期刊文献+
共找到5篇文章
< 1 >
每页显示 20 50 100
Acoustic emission characteristics and stress release rate of coal samples in different dynamic destruction time 被引量:3
1
作者 Xiao Fukun Liu Gang +3 位作者 Zhang Ze shen zhiliang Zhang Fengrui Wang Yifei 《International Journal of Mining Science and Technology》 SCIE EI CSCD 2016年第6期981-988,共8页
Considering the importance of the prediction of rock burst disasters, and in order to grasp the law of acoustic emission(AE) of coal samples in different dynamic destruction time, the SH-II AE monitoring system was ad... Considering the importance of the prediction of rock burst disasters, and in order to grasp the law of acoustic emission(AE) of coal samples in different dynamic destruction time, the SH-II AE monitoring system was adopted to monitor the failure process of coal samples. The study of the change rule of the AE numbers, energy, ‘b' value and spectrum in the micro crack propagation process of the coal samples shows that as dynamic damage time went by, AE presented high-energy counts and the accumulated counts increased during the compression phase. The AE energy and cumulative counts increased during the elastic stage. The AE blank area increased gradually and the blank lines were more and more obvious in the molding stage. The AE counts and energy showed a trend of decrease in the residual damage phase.AE ‘b' values gradually became sparse, and the large scale cracks percentage compared with micro cracks decreased and the degree of damage decreased. The AE frequency spectrum peak went from the residual damage phase to the molding phase, and finally it was nearly stable, besides the bandwidth of the main frequency is gradually narrowed. Also, the frequency peak changed from single peak frequency to bi-peak frequency and to the single peak frequency. Uniaxial compressive strength is more sensitive than the elastic modulus to dynamic damage time. 展开更多
关键词 Dynamic destruction time Acoustic emission Outburst-proneness Stress release rate
下载PDF
Silica supply and diatom blooms in the Jiaozhou Bay, China 被引量:3
2
作者 shen zhiliang YAO Yun WU Yulin 《Acta Oceanologica Sinica》 SCIE CAS CSCD 2016年第10期20-27,共8页
The variations in nutrients(molar ratios) and chlorophyll a in the Jiaozhou Bay were examined before and after a diatom bloom in a period that lasted from November 2003 to March 2004. Negative relationships between ... The variations in nutrients(molar ratios) and chlorophyll a in the Jiaozhou Bay were examined before and after a diatom bloom in a period that lasted from November 2003 to March 2004. Negative relationships between nutrient concentrations, Si/P, Si/N ratios and chlorophyll a content were found during the bloom, which reflected the relationship between nutrient concentrations, phytoplankton biomass and growth. Large increase in nutrient concentrations, particularly SiO_3-Si after the late autumn, is one of major reasons inducing the diatom bloom in winter, and the bloom was finally controlled due to SiO_3-Si depletion by phytoplankton. The bloom was mainly controlled by SiO_3-Si. Before 1998, relatively low level of SiO_3-Si kept ecological balance of eutrophication waters in the Jiaozhou Bay. In recent years, however, human activities have increased SiO_3-Si concentration, which is likely one of the primary cause for the increased diatom blooms in the Jiaozhou Bay. Therefore, it is necessary to control SiO_3-Si concentration in the Jiaozhou Bay. 展开更多
关键词 NUTRIENT PHYTOPLANKTON chlorophyll α BLOOMS Si supply Jiaozhou Bay
下载PDF
矿物掺合料与减水剂相容性对预拌混凝土性能影响试验研究 被引量:1
3
作者 申志良 姚剑平 +3 位作者 周梅君 陈巧梅 范静 李少伟 《福建建设科技》 2022年第4期61-64,共4页
为了探索矿物掺合料与减水剂相容性对预拌混凝土性能的影响,本文通过正交设计对聚羧酸系减水剂、S95矿粉和二级粉煤灰三个因素的三个掺量,分析了矿物掺合料与减水剂相容性对预拌混凝土工作性和强度的影响。结果表明,聚羧酸系减水剂与矿... 为了探索矿物掺合料与减水剂相容性对预拌混凝土性能的影响,本文通过正交设计对聚羧酸系减水剂、S95矿粉和二级粉煤灰三个因素的三个掺量,分析了矿物掺合料与减水剂相容性对预拌混凝土工作性和强度的影响。结果表明,聚羧酸系减水剂与矿物掺合料具有较好的相容性,粉煤灰或矿粉掺入分别对预拌混凝土的工作性或强度具有改善作用。 展开更多
关键词 减水剂 粉煤灰 矿粉 预拌混凝土 工作性 强度
下载PDF
铁(0)促进的醛与溴代硝基甲烷的Henry型反应高效合成2-硝基-1-醇 被引量:1
4
作者 张斯旋 李祥瑞 +4 位作者 李文欣 饶卫东 葛丹华 沈志良 褚雪强 《有机化学》 SCIE CAS CSCD 北大核心 2022年第1期235-241,共7页
以廉价易得、商品化的铁粉为反应促进剂,研究了溴代硝基甲烷与各种醛的Henry型反应,高效地合成了2-硝基-1-醇.该反应在PbCl_(2)和四丁基硫酸氢铵(TBAHS)存在下有效地进行,以中等至良好的产率得到目标产物,并且该反应具有广泛的官能团耐... 以廉价易得、商品化的铁粉为反应促进剂,研究了溴代硝基甲烷与各种醛的Henry型反应,高效地合成了2-硝基-1-醇.该反应在PbCl_(2)和四丁基硫酸氢铵(TBAHS)存在下有效地进行,以中等至良好的产率得到目标产物,并且该反应具有广泛的官能团耐受性. 展开更多
关键词 二氯化铅 Henry型反应 溴代硝基甲烷 2-硝基-1-醇
原文传递
二氟烯醇硅醚作为含氟砌块在构建有机氟化物中的研究进展
5
作者 郭檬檬 于子伦 +4 位作者 陈玉兰 葛丹华 马猛涛 沈志良 褚雪强 《有机化学》 SCIE CAS CSCD 北大核心 2022年第11期3562-3587,共26页
与非氟化合物相比,有机氟化合物由于其特殊的化学和物理性质被广泛应用于药物开发、临床医学、农业化学、材料科学和有机合成等领域.在过去的几十年中,在选择性氟化和氟烷基化合成结构多样的含氟分子方面取得了重大进展.其中,α-氟烷基... 与非氟化合物相比,有机氟化合物由于其特殊的化学和物理性质被广泛应用于药物开发、临床医学、农业化学、材料科学和有机合成等领域.在过去的几十年中,在选择性氟化和氟烷基化合成结构多样的含氟分子方面取得了重大进展.其中,α-氟烷基化羰基代表了生物活性和药物分子中一类重要的分支骨架.在此背景下,基于使用二氟烯醇硅醚(DFSEE)作为独特的氟代烷基化试剂,已经实现了多种引入偕二氟烷基化羰基片段的有效方法,包括羟醛反应、曼尼希反应、芳基化反应、烯丙基化反应、质子化反应、卤化反应、共轭加成反应和烯化反应等.另一方面,DFSEE凭借其优异的反应灵活性,还能与自由基型二氟烷基化和级联反应等新型反应模式相融合.此外,还报道了DFSEE参与的O位选择性加成反应,能够构建多功能的偕二氟烯烃.鉴于有机氟化合物的重要性和基于二氟烯醇硅醚作为反应物参与合成含氟化合物途径的巨大潜力,重点介绍了DFSEE作为关键含氟功能化砌块合成氟化物的最新研究进展. 展开更多
关键词 二氟烯醇硅醚 含氟砌块 含氟化合物 二氟烷基化 有机氟化学
原文传递
上一页 1 下一页 到第
使用帮助 返回顶部