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二氧化硅改性分子筛催化生物质基多元醇制备对二甲苯(英文) 被引量:2
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作者 王声飞 范明慧 +1 位作者 何雨婷 李全新 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2019年第4期513-520,I0003,共9页
本文证明了在二氧化硅改性的分子筛催化作用下,生物质基多元醇(如山梨醇、木糖醇、赤藓糖醇、甘油和乙二醇)可以经过催化裂解、烷基化和异构化等反应,生成高附加值的化学品(对二甲苯).与HZSM-5分子筛催化剂相比,二氧化硅改性的分子筛降... 本文证明了在二氧化硅改性的分子筛催化作用下,生物质基多元醇(如山梨醇、木糖醇、赤藓糖醇、甘油和乙二醇)可以经过催化裂解、烷基化和异构化等反应,生成高附加值的化学品(对二甲苯).与HZSM-5分子筛催化剂相比,二氧化硅改性的分子筛降低了分子筛催化剂的外表面酸和孔径,从而显著的提高对甲苯的选择性和产率.本文详细讨论了催化剂、甲醇添加剂、反应温度和不同类型多元醇原料对对二甲苯选择性和产率的影响.甲醇的添加促进多元醇催化裂解中的烷基化反应,提高了二甲苯的产率.在15%SiO2/HZSM-5催化剂作用下,对二甲苯的产率最高可达到10.9C-mol%,对二甲苯在二甲苯中选择性达到91.1%.本文通过研究相关重要反应和催化剂特性,揭示了生物质基多元醇催化裂解制备对二甲苯的反应路径. 展开更多
关键词 生物质基多元醇 对二甲苯 催化转化 二氧化硅改性的分子筛
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Investigation of Surface Micro Waviness in Single Point Diamond Fly Cutting 被引量:1
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作者 sheng-fei wang Peng-Qiang Fu +2 位作者 Fei-Hu Zhang Chen-Hui An Yong Zhang 《Journal of Harbin Institute of Technology(New Series)》 EI CAS 2014年第5期119-123,共5页
Single point diamond fly cutting is widely used in the manufacture of large-aperture ultra-precision optical elements. However,some micro waviness( amplitude about 30 nm,wavelength about 15 mm) along the cutting direc... Single point diamond fly cutting is widely used in the manufacture of large-aperture ultra-precision optical elements. However,some micro waviness( amplitude about 30 nm,wavelength about 15 mm) along the cutting direction which will decrease the quality of the optical elements can always be found in the processed surface,and the axial vibration of the spindle caused by the cut-in process is speculated as the immediate cause of this waviness. In this paper,the analytical method of dynamic mesh is applied for simulating the dynamic behavior of the vertical spindle. The consequence is then exerted to the fly cutter and the processed surface profile is simulated. The wavelength of the simulation result coincides well with the experimental result which proves the importance of the cut-in process during the single point diamond fly cutting. 展开更多
关键词 surface waviness surface profile spindle dynamic behavior single point diamond fly cutting
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Feasibility of underground NPP and its MCDA-based optimization
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作者 Hou-Bo Qi Feng-Lei Niu +2 位作者 Yun-Gan Zhao Yu Yu sheng-fei wang 《Nuclear Science and Techniques》 SCIE CAS CSCD 2016年第4期89-95,共7页
The underground nuclear power plant(NPP)makes full use of land resources, reduces costs, makes better use of its passive safety, and avoids radioactivity release into the atmosphere in serious nuclear accidents.In thi... The underground nuclear power plant(NPP)makes full use of land resources, reduces costs, makes better use of its passive safety, and avoids radioactivity release into the atmosphere in serious nuclear accidents.In this paper, for obtaining comprehensive and integrated analyses on this new NPP design, we introduce four kinds of underground NPP designs, analyze the feasibility of each design from various aspects, and use the multiple criteria decision analysis method to choose the best option. 展开更多
关键词 核电站 资源优化 决策分析方法 电厂设计 放射性释放 土地资源 被动安全 最佳方案
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