New definition of virtual molecular-group components about CH and CH2 is proposed in the paper.The new reaction,hydrogenation of CH to CH2(HDCH),can be used to represent the change of C and H in RHT.By using the lumping approach,the kinetic models about HDCH,HDS,HDN,HDCCR,HDM,HDNi and HDV reactions were established.They are key components of the new kinetic model for RHT based on reaction sections.During the construction of kinetic model,goodness-to-fit(R^2)between test data and model data was set as the target value,and the model parameters were calculated accurately.In verification test,the predicted content of H,S,N,CCR,M,Ni and V can match well with the test data.展开更多
The VRDS feedstock processed in refineries along the Yangtze River has special characteristics, including high Fe and Ca content, and low sulfur and high nitrogen content. Depending upon feedstock properties and opera...The VRDS feedstock processed in refineries along the Yangtze River has special characteristics, including high Fe and Ca content, and low sulfur and high nitrogen content. Depending upon feedstock properties and operating conditions,some approaches have been developed by the SINOPEC Research Institute of Petroleum Processing(RIPP), which include installing the decalcification facility, developing new guard catalysts and HDCCR catalysts, implementing a new catalyst grading approach, developing a highly efficient distribution technology and applying RICP process in some refineries.The application effects have revealed that the integrated technology, which can be conducive to the long-cycle operation developed by RIPP, can maximize the deposits uptake capacity of the guard reactor and the activity of grading catalysts.展开更多
基金support from the SINOPEC Research Program(No.111145)
文摘The RHT technology and the second generation RHT catalysts were applied in design of an 1.7Mt/a VRDS unit at the SINOPEC Changling Branch Co. The commercial application result demonstrated that the RHT catalysts showed good activity and stability in processing low-sulfur and high-nitrogen residue. The first long period run of unit for processing high Fe and high Ca content residue was achieved. The reasons for excessive pressure drop of R-101 were ascribed to Fe and Ca deposition as well as coke formation.
基金financially supported by the SINOPEC Research Program(Grant KL20009 and 118015-2)。
文摘New definition of virtual molecular-group components about CH and CH2 is proposed in the paper.The new reaction,hydrogenation of CH to CH2(HDCH),can be used to represent the change of C and H in RHT.By using the lumping approach,the kinetic models about HDCH,HDS,HDN,HDCCR,HDM,HDNi and HDV reactions were established.They are key components of the new kinetic model for RHT based on reaction sections.During the construction of kinetic model,goodness-to-fit(R^2)between test data and model data was set as the target value,and the model parameters were calculated accurately.In verification test,the predicted content of H,S,N,CCR,M,Ni and V can match well with the test data.
文摘The VRDS feedstock processed in refineries along the Yangtze River has special characteristics, including high Fe and Ca content, and low sulfur and high nitrogen content. Depending upon feedstock properties and operating conditions,some approaches have been developed by the SINOPEC Research Institute of Petroleum Processing(RIPP), which include installing the decalcification facility, developing new guard catalysts and HDCCR catalysts, implementing a new catalyst grading approach, developing a highly efficient distribution technology and applying RICP process in some refineries.The application effects have revealed that the integrated technology, which can be conducive to the long-cycle operation developed by RIPP, can maximize the deposits uptake capacity of the guard reactor and the activity of grading catalysts.
