ZrB_(2)-Al_(2)O_(3)composite powders were synthesized at 1100℃using a novel ZrB_(2)precursor and Al powders as raw materials.The final ZrB_(2)-Al_(2)O_(3)composite powders consisted of submicron Al_(2)O_(3)and nanosi...ZrB_(2)-Al_(2)O_(3)composite powders were synthesized at 1100℃using a novel ZrB_(2)precursor and Al powders as raw materials.The final ZrB_(2)-Al_(2)O_(3)composite powders consisted of submicron Al_(2)O_(3)and nanosize ZrB_(2)(50-100 nm)particles,which were homogeneously mixed in microscale.Combined with thermodynamic calculation and experiment results,the formation mechanism of ZrB_(2)-Al_(2)O_(3)composite powders was proposed as follows:ZrB_(2)precursor first decomposed into ZrO_(2)and amorphousB2O3.Aluminothermic reduction of ZrO_(2) and B_(2)O_(3) generated Zr and B atoms and the coproducts Al_(2)O_(3),and then,a series of reactions between Zr atoms,B atoms and Al took place to form ZrB_(2)and Al_(3)Zr.Then,ZrB_(2),Al_(2)O_(3)and Al were obtained through a liquid-solid reaction between Al_(3)Zr andB2O3,which is the limiting step in the conversion process.When the Al_(3)Zr was exhausted,the reaction between Al,ZrO_(2)and B became the main reaction to obtain ZrB_(2)and Al_(2)O_(3).展开更多
基金the National Natural Science Foundation of China(Nos.51672170 and 51702206)Shanghai Science and Technology Commission Research Project(No.17XD1424700)。
文摘ZrB_(2)-Al_(2)O_(3)composite powders were synthesized at 1100℃using a novel ZrB_(2)precursor and Al powders as raw materials.The final ZrB_(2)-Al_(2)O_(3)composite powders consisted of submicron Al_(2)O_(3)and nanosize ZrB_(2)(50-100 nm)particles,which were homogeneously mixed in microscale.Combined with thermodynamic calculation and experiment results,the formation mechanism of ZrB_(2)-Al_(2)O_(3)composite powders was proposed as follows:ZrB_(2)precursor first decomposed into ZrO_(2)and amorphousB2O3.Aluminothermic reduction of ZrO_(2) and B_(2)O_(3) generated Zr and B atoms and the coproducts Al_(2)O_(3),and then,a series of reactions between Zr atoms,B atoms and Al took place to form ZrB_(2)and Al_(3)Zr.Then,ZrB_(2),Al_(2)O_(3)and Al were obtained through a liquid-solid reaction between Al_(3)Zr andB2O3,which is the limiting step in the conversion process.When the Al_(3)Zr was exhausted,the reaction between Al,ZrO_(2)and B became the main reaction to obtain ZrB_(2)and Al_(2)O_(3).
