ZnMOF-BTA,a new metal–organic framework with excellent anti-corrosion properties was prepared and characterized.Polarization and immersion tests in 3.5 wt%NaCl were performed on AA2024-T3 alloy to assess the corrosio...ZnMOF-BTA,a new metal–organic framework with excellent anti-corrosion properties was prepared and characterized.Polarization and immersion tests in 3.5 wt%NaCl were performed on AA2024-T3 alloy to assess the corrosion inhibition ability of ZnMOF-BTA.It showed an inhibition efficiency of more than 90%,indicating excellent corrosion inhibition of ZnMOF-BTA on AA 2024-T3 in NaCl.Moreover,ZnMOF-BTA particles were incorporated into polyurethane coatings to create corrosion-resistant coatings.Electrochemical tests and neutral salt spray analysis were used to assess the corrosion protection ability of ZnMOF-BTA-laden polyurethane coatings.The results of electrochemical impedance spectra clearly showed the outstanding corrosion resistance and durability of ZnMOF-BTA coatings after 1440 h of immersion with a high pore resistance(Rpo)of 1.76×10^(10)Ωcm^(2).In addition,during the cross-cut adhesion test,the coating did not detach from the substrate,and after the impact test,there was scarcely any indication of a fracture,which further supports the notion that the coating has strong adhesion to the substrate.展开更多
Rapid NIR light detection and/or writing has drawn much attention,but their practical applications have been limited by obtaining such NIR photodetectors.To address this problem,we have developed a simple and versatil...Rapid NIR light detection and/or writing has drawn much attention,but their practical applications have been limited by obtaining such NIR photodetectors.To address this problem,we have developed a simple and versatile strategy to prepare a non-woven fabric photodetector.The blue non-woven fabric photodetector has been prepared by coating photo-thermochromic ink(including crystal violet lactone(CVL)as the thermo-sensitive dye,polypyrrole(PPy)nanospheres as the photothermal component and hydroxyethyl cellulose(HEC)as the polymer matrix)on white non-woven fabric.When the blue fabric photodetector is irradiated by NIR(808-nm as model,0.75 W cm^(−2))laser,the discoloration occurs in 35 s,and higher laser intensity confers more rapid discoloration.This discoloration results from the photothermal effect of PPy which confers the elevation of temperature(>50℃)and then converts CVL to its leuco form(colorless).When the laser is turned off,the temperature drops to below the transition temperature(<43℃),and then CVL reverts to its initial blue color.Moreover,different figures and images can be easily printed on the fabric photodetector by 808 nm laser,and then they can be erased automatically under ambient conditions,with excellent cycling stability.Therefore,this fabric photodetector may act as a new platform for rapid NIR light detection and writing.展开更多
基金the National Natural Science Foundation of China(Nos.52171089 and 51571202)the LingChuang Research Project of China National Nuclear Corporation(No.E041F212Z1).
文摘ZnMOF-BTA,a new metal–organic framework with excellent anti-corrosion properties was prepared and characterized.Polarization and immersion tests in 3.5 wt%NaCl were performed on AA2024-T3 alloy to assess the corrosion inhibition ability of ZnMOF-BTA.It showed an inhibition efficiency of more than 90%,indicating excellent corrosion inhibition of ZnMOF-BTA on AA 2024-T3 in NaCl.Moreover,ZnMOF-BTA particles were incorporated into polyurethane coatings to create corrosion-resistant coatings.Electrochemical tests and neutral salt spray analysis were used to assess the corrosion protection ability of ZnMOF-BTA-laden polyurethane coatings.The results of electrochemical impedance spectra clearly showed the outstanding corrosion resistance and durability of ZnMOF-BTA coatings after 1440 h of immersion with a high pore resistance(Rpo)of 1.76×10^(10)Ωcm^(2).In addition,during the cross-cut adhesion test,the coating did not detach from the substrate,and after the impact test,there was scarcely any indication of a fracture,which further supports the notion that the coating has strong adhesion to the substrate.
基金This work was financially supported by the National Natural Science Foundation of China(51773036 and 51972056)Shanghai Shuguang Program(18SG29)+3 种基金Natural Science Foundation of Shanghai(18ZR1401700)Innovation Program of Shanghai Municipal Education Commission(2017-01-07-00-03-E00055)the Fundamental Research Funds for the Central UniversitiesDHU Distinguished Young Professor Program.
文摘Rapid NIR light detection and/or writing has drawn much attention,but their practical applications have been limited by obtaining such NIR photodetectors.To address this problem,we have developed a simple and versatile strategy to prepare a non-woven fabric photodetector.The blue non-woven fabric photodetector has been prepared by coating photo-thermochromic ink(including crystal violet lactone(CVL)as the thermo-sensitive dye,polypyrrole(PPy)nanospheres as the photothermal component and hydroxyethyl cellulose(HEC)as the polymer matrix)on white non-woven fabric.When the blue fabric photodetector is irradiated by NIR(808-nm as model,0.75 W cm^(−2))laser,the discoloration occurs in 35 s,and higher laser intensity confers more rapid discoloration.This discoloration results from the photothermal effect of PPy which confers the elevation of temperature(>50℃)and then converts CVL to its leuco form(colorless).When the laser is turned off,the temperature drops to below the transition temperature(<43℃),and then CVL reverts to its initial blue color.Moreover,different figures and images can be easily printed on the fabric photodetector by 808 nm laser,and then they can be erased automatically under ambient conditions,with excellent cycling stability.Therefore,this fabric photodetector may act as a new platform for rapid NIR light detection and writing.
