An efficient and cost-effective method for the preparation of fluorinated conjugated enynes was described, tile method was compatible with a variety of functional groups such as chloride, amine, cyano and ester group....An efficient and cost-effective method for the preparation of fluorinated conjugated enynes was described, tile method was compatible with a variety of functional groups such as chloride, amine, cyano and ester group. The method could also be extended to the coupling of (R,Z)-3-(2-chloro-1,2-difluorovinyl)-4-alkyloxazolidin-2-one (3) with moderate yields.展开更多
基金Acknowledgement The authors gratefully acknowledge the financial support from National Basic Research Program of China (Nos. 2012CB821600, 2010CB126103), the Key Program of Natural Science Foundation of China (No.21032006), National Natural Science Foundation of China (Nos. 21172245, 21172244, B020304), Agroscientific Research in the Public Interest (No. 201103007), the National Key Technologies R&D Program (No. 2011BAE06B05), Shanghai Scientific Research Program (No. 10XD1405200), and SIOC.
文摘An efficient and cost-effective method for the preparation of fluorinated conjugated enynes was described, tile method was compatible with a variety of functional groups such as chloride, amine, cyano and ester group. The method could also be extended to the coupling of (R,Z)-3-(2-chloro-1,2-difluorovinyl)-4-alkyloxazolidin-2-one (3) with moderate yields.