期刊文献+
共找到4篇文章
< 1 >
每页显示 20 50 100
校企联姻筑巢育人,匠心培育筑梦兴牧——黑龙江农业经济职业学院畜牧兽医专业“三主体、三阶段、三融合”现代学徒制人才培养典型案例 被引量:1
1
作者 范学伟 冯永谦 +2 位作者 姜鑫 张绍男 田洪峰 《猪业科学》 2021年第5期70-73,共4页
黑龙江省是我国重要的畜牧业生产基地,习近平总书记在黑龙江省考察调研期间针对农业供给侧改革明确指出:加快推进一、二、三产业深度融合,切实发挥畜牧产业在粮头食尾、农头工尾中的桥梁纽带作用,把黑龙江省建设成全国重要的绿色、安全... 黑龙江省是我国重要的畜牧业生产基地,习近平总书记在黑龙江省考察调研期间针对农业供给侧改革明确指出:加快推进一、二、三产业深度融合,切实发挥畜牧产业在粮头食尾、农头工尾中的桥梁纽带作用,把黑龙江省建设成全国重要的绿色、安全、放心、高品质食品供应基地。近年来,深圳金新农、广东温氏、江西正邦、四川天兆等企业生猪养殖项目纷纷落地投产黑龙江,截至2020年底,黑龙江省生猪存栏1 371.2万头,比上年增长16.9%;出栏1 790.0万头。 展开更多
关键词 畜牧业生产基地 农业供给侧改革 畜牧兽医专业 食品供应 校企联姻 畜牧产业 深度融合 桥梁纽带作用
下载PDF
光催化甲苯衍生物、环烷烃与无机亚磺酸盐的位点选择性C(sp^(3))-H砜基化
2
作者 张少南 曹石 +3 位作者 林玉妹 沙利源 陆成 龚磊 《Chinese Journal of Catalysis》 SCIE EI CAS CSCD 2022年第3期564-570,共7页
烃类是最基础的有机分子之一,具有品种丰富、来源广泛、价格低廉等优势,其多样性、选择性转化一直备受合成化学家关注.然而,这些化合物中通常存在多个键能高、极性低、相互间差异性小的C(sp^(3))-H键,因此,实现高效、选择性C-H官能化极... 烃类是最基础的有机分子之一,具有品种丰富、来源广泛、价格低廉等优势,其多样性、选择性转化一直备受合成化学家关注.然而,这些化合物中通常存在多个键能高、极性低、相互间差异性小的C(sp^(3))-H键,因此,实现高效、选择性C-H官能化极具挑战性.近年来,可见光催化广泛应用于有机合成中,与氢转移催化相结合所发展的可见光氢转移光催化策略在C(sp^(3))-H官能化反应中展现了较大的潜力,特别是为化学、位点、立体选择性等问题的解决带来了新机遇.尽管如此,能在激发态有效切断烷烃、环烷烃等中未活化的C(sp^(3))-H键,被用于直接氢转移光催化的催化剂种类很少,主要局限于十钨酸盐、芳香酮衍生物等,因此,发展新型氢转移光催化剂和新反应具有重要意义.近期人们发现,一种共轭多元醌分子(5,7,12,14-并五苯四酮,PT)具有较好的光物理性质、电化学性能及溶解性,可被用作直接氢转移光催化剂.为了深入研究其催化活性及在惰性烃类化合物转化中的应用,本文利用PT与铜盐协同作用,开发了一种高效、高选择性的C(sp^(3))-H砜基化反应,以无机亚磺酸盐作为砜基化试剂,将一系列甲苯衍生物、环烷烃、药物类似物等转化为具有潜在生物活性和重要合成应用的砜类产物.该反应条件温和、操作简单,不需要使用贵金属催化剂和配体,反应原料均已商品化且价格较便宜.通过自由基淬灭与捕获、自由基钟、控制实验、荧光淬灭等机理实验,证明了反应的自由基历程和铜介导的金属有机过程.X射线光电子能谱证明过程中伴随着零价铜的产生,反应仅需要1.2当量的二价铜盐作为氧化剂,为多样性C‒H官能化反应提出了新的策略和路径.此外,该方法还成功应用于药物类似物的后期官能化,展现了良好的官能团兼容性和位点选择性,进一步证明了其应用价值.综上所述,本文以一种商品化的共轭多元醌作为直接氢转移光催化剂,铜盐为氧化剂,无机亚磺酸盐为砜基化试剂,开发了一种经济低毒、温和易操作的甲苯衍生物、环烷烃C(sp^(3))-H官能化新方法,为砜类化合物的合成与开发利用提供了高效、高选择性的途径,也为药物分子后期官能化提供了有效的手段. 展开更多
关键词 可见光 光催化 C(sp^(3))-H官能化 砜基化 自由基
下载PDF
The effect of thermal fluid derived from mud diapir on sandstone reservoirs in the Yinggehai Basin, South China Sea
3
作者 Xiaowei Lv Meiyan Fu +5 位作者 shaonan zhang Yi Liu Xiaoqi Ding Xianghao Meng Shuai Yin Tengjiao Sun 《Energy Geoscience》 2022年第4期473-484,共12页
The underground thermal fluid is one of the significant factors controlling the formation and quality of reservoirs.The Huangliu Formation(N_(1)h)in YF1 area of the central depression belt in the Yinggehai Basin,South... The underground thermal fluid is one of the significant factors controlling the formation and quality of reservoirs.The Huangliu Formation(N_(1)h)in YF1 area of the central depression belt in the Yinggehai Basin,South China Sea,is characterized by intense thermal fluid activities related to mud diapir and large-scale shallow-water gravity flow deposits.The multi-episodic invasion of high-temperature and CO_(2)-rich thermal fluid into the formation induces complex water-rock reaction during diagenetic pro-cess,providing a preferable investigation opportunity for revealing how thermal fluid affects reservoir quality.This study characterizes the reservoirs in the formation through core and thin section analyses as well as physical property test.The reservoirs are dominated by fine-grained sandstone characterized by medium porosity(15.2-21.3%)and lower permeability(0.56-15.75mD).Based on an analysis of casting thin section,cathode luminescence(CL),scanning electron microscope(SEM),carbon and oxygen isotope,inclusion test,and electron-probe microanalysis(EPMA),we systematically investigate the diagenetic patterns and pore evolution process for the reservoirs in the formation.The episodic invasion of thermal fluid occurred approximately 0.4 Ma ago plays an important role in controlling reservoir development:The CO_(2)-rich formation water induces massive late-stage dissolution,resulting in a higher proportion of dissolved pores(38.7-46.4%),which improves the porosity of reservoirs at a depth of 2600-3100 m.Nevertheless,the late dissolution together with carbonate cementation occurred in closed diagenetic system blocks most seepage channels.Furthermore,the relatively high level clay mineral transformation in the YF1 area leads to a higher content of authigenic illite(44-62%)in the formation.Massive authigenic illite severely blocks the pore throats in fine sandstone,reducing permeability.This study offers an insight to the understanding of mud diapir-derived thermal fluid affecting and controlling the quality of reservoirs in some areas of the Yinggehai Basin. 展开更多
关键词 Thermal fluid Sandstone diagenesis CO_(2)dissolution Low permeability Huangliu Formation
下载PDF
Reservoir formation mechanism analysis and deep high-quality reservoir prediction in Yingcheng Formation in Longfengshan area of Songliao Basin, China 被引量:1
4
作者 Yongmei zhang Xiaoqi Ding +3 位作者 Peng Yang Yan Liu Qi Jiang shaonan zhang 《Petroleum》 2016年第4期334-343,共10页
Although commercial gas flow was produced in several wells with recent years'exploration of Longfengshan area in Changling fault sag,the formation mechanism and controlling factors for high-quality reservoirs stil... Although commercial gas flow was produced in several wells with recent years'exploration of Longfengshan area in Changling fault sag,the formation mechanism and controlling factors for high-quality reservoirs still remained undefined.Here,the Yingcheng tight gas reservoirs of Longfengshan area are used as an example to characterize high-quality reservoir formation mechanism and distribution rules.Based on the thin section,SEM,X-ray diffraction,computed tomography(CT)scanning,burial history,constant-rate mercury penetration and physical properties testing,formation mechanism and controlling factors for high-quality reservoirs were analyzed.Results show the following characteristics.First,the reservoir is dominated by chlorite and laumontite cements,and compaction is the most important factor to control reservoir physical properties.According to this,the reservoir can be divided into compacted tight sandstones,chlorite-cemented sandstones and laumontite-cemented sandstones.Second,the high-quality reservoirs are formed due to early extensive laumontite precipitation and the later dissolution of laumontite by organic acid.Meanwhile,it is found that the distribution of cementation and dissolution exhibits some regulations in sedimentary facies,and the distribution is mainly effected and controlled by the lake water and charging of fresh water.Besides,the distribution model of various types of sandstones was established.Studies over diagenesis and sedimentary facies reveal that the high-quality laumontite-cemented sandstones exist in the outside subaqueous fan-delta of the deep sag in Longfengshan area.These findings have been validated by recent exploration wells which obtained high industrial gas flow. 展开更多
关键词 DIAGENESIS Laumontite cement High-quality reservoir Secondary pore The outside subaqueous fan-delta
原文传递
上一页 1 下一页 到第
使用帮助 返回顶部